Abstract
Radical copolymerization of N-vinylsuccinimide with n-butyl acrylate in pyridine and the influence of donor characteristics of the solvent on the reaction kinetics were studied. The kinetics of copolymerization in various solvents (dichloroethane, dimethyl sulfoxide, and pyridine) were studied.
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Kabanov, V.A., Zubov, V.P., and Semchikov, Yu.D., Kompleksoradikal'naya polimerizatsiya (Complex-Radical Polymerization), Moscow: Khimiya, 1987.
Ivanchev, S.S., Radikal'naya polimerizatsiya (Radical Polymerization), Leningrad: Khimiya, 1985.
Lavrov, N.A., Sivtsov, E.V., and Nikolaev, A.F., Reaktsionnaya sreda i kinetika polimerizatsionnykh protsessov (Reaction Medium and Kinetics of Polymerization Processes), St. Petersburg: Sintez, 2001.
Shal'nova, L.I., Chudnova, V.M., and Trofimova, E.A., Plast. Massy, 1989, no. 11, pp. 29-34.
Lavrov, N.A., Shal'nova, L.I., and Nikolaev, A.F., Plast. Massy, 2001, no. 10, pp. 5-9.
Lavrov, N.A., Sivtsov, E.V., and Nikolaev, A.F., Plast. Massy, 2001, no. 10, pp. 43-45.
Reichardt, C., Solvents and Solvent Effects in Organic Chemistry, Weinheim: VCH, 1988.
Bondarenko, S.G., Nikolaev, A.F., Baranova, S.A., et al., Vysokomol. Soedin., Ser. A, 1981, vol. 23, no. 12, pp. 2639-2651.
Sivtsov, E.V., Lavrov, N.A., and Nikolaev, A.F., Plast. Massy, 2001, no. 10, pp. 20-25.
Lavrov, N.A., Sivtsov, E.V., and Nikolaev, A.F., Zh. Prikl. Khim., 1998, vol. 71, no. 12, pp. 2055-2056.
Ezrielev, A.I., Brokhina, E.L., and Roskin, E.S., Vysokomol. Soedin., Ser. A, 1969, vol. 11, no. 8, pp. 1670-1680.
Kelen, T. and Tüdös F., J. Macromol. Sci., Ser. A, 1979, vol. 9, no. 1, pp. 1-27.
Lavrov, N.A. and Dracheva, O.A., Raschet kineticheskikh parametrov radikal'noi polimerizatsii i sopolimerizatsii s ispol'zovaniem EVM: Metodicheskie ukazaniya (Computer Evaluation of Kinetic Parameters of Radical Polymerization and Copolymerization: Methodical Instructions), St. Petersburg: Sankt-Peterburg. Gos. Tekhnol. Inst., 1995.
Nikolaev, A.F., Bondarenko, V.M., and Lopukhinskii, L.M., Sopolimerizatsiya N-vinilsuktsinimida s butilakrilatom (Copolymerization of N-Vinylsuccinimide with Butyl Acrylate), Available from VINITI, November 17, 1975, no. 3271-75.
Glushchenok, I.N., Universal'nyi metod rascheta konstant sopolimerizatsii: Uchebnoe posobie (Universal Method of Evaluation of Copolymerization Constants: A Manual), Leningrad: Leningr. Tekhnol. Inst., 1975.
Gindin, L.M., Abkin, A.D., and Medvedev, S.S., Dokl. Akad. Nauk SSSR, 1947, vol. 56, no. 2, pp. 177-180.
Gindin, L.M., Abkin, A.D., and Medvedev, S.S., Zh. Fiz. Khim., 1947, vol. 21, no. 11, pp. 1269-1287.
Lavrov, N.A., Raschet cheredovaniya zven'ev v sopolimerakh: Metodicheskie ukazaniya (Calculation of Alternation of Chains in Copolymers: Methodical Instructions), Leningrad: Leningr. Tekhnol. Inst., 1988.
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Lavrov, N.A., Sivtsov, E.V. & Pisarev, A.G. Influence of the Reaction Medium on the Kinetics of Copolymerization of N-Vinylsuccinimide with Butyl Acrylate. Russian Journal of Applied Chemistry 76, 1121–1126 (2003). https://doi.org/10.1023/A:1026370614604
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DOI: https://doi.org/10.1023/A:1026370614604