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Organoantimony Derivatives of 2,4,6-Tribromophenol

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Abstract

2,4,6-Tribromophenoxytetraphenylantimony was prepared in 93% yield by the reaction of pentaphenylantimony with bis(2,4,6-tribromophenoxy)triphenylantimony Ph3Sb(OC6H2Br3-2,4,6)2 in toluene at 90°C (1 h). Bis(2,4,6-tribromophenoxy)triphenylantimony, in turn, was prepared by oxidation of triphenyl- stibine with hydrogen peroxide in the presence of 2,4,6-tribromophenol in ether at 20°C (12 h) in 47% yield, with the second reaction product being μ-oxobis[(2,4,6-tribromophenoxy)triphenylantimony] in which the antimony atom, according to single crystal X-ray diffraction, has a trigonal bipyramidal surrounding with the bridging oxygen atom and 2,4,6-tribromophenoxy substituents in the axial positions.

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REFERENCES

  1. Sharutin, V.V., Zhidkov, V.V., Muslin, D.V., Lyapina, N.Sh., Fukin, G.K., Zakharov, L.N., Yanovskii, A.I., and Struchkov, Yu.T., Izv. Ross. Akad. Nauk, Ser. Khim. 1995, no. 5, p. 958.

  2. Sharutin, V.V., Sharutina, O.K., Osipov, P.E., Pushilin, M.A., Muslin, D.V., Lyapina, N.Sh., Zhidkov, V.V., and Bel'skii, V.K., Zh. Obshch. Khim. 1997, vol. 67, no. 9, p. 1528.

    Google Scholar 

  3. Sharutin, V.V., Sharutina, O.K., Osipov, P.E., Vorob'eva, E.B., Muslin, D.V., and Bel'skii, V.K., Zh. Obshch. Khim. 2000, vol. 70, no. 6, p. 931.

    Google Scholar 

  4. Sharutin, V.V., Senchurin, V.S., Sharutina, O.K., Pakusina, A.P., and Panova, L.P., Zh. Obshch. Khim. 1996, vol. 66, no. 10, p. 1755.

    Google Scholar 

  5. Sharutin, V.V., Sharutina, O.K., Panova, L.P., and Bel'skii, V.K., Zh. Obshch. Khim. 1997, vol. 67, no. 9, p. 1531.

    Google Scholar 

  6. Sharutin, V.V., Sharutina, O.K., Pakusina, A.P., and Bel'skii, V.K., Zh. Obshch. Khim. 1997, vol. 67, no. 9, p. 1536.

    Google Scholar 

  7. Sharutin, V.V., Sharutina, O.K., Egorova, I.V., and Panova, L.P., Zh. Obshch. Khim. 1998, vol. 68, no. 2, p. 345.

    Google Scholar 

  8. Sharutin, V.V., Sharutina, O.K., Tarasova, T.A., Kharsika, A.N., and Bel'skii, V.K., Zh. Obshch. Khim. 1999, vol. 69, no. 12, p. 1979.

    Google Scholar 

  9. Sharutin, V.V., Sharutina, O.K., Senchurin, V.S., Kovaleva, T.A., Shcherbakov, V.I., and Gladyshev, E.N., Zh. Obshch. Khim. 2000, vol. 70, no. 1, p. 69.

    Google Scholar 

  10. Ferguson, G. and Ridley, D.R., Acta Crystallogr., Sect. B 1973, vol. 29, no. 10, p. 2221.

    Google Scholar 

  11. Starikova, Z.A., Shchegoleva, T.M., Trunov, V.K., and Pokrovskaya, I.E., Kristallografiya 1978, vol. 23, no. 5, p. 969.

    Google Scholar 

  12. Breneman, G.L., Acta Crystallogr., Sect. B 1979, vol. 35, no. 4, p. 731.

    Google Scholar 

  13. Preut, H., Ruther, R., and Huber, F., Acta Crystallogr., Sect. C 1985, vol. 41, no. 2, p. 358.

    Google Scholar 

  14. Preut, H., Ruther, R., and Huber, F., Acta Crystallogr., Sect. C 1986, vol. 42, no. 9, pp. 1154–1157.

    Google Scholar 

  15. Tiekink, E.R.T., J. Organomet. Chem. 1987, vol. 333, no. 2, p. 199.

    Google Scholar 

  16. Ouchi, A. and Sato, S., Bull. Chem. Soc. Jpn. 1988, vol. 61, no. 5, p. 1806.

    Google Scholar 

  17. Taylor, M.J., Baker, L.-J., Rickard, C.E.F., and Surman, P.W.J., J. Organomet. Chem. 1995, vol. 498, no. 1, p. C14.

    Google Scholar 

  18. Almond, M.J., Drew, M.G.B., Rice, D.A., Salisbury, G., and Taylor, M.J., J. Organomet. Chem. 1996, vol. 522, no. 2, p. 265.

    Google Scholar 

  19. Effendy, Grigsby, W.J., Hart, R.D., Raston, C.L., Skelton, B.W., and White, A.H., Aust. J. Chem. 1997, vol. 50, no. 6, p. 675.

    Google Scholar 

  20. Gibbons, M.N., Blake, A.J., and Sowerby, D.B., J. Organomet. Chem. 1997, vol. 543, no. 2, p. 217.

    Google Scholar 

  21. Gibbons, M.N. and Sowerby, D.B., J. Organomet. Chem. 1998, vol. 555, no. 2, p. 271.

    Google Scholar 

  22. Mahon, M.F., Molloy, K.C., Omotowa, B.A., and Mesubi, M.A., J. Organomet. Chem. 1998, vol. 560, no. 1, p. 95.

    Google Scholar 

  23. Sharutin, V.V., Sharutina, O.K., Panova, L.P., Nasonova, N.V., Bliznyuk, T.N., and Bel'skii, V.K., Izv. Ross. Akad. Nauk, Ser. Khim. 1999, no. 1, p. 174.

  24. Sharutin, V.V., Sharutina, O.K., Nasonova, N.V., Ivashchik, I.A., Krivolapov, D.B., Gubaidullin, A.T., and Litvinov, I.A., Izv. Ross. Akad. Nauk, Ser. Khim. 1999, no. 12, p. 2346.

  25. Bruker (1998). SMART and SAINT-Plus. Ver. 5.0. Data Collection and Processing Software for the SMART System Madison (the United States): Bruker AXS, 1998.

    Google Scholar 

  26. Bruker (1998). SHELXTL/PC. Ver. 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data Madison (the United States): Bruker AXS, 1998.

    Google Scholar 

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, A. P. Pakusina, M. A. Pushilin, O. V. Subacheva, A. V. Gerasimenko & E. A. Gerasimenko

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  1. V. V. Sharutin
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  2. A. P. Pakusina
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  3. M. A. Pushilin
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  4. O. V. Subacheva
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  5. A. V. Gerasimenko
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  6. E. A. Gerasimenko
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Sharutin, V.V., Pakusina, A.P., Pushilin, M.A. et al. Organoantimony Derivatives of 2,4,6-Tribromophenol. Russian Journal of General Chemistry 73, 541–545 (2003). https://doi.org/10.1023/A:1025628217346

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