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Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Physicochemical Study of an Anhydrous Organic Acidic Cyclohexaphosphate

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Abstract

The new organic–inorganic hybrid [5-Cl-2-(CH3)C6H3NH3]4H2P6O18 has been synthesized by the slow evaporation method. X-ray diffraction on a single crystal shows that this acidic cyclohexaphosphate crystallized in the monoclinic space group C 2/c with a = 33.89(11) Å, b = 9.16(16) Å, c = 13.68(3) Å, β = 91.35(2)°, V = 4244.9(19) Å3 and Z = 4. 31P MAS-NMR and 13C CP/MAS-NMR results are in accordance with X-ray findings. Fluorescent study shows the blue photoluminescence. Furthermore, FT-IR analysis was studied and the complete vibrational assignments were done. Intermolecular interactions were analyzed using Hirshfeld surface analysis and the associated 2D fingerprint plots.

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Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021, Zarzouna, Tunisia

    Ramzi Fezai & Mohamed Rzaigui

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  1. Ramzi Fezai
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  2. Mohamed Rzaigui
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Correspondence to Ramzi Fezai.

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10895_2017_2181_MOESM1_ESM.zip

Crystallographic data (CIF) for the studied structure have been deposed with the Cambridge crystallographic data centre as supplementary publication N° CCDC- 1551578. Copies of the data can be obtained, free for charge, at http://www.ccdc.cam.ac.uk/conts/retrieving.html and applying to the CCDC, 12 Union Road, Cambridge CB 12 EZ, UK (Fax: int.code +44(1223)336-033or e-mail: deposit@ccdc.cam.ac.uk). (ZIP 4 KB)

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Fezai, R., Rzaigui, M. Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Physicochemical Study of an Anhydrous Organic Acidic Cyclohexaphosphate. J Fluoresc 28, 183–193 (2018). https://doi.org/10.1007/s10895-017-2181-4

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  • DOI: https://doi.org/10.1007/s10895-017-2181-4

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