Abstract
Emulsions are thermodynamically unstable systems, since they will separate to reduce the interfacial area between the oil phase and the water phase, as a function of time. As a metastable system, surfactant molecules, amphiphilic polymers or solid particles must be present before a stable emulsion system is formed. These components of an emulsion system are called emulsifiers. The relative balance of the hydrophilic and lipophilic properties of these emulsifiers is known to be the most important parameter dictating the emulsion type, whether an oil-in-water (o/w) or water-in-oil (w/o) emulsion. Irrespective of the emulsion type formed, demulsification is a costly exercise in the oil and gas industry. This chapter describes the fundamental role played by surface active agents (surfactants) as integral components of a chemical demulsifier.
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References
Kokal SL (2005) Crude oil emulsions: a state-of-the-art review. SPE Prod Fac 20(01):5–13
Kokal SL, Al Ghamdi A (2006) Oil/water separation experience from a large oil field. SPE Product Oper 21(03):365–371
Langevin D et al (2004) Crude oil emulsion properties and their application to heavy oil transportation. Oil Gas Sci Technol 59(5):511–521
Fingas M, Fieldhouse B (2009) Studies on crude oil and petroleum product emulsions: water resolution and rheology. Colloids Surf A 333(1):67–81
Fingas M, Fieldhouse B (2014) Water-in-oil emulsions: formation and prediction. Spill Sci Technol 225
Becher P (1988) Basic theory, measurement and applications. In: Encyclopedia of emulsion technology, vol 3. Dekker, New York
Sheu EY, Mullins OC (1998) Structures and dynamics of asphaltenes. Plenum Press, pp 337–423
Schramm LL (1992) Petroleum emulsions. ACS Publication
Sjoblom J (2005) Emulsions and emulsion stability: surfactant science series/61-Chp 14, vol 132. CRC Press
Clayton W (1923) The theory of emulsions and emulsification. J. & A. Churchill
Chevalier Y, Bolzinger M-A (2013) Emulsions stabilized with solid nanoparticles: pickering emulsions. Colloids Surf Physicochem Eng Aspects 439:23–34
Abdel-Raouf M (2012) Crude oil emulsions: composition stability and characterization. BoD–Books on Demand
Umar AA et al (2018) A review of petroleum emulsions and recent progress on water-in-crude oil emulsions stabilized by natural surfactants and solids. J Petrol Sci Eng 165:673–690
Umar A, Saaid I, Sulaimon A (2017) The roles of polar compounds in the stability and flow behavior of water-in-oil emulsions. ICIPEG 2016. Springer, pp 643–653
Urdahl O, Sjöblom J (1995) Water-in-crude oil emulsions from the Norwegian continental shelf. A stabilization and destabilization study. J Dispersion Sci Technol 16(7):557–574
Schramm LL (2000) Surfactants: fundamentals and applications in the petroleum industry. In: Surfactants in solutions. Cambridge University Press
Dingcong W (2002) A study of identifying the emulsion type of surfactant: volume balance value. J Colloid Interface Sci 247(2):389–396
Pasquali RC, Sacco N, Bregni C (2009) The studies on hydrophilic–lipophilic balance (HLB): sixty years after William C. Griffin’s pioneer work (1949–2009). Lat Am J Pharm 28(2):313–317
Zafeiri I et al (2017) Emulsions co-stabilised by edible pickering particles and surfactants: the effect of HLB value. Colloid Interface Sci Commun 17:5–9
Surfluh J (1937) Prevention of oil-field emulsions. In: Drilling and production practice. American Petroleum Institute
Powell KC, Damitz R, Chauhan A (2017) Relating emulsion stability to interfacial properties for pharmaceutical emulsions stabilized by Pluronic F68 surfactant. Int J Pharm 521(1):8–18
Alvarado V, Wang X, Moradi M (2011) Stability proxies for water-in-oil emulsions and implications in aqueous-based enhanced oil recovery. Energies 4(7):1058–1086
McClements DJ, Jafari SM (2017) Improving emulsion formation, stability and performance using mixed emulsifiers: a review. Adv Colloid Interface Sci
Kokal S, Wingrove M (2000) Emulsion separation index: from laboratory to field case studies. In: SPE annual technical conference and exhibition. Society of Petroleum Engineers
Kokal S (2002) Crude oil emulsions: a state-of-the-art review. In: SPE annual technical conference and exhibition. Society of Petroleum Engineers
Jones T, Neustadter E, Whittingham K (1978) Water-in-crude oil emulsion stability and emulsion destabilization by chemical demulsifiers. J Can Petrol Technol 17(02)
Strassner J (1968) Effect of pH on interfacial films and stability of crude oil-water emulsions. J Petrol Technol 20(03):303–312
Moroney JR, Berg MD (1999) An integrated model of oil production. Energy J 20(1)
Umar AA et al (2020) Magnetic polyester bis-MPA dendron nanohybrid demulsifier can effectively break water-in-crude oil emulsions. J Market Res 9(6):13411–13424
Kim Y-H, Wasan D, Breen P (1995) A study of dynamic interfacial mechanisms for demulsification of water-in-oil emulsions. J Colloids Surf A Physicochem Eng Aspects 95(2–3):235–247
Gafonova OV, Yarranton HW (2001) The stabilization of water-in-hydrocarbon emulsions by asphaltenes and resins. J Colloid Interface Sci 241(2):469–478
Myers D (1990) Surfaces, interfaces and colloids. Wiley-Vch, New York etc.
Thompson D, Taylor A, Graham D (1985) Emulsification and demulsification related to crude oil production. Colloids Surf 15:175–189
Manning FS, Thompson RE (1991) Oilfield processing of petroleum: natural gas, vol 1. Pennwell books
Feng X et al (2009) Mechanistic study on demulsification of water-in-diluted bitumen emulsions by ethylcellulose. Langmuir 26(5):3050–3057
Meyer P (1964) Chemelectric treating a new phase in the electrical dehydration of oil emulsions. In: SPE production automation symposium. Society of Petroleum Engineers, Kansas
Schramm LL (2014) Emulsions, foams, suspensions, and aerosols: microscience and applications. Wiley
Monson T (1969) Chemical resolution of emulsions. In: Surface operations in petroleum production, II. Elsevier
Becker J (1997) Crude oil waxes, emulsions, and asphaltenes. Pennwell Books
Merchant Jr P, Lacy SM (1988) Water based demulsifier formulation and process for its use in dewatering and desalting crude hydrocarbon oils. Google Patents
Kim YH, Wasan DT (1996) Effect of demulsifier partitioning on the destabilization of water-in-oil emulsions. Ind Eng Chem Res 35(4):1141–1149
Abdel-Azim AAA , Zaki NN, Maysour NES (1998) Polyoxyalkylenated amines for breaking water-in-oil emulsions: effect of structural variations on the demulsification efficiency. Polym Adv Technol 9(2):159–166
Dalmazzone C, Noïk C (2001) Development of new” green” demulsifiers for oil production. In: SPE international symposium on oilfield chemistry. Society of Petroleum Engineers
Dalmazzone C, Noik C, Komunjer L (2005) Mechanism of crude-oil/water interface destabilization by silicone demulsifiers. SPE J 10(01):44–53
Darling DF (1982) Recent advances in the destabilization of dairy emulsions. J Dairy Res 49(4):695–712
Mat H et al (2005) Study on demulsifier formulation for treating Malaysian crude oil emulsion
Sjoblom J (2001) Encyclopedic handbook of emulsion technology. CRC Press
Salager J-L (1990) The fundamental basis for the action of a chemical dehydrant. Influence of the physical and chemical formulation on the stability of an emulsion. Int Chem Eng 30(1):103–116
Salager J-L (2002) Surfactants types and uses. FIRP booklet, (E300A)
Schramm LL, Stasiuk EN, Marangoni DG (2003) 2 Surfactants and their applications. Annu Rep Sect “C” (Phys Chem) 99:3–48
Migahed M, Al-Sabagh A (2009) Beneficial role of surfactants as corrosion inhibitors in petroleum industry: a review article. Chem Eng Commun 196(9):1054–1075
Fingas M (2014) Handbook of oil spill science and technology, vol 1. Wiley
Shehzad F, Hussein IA, Kamal MS, Ahmad W, Sultan AS, Nasser MS (2018) Polymeric surfactants and emerging alternatives used in the demulsification of produced water: a review. Polym Rev 58(1):63–101
Maurice S, Ken A (2008) Emulsions and oil treating equipment. Gulf Professional Publishing, Hardbound
Li Y et al (2017) A versatile and efficient approach to separate both surfactant-stabilized water-in-oil and oil-in-water emulsions. Sep Purif Technol 176:1–7
Bhardwaj A, Hartland S (1994) Kinetics of coalescence of water droplets in water-in-crude oil emulsions. J Dispers Sci Technol 15(2):133–146
Kelland MA (2014) Production chemicals for the oil and gas industry. CRC press
Zhang Z, Xu G, Wang F, Dong S, Chen Y (2005) Demulsification by amphiphilic dendrimer copolymers. J Colloid Interface Sci 282(1–4)
Wang J, Li C-Q, Li J, Yang J-Z (2007) Demulsification of crude oil emulsion using polyamidoamine dendrimers. Sep Sci Technol 42(9):2111–2120
Wang J, Hu F-L, Li C-Q, Li J, Yang Y (2010) Synthesis of dendritic polyether surfactants for demulsification. Sep Purif Technol 73(3):349–354
Fink J (2015) Petroleum engineer's guide to oil field chemicals and fluids Gulf Professional Publishing, Chp 23, p 705
Matijevic E, Good RJ (2012) Surface and colloid science, vol 12. Springer Science & Business Media
Sjöblom J (2012) Emulsions: a fundamental and practical approach, vol 363. Springer Science & Business Media
Angle CW (2001) Chemical demulsification of stable crude oil and bitumen emulsions in petroleum recovery—a review. Marcel Dekker, New York, pp 541–594
Hanapi B et al (2006) Study on demulsifier formulation for treating Malaysian crude oil emulsion. Internet website. http://eprints.utm.my/2768/1/74004.pdf
Fink J (2003) Oil field chemicals. Elsevier
Al-Sabagh AM et al (2013) Synthesis and evaluation of new demulsifiers incorporating linear alkyl benzene moiety for treating water-in-oil emulsion. J Dispers Sci Technol 34(7):996–1007
Barnickel WS (1922) Apparatus for treating natural emulsions of petroleum. Google Patents
Mansur CR et al (2004) PLURONIC× TETRONIC polyols: study of their properties and performance in the destabilization of emulsions formed in the petroleum industry. J Colloid Interface Sci 271(1):232–240
Alvarez F et al (2011) Dissipative particle dynamics (DPD) study of crude oil− water emulsions in the presence of a functionalized co-polymer. Energy Fuels 25(2):562–567
Beyer J et al (2001) Ecotoxicology of oilfield chemicals: the relevance of evaluating low-dose and long-term impact on fish and invertebrates in marine recipients. In: SPE international symposium on oilfield chemistry. Society of Petroleum Engineers
Al-Sabagh AM, Kandile NG, Noor El-Din MR (2011) Functions of demulsifiers in the petroleum industry. Sep Sci Technol 46(7):1144–1163
Ali N et al (2014) Synthesis of P (MMA-co-AA-co-DVB) Fe 3 O 4/magnetic composite nanoparticles. In: Proceedings of 2014 11th international Bhurban conference on applied sciences & technology (IBCAST). IEEE, Islamabad, Pakistan
Reeve PFD (2002) Method of inhibiting the formation of oil and water emulsions. Google Patents
Peña AA, Hirasaki GJ, Miller CA (2005) Chemically induced destabilization of water-in-crude oil emulsions. Ind Eng Chem Res 44(5):1139–1149
Feng X et al (2008) Biodegradable polymer for demulsification of water-in-bitumen emulsions. Energy Fuels 23(1):451–456
Killat GR, Conklin JR (1984) Use of quaternized polyamidoamines as demulsifiers. Google Patents
Conklin JR, Wilson LR (1984) Use of heterocyclic ammonium polyamidoamines as demulsifiers. Google Patent
Yang M, Stewart A, Davies G (1996) Interactions between chemical additives and their effects on emulsion separation. In: SPE annual technical conference and exhibition. Society of Petroleum Engineers
Pensini E et al (2014) Demulsification mechanism of asphaltene-stabilized water-in-oil emulsions by a polymeric ethylene oxide–propylene oxide demulsifier. J Energy Fuels 28(11):6760–6771
Nurainia M, Abdurahmanab H, Kholijaha A (2011) Effect of chemical breaking agents on water-in-crude oil emulsion system. Int J 2(4)
Madaan V et al (2014) Emulsion technology and recent trends in emulsion applications. Int Res J Pharm 5(7):533–542
McMahon AJ (1992) Interfacial aspects of water-in-crude oil emulsion stability. Emulsions—a fundamental and practical approach. Springer, pp 135–156
Manousakis M, Avranas A (2013) Dynamic surface tension studies of mixtures of hydroxypropylmethylcellulose with the double chain cationic surfactants didodecyldimethylammonium bromide and ditetradecyldimethylammonium bromide. J Colloid Interface Sci 402:237–245
Fink J (2015) Petroleum engineer’s guide to oil field chemicals and fluids. Gulf Professional Publishing. GPP
Müller FH, Weiss A (2007) Emulsions, vol 63. Steinkopff
Krawczyk MA, Wasan DT, Shetty CJI (1991) Chemical demulsification of petroleum emulsions using oil-soluble demulsifiers. J Indus Eng Chem Res 30(2):367–375
Kang W et al (2006) Influence of demulsifier on interfacial film between oil and water. J Colloids Surf A Physicochem Eng Aspects 272(1–2):27–31
Pensini E et al (2014) Demulsification mechanism of asphaltene-stabilized water-in-oil emulsions by a polymeric ethylene oxide–propylene oxide demulsifier. Energy Fuels 28(11):6760–6771
Hunter TN et al (2008) The role of particles in stabilising foams and emulsions. Adv Coll Interface Sci 137(2):57–81
Kilpatrick PK (2012) Water-in-crude oil emulsion stabilization: review and unanswered questions. Energy Fuels 26(7):4017–4026
Bhardwaj A, Hartland S (1993) Study of demulsification of water-in-crude oil emulsion. J Dispers Sci Technol 14(5):541–557
Farn RJ (2008) Chemistry and technology of surfactants. Wiley
Akther S, Hwang J-Y, Lee H-M (2007) Effects of the water quality on the dispersion properties of bentonites used for drilling fluid. J Mineral Soc Korea 20(1):21–33
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Umar, A.A., Nnakenyi, N.I., Abba, M.K., Roy-Omeni, I.H. (2021). Surfactants as Integral Components of Chemical Demulsifiers. In: Solling, T., Shahzad Kamal, M., Shakil Hussain, S.M. (eds) Surfactants in Upstream E&P. Petroleum Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-70026-3_16
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