Abstract
A mechanism of SO2 chemisorption by aqueous solutions of carbamide was suggested. The effective rate constants of accumulation of hydrogen ions in the reaction of sulfur dioxide with aqueous solutions of carbamide in the range 278-313 K were determined.
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Pai, Z.P., Khim. Interes. Ustoich. Razv., 1998, no. 6, pp. 367-374.
Khoma, R.E., Nikitin, V.I., and Gavrilenko, M.I., Visn. Odes. Nats. Univ., 2000, vol. 5, no. 5, pp. 39-44.
Huss, A.J. and Eckert, C.A., J. Phys. Chem., 1977, vol. 81, no. 24, pp. 2268-2270.
Romanenko, S.A., Component Composition of Aqueous Solutions of Sulfur(IV), Cand. Sci. Dissertation, Leningrad, 1986.
Pereda, S., Thomsen, K., and Rasmussen, P., Chem. Eng. Sci., 2000, vol. 55, pp. 2663-2671.
Labutin, N.A., Batikha, M.M., Groshev, G.L. and Korotaevskii, K.N., Khim. Khim. Tekhnol., 1997, vol. 40, no. 4, pp. 55-58.
Blokhin, P.V., Recovery of Sulfur Dioxide from Gas Discharges with Amine-containing Industrial Waste, Cand. Sci. Dissertation, Nizhni Novgorod, 2000.
Postnikova, I.N., Recovery of Sulfur Dioxide from Waste Gases with Melamine-based Polymers, Cand. Sci. Dissertation, Ivanovo, 1996.
Pavlova, I.V., Recovery of Sulfur Dioxide from Waste Gases with a Sorbent Based on Carbamidoformaldehyde Resin, Cand. Sci. Dissertation, Nizhni Novgorod, 1995.
Okhotnikova, A.P., Kostoglod, A.B., Astrelin, I.N., and Knyazev, Yu.V., Sbornik nauchnykh trudov Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Sovremennye problemy khimicheskoi tekhnologii neorganicheskikh veshchestv,” Ukraina, Odessa, 2001 (Proc. Int. Sci.-Technol. Conf. “Modern Problems of Chemical Technology of Inorganic Substances,” Ukraine, Odessa 2001), vol. 2, pp. 156-159.
Petrovskii, V.E. and Beznosik, Yu A., Sbornik nauchnykh trudov Mezhdunarodnoi nauchno-tekhnicheskoi konferentsii “Sovremennye problemy khimicheskoi tekhnologii neorganicheskikh veshchestv,” Ukraina, Odessa, 2001 (Proc. Int. Sci.-Technol. Conf. “Modern Problems of Chemical Technology of Inorganic Substances,” Ukraine, Odessa, 2001), vol. 2, pp. 165-167.
Zotov, A.T., Mochevina (Urea), Moscow: Goskhimizdat, 1963.
Kaminskaia, N.V. and Kostié, N.M., Inorg. Chem., 1997, vol. 36, no. 25, pp. 5917-5996.
Nikitin, V.I, Khoma, R.E., and Gavrilenko, M.I., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2000, vol. 43, no. 2, pp. 14-16.
Khoma, R.E., Nikitin, V.I., and Gavrilenko, M.I., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, vol. 44, no. 6, pp. 24-27.
Adelman, R.L., J. Org. Chem., 1964, vol. 29, no. 7, pp. 1837-1844.
Albert, A. and Serjeant, E., Ionization Constants of Acids and Bases, A laboratory manuel, New York: Wiley, 1962.
Crocker, C.L., Am. J. Med. Technol., 1967, vol. 33, p. 361.
Voskresenskii, P.I., Tekhnika laboratornykh rabot (Methods of Laboratory Works), Moscow: Khimiya, 1973.
Kel'man, F.N., Brutskus, E.B, and Osherovich, R.Kh., Metody analiza pri kontrole proizvodstva sernoi kisloty i fosfornykh udobrenii (Analytical Techniques in Control over Production of Sulfuric Acids and Phosphorus Fertilizers), Moscow: Khimiya, 1965.
Klimova, V.A., Osnovnye metody analiza organicheskikh soedinenii (Basic Methods for Analysis of Organic Compounds), Moscow: Khimiya, 1975.
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Khoma, R.E., Nikitin, V.I. & Gavrilenko, M.I. On Reaction of Sulfur Dioxide with Aqueous Solutions of Carbamide. Russian Journal of Applied Chemistry 76, 513–517 (2003). https://doi.org/10.1023/A:1025750112127
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DOI: https://doi.org/10.1023/A:1025750112127