Abstract
The review is devoted to the analysis of the effect of the addition of various surfactants on the composition, structure, and the properties of the interfacial adsorption layers (IALs) formed at equilibrium in the aqueous gelatin solution–hydrocarbon system. Associates of variable compositions that are determined by the component ratio and the concentration of added surfactant are formed due to the interaction between gelatin and surfactant. The formation of associates is equivalent to the modification of gelatin. The properties of the IALs of modified gelatins are discussed on the basis of our own results and published data on the interfacial tension, the mass accumulation of surface-active components at the interfaces during the IAL formation, the IAL rheological properties and the stability of emulsion films varied with the conditions of IAL formation (the nature of low-molecular-weight surfactant, component concentrations, pH of aqueous phase, and temperature). It was concluded that modified gelatins can be considered as new surfactants governing the dynamics of the formation and fracture mechanism of the IALs and the stability of emulsion films. The properties of the IALs of modified gelatins are compared with those of IALs formed by gelatin and low-molecular-weight surfactants under the conditions when associates are formed directly at the interface due to the use of oil-soluble surfactants.
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REFERENCES
Rehbinder, P.A., Poverkhnostnye yavleniya v dispersnykh sistemakh. Kolloidnaya khimiya. Izbr. trudy (Interfacial Phenomena in Disperse Systems. Colloid Chemistry. Selected Works), Moscow: Nauka, 1978, vol. 1.
Rehbinder, P.A., Fiziko-khimicheskaya mekhanika. Izbr. trudy (Physico-chemical Mechanics. Selected Works), Moscow: Nauka, 1979, vol. 2.
Izmailova, V.N. and Rehbinder, P.A., Strukturoobrazovanie v belkovykh sistemakh (Structure Formation in Protein Systems), Moscow: Khimiya, 1974.
Adamson, A.W., Physical Chemistry of Surfaces, New York: Wiley, 1963. Translated under the title Fizicheskaya khimiya poverkhnostei, Moscow: Mir, 1979.
Mazurov, V.I., Biokhimiya kollagenovykh belkov (Biochemistry of Collagen Proteins), Moscow: Khimiya, 1974.
Veis, A., The Macromolecular Chemistry of Gelatin, New York: Academic, 1964. Translated under the title Makromolekulyarnaya khimiya zhelatina, Moscow: Pishchepromizdat, 1971.
Nagarajan, R., Colloids Surf., 1985, vol. 13, p. 1.
Narath, A. and Grindlach, D., Photogr. Correspondence, 1969, vol. 105,no. 1, p. 53.
Nordwig, A., Hormann, H., Kuhn, K., et al., Z. Phys. Chem., 1961, vol. 325,no. 2, p. 242.
Wustneck, R., Tsastrov, L., and Kretzchmar, G., Kolloidn. Zh., 1987, vol. 49,no. 1, p. 10.
Zavlin, P.M., Nuss, V.P., Ovchinnikov, A.N., et al., Zh. Nauchn. Prikl. Fotogr., 1993, vol. 38,no. 5, p. 8.
Zavlin, P.M., Nuss, P.V., Ovchinnikov, A.N., et al., Zh. Prikl. Khim. (St. Petersburg), 1993, vol. 66,no. 3, p. 615.
Zavlin, P.M., Izmailova, V.N., Musaelyan, G.S., et al., Zh. Prikl. Khim. (St. Petersburg), 1993, vol. 66,no. 2, p. 622.
Zavlin, P.M., Sakvarelidze, M.A., Yakhdzhi, Kh., et al., Zh. Prikl. Khim. (St. Petersburg), 1993, vol. 66,no. 2, p. 707.
Pezron, I., Djabourov, M., and Leblond, J., Polymer, 1991, vol. 32, p. 3200.
Izmailova, V.N., Yampol'skaya, G.P., and Summ, B.D., Poverkhnostnye yavleniya v belkovykh sistemakh (Surface Phenomena in Protein Systems), Moscow: Khimiya, 1988.
Harrington, W.F. and Hippel, P.H., Arch. Biochem. Biophys., 1961, vol. 92,no. 1, p. 100.
Chien, C.W. and Wise, W.B., Biochemistry, 1975, vol. 14,no. 12, p. 2786.
Izmailova, V.N. and Yampol'skaya, G.P., Kozh.-Obuvn. Prom-st'., 1990, no. 11, p. 34.
Dolinnyi, A.I. and Izmailova, V.N., Vysokomol. Soedin., Ser. B, 1978, vol. 20,no. 1, p. 39.
Fruhner, H. and Kretzschmar, G., Colloid Polym. Sci., 1989, vol. 267,no. 9, p. 839.
Holba, V., Colloid Polym. Sci., 1989, vol. 267, p. 456.
Wustneck, R., Wustneck, N.R., Hermel, H., and Tsastrov, L., Kolloidn. Zh., 1987, vol. 49,no. 2, p. 244.
Derkach, S.R., Izmailova, V.N., and Zotova, K.V., Zh. Prikl. Khim. (St. Petersburg), 1993, vol. 66,no. 3, p. 627.
Sovilj, V., Colloid Polym. Sci., 1998, vol. 276,no. 4, p. 328.
Muller, D., Malmsten, M., Bergenstahl, B., et al., Langmuir, 1998, vol. 14, p. 3107.
Tavernier, B.H., J. Colloid Interface Sci., 1983, vol. 93, p. 419.
Knox, W.J. and Wright, J.F., J. Colloid Interface Sci., 1965, vol. 20, p. 177.
Knox, W.J. and Parshall, T.D., J. Colloid Interface Sci., 1970, vol. 33,no. 1, p. 16.
Wustneck, R., Tsastrov, L., and Kretzchmar, G., Kolloidn. Zh., 1985, vol. 47,no. 3, p. 462.
Wustneck, R., Warnheim, T, Colloid Polym. Sci., 1988, vol. 266,no. 10, p. 926.
Dreja, M., Heine, K., Tieke, B., and Junkers, G., Colloid Polym. Sci., 1996, vol. 274, p. 1044.
Wustneck, R. and Kretzchmar, G., Kolloidn. Zh., 1987, vol. 49,no. 3, p. 555.
Trapeznikov, A.A. and Vins, V.G., Kolloidn. Zh., 1979, vol. 41,no. 2, p. 392.
Izmailova, V.N., Derkach, S.R., Zotova, K.V., and Danilova, R.G., Kolloidn. Zh., 1993, vol. 55,no. 3, p. 54.
Greener, J., Contestable, B.A., and Bale, M., Macromolecules, 1987, vol. 20, p. 2490.
Arora, J.P.S., Soam, D., Singh, S.P., et al., Tenside Deterg., 1984, vol. 21,no. 2, p. 87.
Arora, J.P.S., Singhal, V.K., Singh, S.P., et al., Ibid, 1984, vol. 21,no. 3, p. 15.
Howe, A.M., Wilkinst, A.G., and Goodwint, J.W., J. Photogr. Sci., 1992, vol. 40, p. 234.
Arora, J.P.S., Pal, C., and Dutt, D., Tenside Deterg., 1991, vol. 28, p. 215.
Howe, A.M., Clarke, A., and Whitesides, T.H., Langmiur, 1997, vol. 13, p. 2617.
Valentini, J.E., Thomas, W.R., Sevenhuysen, P., et al., Ind. Eng. Chem. Res. Dev., 1991, vol. 30, p. 453.
Knox, W.J. and Parshall, T.D., J. Colloid Interface Sci., 1970, vol. 33,no. 1, p. 16.
Kretzschmar, G., Fruhner, H., and Kragel, J., Tenside Surfactants, Deterg., 1993, vol. 30, p. 110.
Kretzschmar, G. and Lunkenheimer, K., Ber. Bunsenges. Phys. Chem., 1970, vol. 74, p. 1064.
Lunkenheimer, K., Hartenstein, C., Miller, R., and Wantke, K.D., Colloids Surf. A, 1984, vol. 8, p. 271.
Avramides, K.S. and Jiang, T.S., J. Colloid Interface Sci., 1991, vol. 147, p. 262.
Fruhner, H. and Wantke, K.D., Colloids Surf. A, 1996, vol. 114, p. 53.
Vollhardt, D., Kretzschmar, G.J., and Signal, L.M., Colloid Polym. Sci., 1976, vol. 4,no. 5, p. 333.
Wustnek, R., Krotov, V., and Ziller, M., Colloid Polym. Sci., 1984, vol. 262,no. 1, p. 67.
Hempt, C., Lunkenheimer, K., and Miller, R., Z. Phys. Chem. (Leipzig), 1985, vol. 266,no. 4, p. 713.
Wustneck, R. and Fruhner, H., Colloid Polym. Sci., 1981, vol. 259, p. 1228.
Fukushima, K., Sugihara, G., Murata, Y., and Tanaka, M., Bull. Chem. Soc. Jpn., 1981, vol. 54, p. 3122.
Wustneck, R., Kretzchmar, G., and Tsastrov, L., Kolloidn. Zh., 1987, vol. 49,no. 2, p. 239.
Wustneck, R., Colloid Polym. Sci., 1984, vol. 2662, p. 821.
Wustneck, R. and Kragel, J., in Proteins at Liquid Interfaces, Mebius, D. and Miller, R., Eds., Amsterdam: Elsevier, 1998, vol. 7, p. 433.
Raab, A., Porschke, R., and Gareis, H., Imaging Sci. J., 1997, vol. 45,no. 3/4, p. 220.
Fruhner, H. and Kretzschmar, G., Colloid Polym. Sci., 1992, vol. 270, p. 177.
Birch, B.J., Clarke, D.E., Lee, R.S., and Oakes, J., Anal. Chim. Acta, 1974, vol. 70, p. 417.
Fukushima, K., Murata, Y., Sugihara, G., and Tanaka, M., Bull. Chem. Soc. Jpn., 1982, vol. 55, p. 1376.
Fukushima, K., Sugihara, G., Murata, Y., and Tanaka, M., Bull. Chem. Soc. Jpn., 1982, vol. 55, p. 3113.
Mittal, K.L. and Fendler, E.J., Solution Behavior of Surfactants, Mittal, K.L. and Lindmann, B., Eds., New York: Plenum, vol. 1, 1983.
Hayakawa, K., Ayub, A.L., and Kawa, J.C.T., Colloids Surf., 1982, vol. 4, p. 389.
Arora, J.P.S., Singh, S.P., and Singhal, V.K., Tenside Deterg., 1984, vol. 21, p. 197.
Isemura, T., Tokiva, F., and Ikeda, S., Bull. Chem. Soc. Jpn., 1962, vol. 35, p. 240.
Whitesides, T.H. and Miller, D.D., Langmuir, 1994, vol. 10, p. 2899.
Congrove, T., White, S.J., Zarbakhsh, A., et al., Langmuir, 1995, vol. 11, p. 744.
Congrove, T., White, S.J., Zarbakhsh, A., et al., J. Chem. Soc., Faraday Trans., 1996, vol. 92,no. 4, p. 595.
Heenan, R.K., White, S.J., Cosgrove, T., et al., Prog. Colloid Polym. Sci., 1994, vol. 97, p. 316.
Maity, S., Jena, S.S., Pradhan, A., and Bohidar, H.B., Colloid Polym. Sci., 1998, vol. 276,no. 7, p. 666.
Miller, D.D., Lenhart, W., Antalek, B.J., et al., Langmuir, 1994, vol. 10,no. 1, p. 68.
Griffiths, P.C., Stilbs, P., Howe, A.M., and Cosgrove, T., Langmuir, 1996, vol. 12, p. 2884.
Klenin, V.I., Shchegolev, S.Yu., and Lavrushin, V.I., Kharakteristicheskie funktsii svetorasseyaniya dispersnykh sistem (Characteristic Functions of Light Scattering from Disperse Systems), Saratov, 1977, p. 176.
Goddard, E.D., Colloids Surf. A, 1986, vol. 19, p. 255.
Rusanov, A.I. and Prokhorov, V.A., Mezhfaznaya tenziometriya (Interfacial Tensiometry), St. Petersburg: Khimiya, 1994.
Wustneck, R. and Warnheim, T., Colloid Polym. Sci., 1988, vol. 266,no. 10, p. 926.
Poverkhnostno-aktivnye veshchestva. Spravochnik (Handbook on Surfactants), Abramzon, A.A. and Gaevoi, G.M., Eds., Leningrad: Khimiya, 1979.
Izmailova, V.N., Derkach, S.R., Levachev, S.M., et al., Kolloidn. Zh., 1997, vol. 59,no. 2, p. 174.
Pitt, A.R., Morley, S.D., Burbidge, N.J., and Quickenden, E., Colloids Surf. A, 1996, vol. 114, p. 321.
Meguro, K., Kanbe, T., and Esumi, K., J. Am. Oil Chem. Soc., 1983, vol. 60, p. 1050.
Vinetsky, Y. and Magdassi, S., Colloid Polym. Sci., 1998, vol. 276,no. 5, p. 395.
Swalen, J.D., Surfactants in Solutions, 1991, vol. 11, p. 41.
Jackson M. and Mantsch H.H., Spectrochim. Acta Rev., 1993, vol. 15, p. 53.
Delhaye, M., Dupelrat, M., and Levy, Y., J. Raman Spectrosc., 1979, vol. 8,no. 6, p. 351.
Kiselyova, O.I. and Yaminskii, I.V., Kolloidn. Zh., 1999, vol. 61,no. 1, p. 5.
Gunning, A.P., Wilde, P.J., Clark, D.C., et al., J. Colloid Interface Sci., 1996, vol. 183, p. 600.
Haugstad, G., Gladfelter, W.L., and Jones, R.R., Langmuir, 1998, vol. 14, p. 3944.
Izmailova, V.N., Tarasevich, B.N., Busol, T.F., and Pis'mennaya, G.M., Kolloidn. Zh., 1977, vol. 39,no. 5, p. 958.
Moiseev, Yu.V., Borovkova, N.K., and Tsepalova, N.A., Vysokomol. Soedin., Ser. B, 1977, vol. 19,no. 1, p. 3.
Harrick, N.J., Internal Reflection Spectroscopy, New York: Wiley, 1967. Translated under the title Spektroskopiya vnutrennego otrazheniya, Moscow: Mir, 1970, p. 335.
Tarasevich, B.N., Busol, T.F., Pshenitsin, V.I., and Izmailova, V.N., Vysokomol. Soedin., Ser. A, 1984, vol. 26,no. 5, p. 1106.
Busol, T.F., The Study of Interfacial Adsorption Layers of Gelatin by the Internal Reflectance Spectroscopy, Cand. Sci. (Chem.) Dissertation, Moscow: Moscow State Univ., 1980.
Morozova, L.Z., The Study of Interfacial Adsorption Layers of Globular Proteins by the Internal Reflectance Spectroscopy, Cand. Sci. (Chem.) Dissertation, Moscow: Moscow State Univ., 1986.
Tarasevich, B.N. and Izmailova, V.N., Zh. Nauchn. Prikl. Fotogr., 1997, vol. 42,no. 1, p. 46.
Izmailova, V. N., Tulovskaya, Z.D., Pis'mennaya, G.M., and Rehbinder, P.A., Kolloidn. Zh., 1972, vol. 34, p. 340.
Tarasevich, B.N., Izmailova, V.N., Derkach, S.R., and Petrova, L.A., Zh. Nauchn. Prikl. Fotogr., 1998, vol. 43,no. 3, p. 14.
Wustneck, R. and Muller, H.J., Colloid Polym. Sci., 1986, vol. 267,no. 1, p. 97.
Scheludko, A., Adv. Colloid Interface Sci., 1967, vol. 1, p. 391.
Kruglyakov, P.M. and Exerowa, D.R., Pena i pennye plenki (Foam and Foam Films), Moscow: Khimiya, 1990.
Pavlov, M.Yu. and Fedorov, B.A., Biofizika, 1982, vol. 27,no. 4, p. 609.
Tarasevich, B.N., Morozova, L.Z., Izmailova, V.N., and Novoselova, M.A., Kolloidn. Zh., 1981, vol. 43,no. 6, p. 1191.
Summ, B.D. and Goryunov, Yu.V., Fiziko-khimicheskie osnovy smachivaniya i rastekaniya (Physicochemical Fundamentals of Wetting and Spreading), Moscow: Khimiya, 1976, p. 231.
Summ, B.D., Goryunov, Yu.V., Kiseleva, N.V., et al., Kolloidn. Zh., 1983, vol. 45,no. 6, p. 1162.
Mironyuk, N.B., Busol, T.F., Tarasevich, B.N., et al., Vysokomol. Soedin., Ser. B, 1982, vol. 24, p. 391.
Mironyuk, N.B., Goryunov, Yu.V., Izmailova, V.N., et al., Vestn. Mosk. Univ., Ser. Khim., 1982, vol. 23, p. 241.
Izmailova, V.N. and Yampol'skaya, G.P., in Fiziko-khimicheskaya mekhanika i liofil'nost' dispersnykh sistem (Physicochemical Mechanics and Lyophilicity of Disperse Systems), Kiev: Naukova Dumka, 1979, vol. 11, p. 63.
Alent'ev, A.Yu., Izmailova, V.N., and Yampol'skaya, G.P., Kolloidn. Zh., 1991, vol. 53,no. 4, p. 609.
Levachev, S.M. and Izmailova, V.N., Kolloidn. Zh., 1994, vol. 56,no. 2, p. 193.
Rodin, V.V. and Izmailova, V.N., Kolloidn. Zh., 1994, vol. 56,no. 1, p. 91.
Naryshkina, E.P., Volkov, V.Ya., Dolinnyi, A.I., and Izmailova, V.N., Vysokomol. Soedin., Ser. A, 1982, vol. 24,no. 9, p. 1908.
Rose, P. and Gross, S., J. Photogr. Sci., 1975, vol. 23,no. 2, p. 54.
Pchelin, V.A. Izmailova, V. N., and Ochurova, K.T., Dokl. Akad. Nauk SSSR, 1958, vol. 123,no. 3, p. 505.
Yampol'skaya, G.P., Izmailova, V.N., Pchelin, V.A., and Volynskaya, A.V., Vysokomol. Soedin., 1965, vol. 7,no. 11, p. 1956.
Yampol'skaya, G.P., Izmailova, V.N., and Pchelin, V.A., Vysokomol. Soedin., Ser. A, 1970, vol. 12,no. 9, p. 1923.
Voron'ko, N.G., Derkach, S.R., and Izmailova, V.N., Zh. Nauchn. Prikl. Fotogr., 1999, vol. 44,no. 4, p. 63.
Izmailova, V.N., Yampol'skaya, G.P., and Tulovskaya, Z.D., Kolloidn. Zh., 1998, vol. 60,no. 5, p. 598.
Izmailova, V.N., Yampol'skaya, G.P., Bobrova, L.E., et al., Poverkhnostnye yavleniya i poverkhnostnoaktivnye veshchestva (Surface Phenomena and Surfactants), Abramzon, A.A. and Shchukin, E.D., Eds., Leningrad: Khimiya, 1984, p. 90.
Rehbinder, P.A. and Trapeznikov, A.A., Zh. Fiz. Khim., 1938, vol. 12, p. 573.
Rehbinder, P.A., Novye metody fiziko-khimicheskikh issledovanii poverkhnostnykh yavlenii (Novel Methods of Physicochemical Studies of Surface Phenomena), Moscow: Akad. Nauk SSSR, 1950, p. 5.
Tarasevich, B.N. and Izmailova, V.N., Abstracts of Papers, Int. Conf. on Colloid Chemistry and Physical-Chemical Mechanics, Moscow: Khimich. Fakult., Mosk. Gos. Univ., 1998, p. 205.
Musabekov, K.B., Zhubanov, B.A., Izmailova, V.N., and Summ, B.D., Mezhfaznye sloi polielektrolitov (Interfacial Layers of Polyelectrolytes), Alma-Ata: Nauka, 1987, p. 111.
Derkatch, S.R., Izmailova, V.N., Petrova, L.A., and Danilova, R.G., Abstracts of Papers, Second World Congress on Emulsions, Bordeaux, 1997, vol. 2, p. 231.
Derkatch, S.R., Petrova, L.A., Izmailova, V.N., and Tarasevitch, B.N., Colloids Surf. A, 1999, vol. 152, p. 189.
Derkach, S.R., Izmailova, V.N., Zotova, K.V., and Pyleva, Yu.V., Kolloidn. Zh., 1994, vol. 56,no. 6, p. 751.
Kruglyakov, P.M. and Rovin, Yu.G., Fiziko-khimiya chernykh uglevodorodnykh plenok (Physical Chemistry of Black Hydrocarbon Films), Moscow: Nauka, 1978, p. 183.
El'-Shimi, A.F. and Izmailova, V.N., Kolloidn. Zh., 1967, vol. 29,no. 5, p. 745.
Izmailova, V.N., Gritskova, I.A., Bakharvand, Kh., et al., Kolloidn. Zh., 1997, vol. 59,no. 3, p. 334.
Izmailova, V.N., Gritskova, I.A., Martynova, E.V., et al., Abstracts of Papers, 8 Nauchno-tekhnicheskaya konferentsiya Murmanskogo gosudarstvennogo tekhnicheskogo universiteta (Proc. 8th Scientific and Technical Conf. of Murmansk State Univ.), Murmansk: Murmansk. Gos. Tekh. Univ., 1997, p. 93.
Derkach, S.R., Izmailova, V.N., and Petrova, L.A., Zh. Nauchn. Prikl. Fotogr., 1998, vol. 43,no. 2, p. 40.
Stainsby, G., Nature, 1952, vol. 169,no. 4, p. 662.
Tanaki, K. and Tamamushi, B., Bull. Chem. Soc. Jpn., 1955, vol. 28,no. 8, p. 555.
Graham, D.E. and Phillips, M.C., J. Colloid Interface Sci., 1979, vol. 70,no. 3, p. 415.
Derkatch, S.R., Izmailova, V.N., Petrova, L.A., et al., Abstracts of Papers, Int. Conf. on Colloid Chemistry and Physical-Chemical Mechanics, Moscow: Moscow State Univ., 1998, p. 155.
Izmailova, V.N., Khasanova, R.G., Brainin, L.B., et al., Abstracts of Papers, 7 Vsesoyuznaya konferentsiya po PAV i syr'yu dlya ikh proizvodstva (Proc. 7th All-Union Conf. on Surfactants and Raw Materials for Their Production), Belgorod, 1988, part 2, p. 454.
Khasanova, R.G., Izmailova, V.N., Pereverzentseva, S.P., and Brainin, L.B., Tekhnologiya registriruyushchikh sredstv (Technology of Recording Agents), Moscow: GosNIIkhimfotoproekt, 1989, p. 39.
Zhurkov, S.N. and Tomashevskii, E.B., in Nekotorye problemy prochnosti tverdogo tela (Some Problems of Solid Strength), Moscow: Akad. Nauk SSSR, 1959, p. 68.
Regel', V.R., Slutsker, A.I., and Tomashevskii, E.B., Kineticheskaya priroda prochnosti tverdykh tel (Kinetic Nature of Solid Strength), Moscow: Nauka, 1974.
Izmailova, V.N., Yampol'skaya, G.P., Tulovskaya, Z.D., and Malkova, D.A., Uspekhi kolloidnoi khimii (Advances of Colloid Chemistry), Tashkent: FAN, 1987, p. 147.
Izmailova, V.N., in Progress in Surface and Membrane Science, Cadenhead, D. and Danielli, F.J., Eds., New York: Academic, 1979, vol. 13, p. 143.
Frieberg, S. and Jansson, O., J. Colloid Interface Sci., 1976, vol. 55, p. 614.
Izmailova, V.N., Yampol'skaya, G.P., Pis'mennaya, G.M., and Tulovskaya, Z.D., Fiziko-khimicheskaya mekhanika i liofil'nost' dispersnykh sistem (Physicochemical Mechanics and Lyophilicity of Disperse Systems), Kiev: Naukova Dumka, 1980, vol. 12, p. 56.
Howe, A.M. and Clarke, A., Langmuir, 1997, vol. 13, p. 2617.
Vinetsky, Y. and Magdassi, S., J. Colloid Interface Sci., 1997, vol. 189,no. 1, p. 83.
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Izmailova, V.N., Derkach, S.R., Levachev, S.M. et al. Properties of Interfacial Layers in Multicomponent Systems Containing Gelatin. Colloid Journal 62, 653–675 (2000). https://doi.org/10.1023/A:1026644306369
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DOI: https://doi.org/10.1023/A:1026644306369