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Polymerization of pyrrole with 4-hydroxybenzaldehyde over Al-MCM-41 mesoporous aluminosilicate materials

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Abstract

Mesoporous MCM-41 materials containing aluminum with different Si/Al ratios (20, 40, and 80) were synthesized under hydrothermal condition. The materials were characterized using X-ray diffraction (XRD), nitrogen adsorption, Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), energy-dispersive x-ray (EDX), transmission electron microscopy (TEM), and NH3 temperature programmed desorption (TPD) techniques. Incorporation of aluminum into MCM-41-type silica leads to creation of active and selective catalysts for condensation of pyrrole with 4-hydroxybenzaldehyde. The reaction was carried out at room temperature whilst stirring at 500 rpm. The catalyst Al-MCM-41 with Si/Al ratio of 20 produced a very high yield of [(pyrrole-2,5-diyl)-co-(benzylidene)]. The catalyst could be easily separated from the polymer product and regenerated by calcination.

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Authors and Affiliations

  1. Laboratoire de Chimie des Polymères, Université d’Oran, BP 1524, El-Mnaouer, 31000, Oran, Algeria

    Karim Chikh, Larbi Bouhadjar, Rachid Meghabar & Mohamed Belbachir

  2. Laboratoire de Chimie des Matériaux (LCM), Université d’Oran, BP 1524, El-Mnaouer, 31000, Oran, Algeria

    Bouhadjar Boukoussa, Rachida Hamacha & Abdelkader Bengueddach

  3. Laboratoire de Chimie des Matériaux et applications, Université des sciences et de la technologie (USTO), BP 1505, El-Mnaouer, 31000, Oran, Algeria

    Mohamed Bencheikh

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  1. Karim Chikh
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  2. Bouhadjar Boukoussa
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Chikh, K., Boukoussa, B., Bouhadjar, L. et al. Polymerization of pyrrole with 4-hydroxybenzaldehyde over Al-MCM-41 mesoporous aluminosilicate materials. Res Chem Intermed 41, 6485–6496 (2015). https://doi.org/10.1007/s11164-014-1755-x

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  • DOI: https://doi.org/10.1007/s11164-014-1755-x

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