Abstract
The adsorption of atrazine and two model compounds,2-chloropyrimidine and 3-chloropyridine on clay minerals(bentonite, montmorillonite and kaolinite), organic matter (humic acid) and soil (with and without organic matter) has beenstudied using FT-infrared spectroscopy (IR), thermogravimetric analysis (TGA), high pressureliquid chromatography (HPLC) and X-ray diffraction (XRD).3-Chloropyridine, 2-chloropyrimidine and atrazine were adsorbedthrough hydrogen bonding on bentonite, montmorillonite, humic acid and soil. In addition tohydrogen bonding, protonation of 3-chloropyridine and atrazine was also observed.In the adsorption of 2-chloropyrimidine on bentonite and montmorillonitean ion exchange mechanism also occurred. No adsorption of 3-chloropyridine or 2-chloropyrimidine wasobserved on the kaolinite clay mineral.Both the clay minerals and organic matter of soil contribute tothe adsorption of organic compounds on soil but the clay minerals bentonite and montmorilloniteplay a major role in their adsorption on soil.
Similar content being viewed by others
References
J.E.D. Davies and N. Jabeen: J. Incl. Phenom. 43, 329 (2002).
L. Clausen, I. Fabricius, and L. Madsen: J. Environ. Qual. 30, 846 (2001).
G.Y. Sheng, C.T. Johnston, B.J. Teppen, and S.A. Boyd: J. Agric. Food Chem. 49, 2899 (2001).
C. Moreau-Kervevan and C. Mouvet: J. Environ. Qual. 27, 46 (1998).
I. Martine-Neto, E.M. Vieira, and G. Sposito: Environ. Sci. Technol. 28, 1867 (1994).
M. Graymore, F. Stagnitti, and G. Allinson: Environ. Int. 26, 483 (2001).
R.S. Hoffman, P.D. Capel, and S.J. Larson: Environ. Toxic. Chem. 19, 2249 (2000).
M.A. Lw and H.M. Selim: Rev. Environ. Contamin. Toxic. 145, 129 (1996).
U. Herwig, E. Klumpp, H.D. Narres, and M.J. Schwuger: Appl. Clay Sci. 18, 211 (2001).
E. Barriuso and R. Calvet: Int. J. Environ. Anal. Chem. 46, 117 (1992).
T. Grundl and G. Small: J. Contamin. Hydrol. 14, 117 (1993).
D.A. Laird, P.Y. Yen, C.W. Koskinen, T.R. Steinheimer, and R.H. Dowdy: Environ. Sci. Technol. 28, 1054 (1994).
D.S. Gamble and S.U. Khan: Soil Sci. 65, 435 (1985).
V.P. Evangelou and J. Wang: Spectrochim. Acta 49A, 291 (1993).
R.N. Lerch, E.M. Thurman, and P.E. Blanchard: Environ. Toxic. Chem. 18, 2161 (1999).
J.W. Ward: J. Colloid. Interface Sci. 28, 269 (1968).
J. Sullivan and G.T. Felbeck: Soil Sci. 106, 42 (1968).
C. Breen, A. Deane, and J.J. Flynn: Clay Miner. 22, 169 (1987); C. Breen: Clay Miner. 26, 487 (1991).
H.S. Green, W. Kynaston, and H.M. Paisley: Spectrochim. Acta 19, 549 (1963).
N.S. Gill, R.H. Nuttall, D.E. Scaife, and D.W.A. Sharp: J. Inorg. Nucl. Chem. 18, 79 (1961).
A.N. Sidorov: Optik. Specktrosk. 8, 51 (1960); Chem. Abstr. 54, 16180f.
S. Akyüz, T. Akyüz, and J.E.D. Davies: J. Incl. Phenom. 15, 105 (1993).
J.M. Serratosa: Clay and Clay Miner. Proc. Fourteenth Nat. Conf., Berkeley, California (1966).
V.C. Farmer and M.M. Mortland: J. Chem. Soc. (A), 344 (1966).
G.E. Lailach, T.D. Thompson, and G.W. Brindley: Clays Clay Miner. 16, 285 (1968); Clays Clay Miner. 16, 295 (1968).
T.D. Thompson and G.W. Brindley: Am. Miner. 54, 858 (1969).
A.H. Khairy, G. Davies, H.Z. Ibrahim, and E.A. Ghabbour: J. Phys. Chem. 100, 2410 (1996).
R. Foglizzo and A. Novak: Spectrochim. Acta 25A, 2281 (1970).
P. Pichat: J. Phys. Chem. 78, 2376 (1974).
C.B. Brown and J.L. White: Soil Sci. Soc. Am. Proc. 33, 863 (1969).
M. Cruz, J.L.White, and J.D. Russell: Israel J. Chem. 6, 315 (1968).
J.D. Russell, M. Cruz, J.L. White, G.W. Bailey, W.R. Payne Jr., J.D. Pope Jr., and J.I. Teasley: Science 160, 1340 (1968); J.D. Russell, M. Cruz, and J.L. White: J. Agric. Food Chem. 16, 21 (1968).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Davies, J.E.D., Jabeen, N. The Adsorption of Herbicides and Pesticides on Clay Minerals and Soils. Part 2. Atrazine. Journal of Inclusion Phenomena 46, 57–64 (2003). https://doi.org/10.1023/A:1025604713256
Issue Date:
DOI: https://doi.org/10.1023/A:1025604713256