Abstract
The interaction of Au(En)2 3+ with the chloride ion in an aqueous solution at I = 2.5 mol/l and T = 20°C was studied by spectrophotometry. The equilibrium constant of formation of the Au(En)2Cl2+ penta coordinated complex was determined.
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Adams, H.-N. and Strahle, J., Z. Anorg. Allg. Chem., 1982, vol. 485, no. 2, p.65.
Marangoni, G., Pitteri, B., and Bertolasi, V., et al., J. Chem. Soc., Dalton Trans., 1986, no. 9, p. 1941.
Minacheva, L.Kh., Gladkaya, A.Sh., Sakharova, V.G., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 3, p. 683.
Makotchenko, E.V. and Novoselov, R.I., Blagorodnye metally: khimiya i analiz. Sb. Nauchn. tr. In-ta neorgan. khimii SO AN SSSR (Noble Metals: Chemistry and Analysis. Collection of Scientific Works of the Institute of Inorganic Chemistry, Siberian Branch of the USSR Academy of Sciences), Novosibirsk, 1989, p. 112.
Tatarchuk, V.V., Kostin, G.A., and Torgov, V.G., Zh. Neorg. Khim., 1998, vol. 43, no. 2, p. 348.
Belevantsev, V.I., Pastukhov, A.A., Makotchenko, E.V., and Novoselov, R.I., Koord. Khim., 1982, vol. 8, no. 3, p. 297.
Makotchenko, E.V., Malkova, V.I., and Belevantsev, V.I., Koord. Khim., 1999, vol. 25, no. 4, p. 302.
Don, G.M., Fedotov, M.A., Golovaneva, I.F., and Gladkaya, A.Sh., Zh. Neorg. Khim., 1994, vol. 39, no. 1, p. 135.
Golovaneva, I.F., Don, G.M., and Gladkaya, A.Sh., Izv. Akad. Nauk SSSR, Ser. Khim., 1989, no. 3, p. 570.
Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974, p. 287.
Gladkaya, A.Sh., Evstaf'eva, O.N., and Salyn', Ya.V., Koord. Khim., 1984, vol. 10, no. 6, p. 801.
Mironov, I.V. and Tsvelodub, L.D., Zh. Neorg. Khim., 2000, vol. 45, no. 3, p. 425.
Sadofeev, I.G. and Mironov, I.V., Ber. Bunsen-Ges. Phys. Chem., 1998, vol. 102, no. 1, p. 32.
Block, B.P. and Bailar, J.C., J. Am. Chem. Soc., 1951, vol. 73, no. 10, p. 4722.
Belevantsev, V.I. and Peshchevitskii, B.I., Issledovanie slozhnykh ravnovesii v rastvore (Study of Complex Equilibria in Solutions), Novosibirsk: Nauka, 1978, p. 130.
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Makotchenko, E.V. Spectrophotometric Study of Complexation of Bis(ethylenediamine)gold(III) with the Chloride Ion in an Aqueous Solution. Russian Journal of Coordination Chemistry 29, 720–724 (2003). https://doi.org/10.1023/A:1026028201264
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DOI: https://doi.org/10.1023/A:1026028201264