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Chemical and Electrochemical Behavior of Gallium in the Room-Temperature Ionic Liquid of the Composition [C6H11N2][N(SO2CF3)2]

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Abstract

The behavior of gallium trichloride in the room-temperature ionic liquid of the composition [C6H11N2][N(SO2CF3)2] at 298-308 K in an inert gas atmosphere was studied by linear and cyclic voltammetry and spectrophotometry. The reduction and oxidation potentials of gallium were determined. Assumptions concerning the composition of the gallium complex species were made.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russia

    V. V. Smolenskii & A. L. Bove

  2. Institute of Metallurgy, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russia

    A. A. Khokhryakov

  3. Research Institute of Atomic Reactors, Russian Federation State Scientific Center, Dimitrovgrad, Ul'yanovsk oblast, Russia

    A. G. Osipenko

Authors
  1. V. V. Smolenskii
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  2. A. L. Bove
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  3. A. A. Khokhryakov
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  4. A. G. Osipenko
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Smolenskii, V.V., Bove, A.L., Khokhryakov, A.A. et al. Chemical and Electrochemical Behavior of Gallium in the Room-Temperature Ionic Liquid of the Composition [C6H11N2][N(SO2CF3)2]. Radiochemistry 45, 499–502 (2003). https://doi.org/10.1023/A:1026220211491

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