Abstract
Mesoporous AlMSU-X molecular sieves with high acidity have been prepared from preformed beta nanoclusters under strong acidic conditions in the presence of nonionic TX-100 as structure directors. These materials were characterized by XRD, HRTEM, N2-adsorption, 27Al MAS NMR, NH3-TPD, IR-pyridine adsorption and catalytic cracking of cumene and 1,3,5-triisopropylbenzene. The experimental results showed that Al heteroatoms had been successfully incorporated into the framework structure of mesoporous MSU-X, and so-produced catalysts exhibited superior catalytic properties.
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A. Karlsson, M. Stocker and R. Schmidt, Microporous Mesoporous Mater. 27 (1999) 181.
M. J. Verhoef, P. J. Kooyman, J. C. van der Waal, M. S. Rigutto, J. A. Peters and H. van Beckkum, Chem. Mater. 13 (2001) 683.
D. T. On and S. Kaliaguine, Angew. Chem. Int. Ed. 40 (2001) 3248.
D. T. On and S. Kaliaguine, J. Am. Chem. Soc. 125 (2003) 618.
Y. Liu, W. Zhang and T. J. Pinnavaia, Angew. Chem., Int. Ed. 40 (2001) 1255.
Z. Zhang, Y. Han, L. Zhu, R. Wang, Y. Yu, S. Qiu, D. Zhao and F. Xiao, Angew. Chem., Int. Ed. 40 (2001) 1258.
J. Agundez, I. Diaz, C. M. Alvarez, J. P. Pariente and E. Sastre, J. Chem. Soc., Chem. Commun. (2003) 150.
Y. Liu, W. Zhang and T. J. Pinnavaia, J. Am. Chem. Soc. 122 (2000) 8791.
Y. Han, F. Xiao, S. Wu, Y. Sun, X. Meng, D. Li, S. Lin, F. Deng and X. Ai, J. Phys. Chem., B105 (2001) 7963.
Y. Liu and T. J. Pinnavaia, Chem. Mater. 14 (2002) 3.
Y. Han, S. Wu, Y. Sun, D. Li and F. Xiao, Chem. Mater. 14 (2002) 1144.
P. Shih, H. Lin and C. Mou, 3rd International Mesostructured Materials Symposium, Korea (2002) p. 10.
S. A. Bagshaw, E. Prouzel and T. J. Pinnavaia, Science 269 (1995) 1242.
S. S. Kim, T. R. Pauly and T. J. Pinnavia, J. Chem. Soc., Chem. Commun. (2000) 835.
D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka and G. D. Stucky, Science 279 (1998) 548.
D. Zhao, C. Nie, Y. Zhou, S. Xia, L. Huang and Q. Li, Catal. Today 68 (2001) 11.
Z. Luan, M. Hartmann, D. Zhao, W. Zhou and L. Kevan, Chem. Mater. 11 (1999) 1621.
S. Bagshaw, T. Kemmitt and N. Milestone, Microporous Mesoporous Mater. 22 (1998) 419.
B. Chakraborty, B. Viswanathan, Catal. Today 49 (1999) 253.
L. Zhu, F. Xiao, Z. Zhang, Y. Sun, Y. Han and S. Qiu, Catal. Today 68 (2001) 209.
H. Koch and W. Reschetilowski, Microporous Mesoporous Mater. 25 (1998) 127.
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Zhai, SR., Wei, W., Wu, D. et al. Synthesis, Characterization and Catalytic Activities of Mesoporous AlMSU-X with Wormhole-Like Framework Structure. Catalysis Letters 89, 261–267 (2003). https://doi.org/10.1023/A:1025718932695
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DOI: https://doi.org/10.1023/A:1025718932695