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Synthesis, Characterization and Catalytic Activities of Mesoporous AlMSU-X with Wormhole-Like Framework Structure

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Abstract

Mesoporous AlMSU-X molecular sieves with high acidity have been prepared from preformed beta nanoclusters under strong acidic conditions in the presence of nonionic TX-100 as structure directors. These materials were characterized by XRD, HRTEM, N2-adsorption, 27Al MAS NMR, NH3-TPD, IR-pyridine adsorption and catalytic cracking of cumene and 1,3,5-triisopropylbenzene. The experimental results showed that Al heteroatoms had been successfully incorporated into the framework structure of mesoporous MSU-X, and so-produced catalysts exhibited superior catalytic properties.

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Correspondence to Yu-Han Sun.

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Zhai, SR., Wei, W., Wu, D. et al. Synthesis, Characterization and Catalytic Activities of Mesoporous AlMSU-X with Wormhole-Like Framework Structure. Catalysis Letters 89, 261–267 (2003). https://doi.org/10.1023/A:1025718932695

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