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Solubility and Complexation in the Series of Compounds of Alkaline-Earth and Alkali Metals

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Abstract

The solubility of salts with alkali and alkaline-earth metal cations and its dependence on the anion radius were discussed. The theoretical results were confirmed by experimental data on solubility. The stability of complexes in the Mg2+–Ba2+ series was considered depending on the ligand charge and radius. The revealed tendencies were explained in terms of the competition between solvent and ligand in solution for a central ion.

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Vasil'ev, V.P. Solubility and Complexation in the Series of Compounds of Alkaline-Earth and Alkali Metals. Russian Journal of Coordination Chemistry 29, 669–674 (2003). https://doi.org/10.1023/A:1026011830397

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  • DOI: https://doi.org/10.1023/A:1026011830397

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