Skip to main content
SpringerLink
Log in

On the adsorption mechanism of copper ions on bentonite clay

  • Full Article
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The adsorption of copper ions on bentonite clay was studied as a function of the pH of the medium, contact time, and temperature. A comparative study of the applicability of the Langmuir and Freindlich adsorption models for the description of the experimental adsorption isotherms of Cu2+ was carried out. The constants and parameters of the equations describing the adsorption equilibrium were determined. The correlation coefficients (R2) indicate that both models satisfactorily outline the sorption process. However, the Langmuir adsorption isotherm is more preferable for describing adsorption of Cu2+ ions on bentonite clay, since it allows one to determine the limiting adsorption capacity. The adsorption of Cu2+ ions on bentonite clay increases as the temperature increases from 293 to 333 K. At the same time, the shape of the adsorption isotherms remains unchanged.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. E. Belousov, V. V. Krupskaya, Georesursy [Georesources], 2019, 21, No. 3, 79–90 (in Russian).

    Article  Google Scholar 

  2. A. I. Vezentsev, V. A. Peristiy, V. D. Bukhanov, L. F. Peristaya, P. V. Sokolovskiy, F. Roessner, M. O. Mikhailyukova, A. A. Greish, Russ. J. Phys. Chem. A., 2018, 92, 1806–1812; DOI: https://doi.org/10.1134/S0036024418090339.

    Article  CAS  Google Scholar 

  3. N. Volovicheva, A. Vezentsev, S. Korolkova, P. Sokolovskiy, Int. J. Appl. Eng. Res., 2015, 10, 31381–31388.

    Google Scholar 

  4. A. I. Vezentsev, L. F. Goldovskaya-Peristaya, V. A. Peristiy, E. V. Kopylova, E. V. Kormosh, Res. J. Pharmac., Biol. Chem. Sci., 2016, 7, 2705–2713.

    CAS  Google Scholar 

  5. N. A. Volovicheva, S. V. Korol’kova, A. I. Vezentsev, Nauch. Ved. Belgorod. Gos. Un-ta. Ser. Estestvennye Nauki [Scientific Writings of Belgorod State Univ., Nat. Sci.], 2016, No. 25 (246), 63–69 (in Russian).

    Google Scholar 

  6. L. F. Goldovskaya-Peristaya, A. I. Vezentsev, V. A. Peristiy, E. V. Dobrodomova-Kopylova, Nauch. Ved. Belgorod. Gos. Un-ta. Ser. Estestvennye Nauki [Scientific Writings of Belgorod State Univ., Nat. Sci.], 2016, No. 11 (232), 117–128 (in Russian).

    Google Scholar 

  7. V. V. Milyutin, A. I. Vezentsev, P. V. Sokolovskiy, N. A. Nekrasova, Sorbtsionnye i Khromatograficheskie Protsessy [Sorption and Chromatographic Processes], 2014, 14, 879–883 (in Russian).

  8. A. I. Vezentsev, L. F. Goldovskaya-Peristaya, P. V. Sokolovskiy, V. A. Peristiy, V. D. Buhanov, Adv. Environ. Biol., 2014, 8, No. 3, 13–16.

    CAS  Google Scholar 

  9. A. I. Vezentsev, P. V. Sokolovskiy, V. D. Buhanov Adv. Environ. Biol., 2014, 8, No. 13, 38–41.

    CAS  Google Scholar 

  10. M. H. Bradbury, B. Baeyens, Radiochim. Acta, 2006, 94, 619–625.

    Article  CAS  Google Scholar 

  11. Z. Guo, Colloids Surfaces, A, Physicochem. Eng. Asp., 2009, 339, 126–133.

    Article  CAS  Google Scholar 

  12. S. Gu, X. Kang, L. Wang, E. Lichtfouse, C. Wang, Environ. Chem. Lett., 2019, 17, 629–654.

    Article  CAS  Google Scholar 

  13. R. Yous, H. Cherifi, R. Khalladi, Desalination and Water Treatment, 2021, 221, 207–221.

    Article  CAS  Google Scholar 

  14. S. Yang, X. E. T Xiao, Inorg. Chem. Commun., 2021, 125, 108464.

    Article  CAS  Google Scholar 

  15. Y. S. Hong, Appl. Clay Sci., 2019, 175, 190–192.

    Article  CAS  Google Scholar 

  16. A. I. Vezentsev, L. F. Goldovskaya-Peristaya, V. A. Peristiy, E. V. Kopylova, E. V. Kormosh, Res. J. Pharmac., Biol. Chem. Sci., 2016. 7, 2705–2713.

    CAS  Google Scholar 

  17. X. Zhao, B. Tuo, S. Long, X. Song, L. Wan, H. Xiang, Micro and Nano Lett., 2021, 16, 304–312.

    Article  CAS  Google Scholar 

  18. P. V. Sokolovskiy, F. Roessner, A. I. Vezentsev, T. V. Konkova, M. B. Alekhina, S. S. Manokhin, A. A. Greish, Russ. J. Phys. Chem. A, 2018, 92, 1947–1952; DOI: https://doi.org/10.1134/S0036024418100333.

    Article  CAS  Google Scholar 

  19. L. Qin, Y. Zhao, L. Wang, L. Zhang, S. Kang, W. Wang, T. Zhang, S. Song, Chemosphere, 2020, 252, 126560.

    Article  CAS  Google Scholar 

  20. Y. Chu, M. A. Khan, M. Xia, W. Lei, F. Wang, S. Zhu, X. Yan, Chem. Eng. Res. Design, 2020, 157, 142–152.

    Article  CAS  Google Scholar 

  21. H. Nguyen Van, H. Chu Van, T. Luu Hoang, V. D. K. Nguyen, C. N. Ha Thuc, Arab. J. Chem., 2020, 13, 7212–7223.

    Article  CAS  Google Scholar 

  22. A. Geroeeyan, A. Niazi, E. Konoz, Water Sci. Technol., 2021, 83, 2271–2286.

    Article  CAS  Google Scholar 

  23. N. D. Mu’azu, A. Bukhari, K. Munef, J. King Saud University — Sci., 2020, 32, 412–422.

    Article  Google Scholar 

  24. Y. Abdellaou, M. T. Olguín, M. Abatal, B. Ali, S. E. Díaz Méndez, A. A. Santiago, Superlattices and Microstructures, 2019, 127, 165–175.

    Article  Google Scholar 

  25. J. Wang, W. Wang, Z. Ai, M. Li, H. Li, W. Peng Y. Zhao, S. Song, Appl. Clay Sci., 2021, 210, 106153.

    Article  CAS  Google Scholar 

  26. X.-F. Sun, Y. Hao, Y. Cao, Q. Zeng, Int. J. Biol. Macromol., 2019, 127, 511–519.

    Article  CAS  Google Scholar 

  27. A. V. Kostin, L. V. Mostalygina, O. I. Bukhtoyarov, Sorbtsionnye i khromatograficheskie protsessy [Sorption and Chromatographic Processes], 2012, 12, 949–957 (in Russian).

    Google Scholar 

  28. I. Langmuir, J. Am. Chem. Soc., 1916, 38, 2221–2295.

    Article  CAS  Google Scholar 

  29. H. M. F. Freundlich, J. Phys. Chem., 1906, 57, 385–471.

    CAS  Google Scholar 

  30. J. J. Giner-Casares, G. Brezesinski, H. Möhwald, Current Opinion in Colloid Interface Sci., 2014, 19, 176–182.

    Article  CAS  Google Scholar 

  31. C. H. Giles, J. Soc. Dyers and Colourists, 1973, 89, 287–291.

    Article  CAS  Google Scholar 

  32. K. V. Kumar, S. Gadipelli, B. Wood, K. A. Ramisetty, A. A. Stewart, C. A. Howard, J. Mater. Chem. A, 2019, 7, 10104–10137.

    Article  CAS  Google Scholar 

  33. O. I. Bukhtoyarov, L. V. Mostalygina, D. N. Kamaev, A. V. Kostin, Sorbtsionnye i khromatograficheskie protsessy [Sorption and Chromatographic Processes], 2011, 11, 518–524 (in Russian).

    CAS  Google Scholar 

  34. A. I. Vezentsev, D. M. Thuy, L. F. Peristaya, V. A. Peristyj, A. T. Alateya, P. T. Minh, J. Eng. Sci. Technol., 2019, 14, 520–530.

    Google Scholar 

  35. T. H. Shaymaa, A. K. A. Seroor, J. Ecol. Eng., 2021, 22, 104–111.

    Google Scholar 

  36. E. D. Dmitrieva, A. A. Goryacheva, K. V. Syundyukova, E. N. Muzafarov, Sorbtsionnye i khromatograficheskie protsessy [Sorption and Chromatographic Processes], 2016, 16, 813–820 (in Russian).

    CAS  Google Scholar 

  37. A. I. Vezentsev, N. A. Volovicheva, S. V. Korol’kova, K. S. Sovetova, Vestn. Tekhnol. Un-ta [Bull. Technol. Univ.], 2020, 23, No. 6, 35–39 (in Russian).

    Google Scholar 

  38. E. M. Sapargaliev, Vestn. Ros. Un-ta Druzhby Narodov. Ser. Inzhenernye Issledovaniya [Bull. Russ. Univ. Peoples Friendship, Ser. Eng. Res.], 2007, No. 2, 77–81 (in Russian).

    Google Scholar 

  39. L. Yan, X. Shan, B. Wen, G. Owens. J. Hazar. Mater., 2008, 156, 499–508.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Belgorod State National Research University, 85 ul. Pobedy, 308015, Belgorod, Russian Federation

    A. I. Vezentsev & N. M. Gorbunova

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prospect, 119991, Moscow, Russian Federation

    P. V. Sokolovskiy & A. A. Greish

  3. LLC “Company BENTONIT,”, Build. 1, 12 ul. Tverskaya, 125009, Moscow, Russian Federation

    S. G. Mar’inskikh

  4. Tyumen Industrial University, 38 ul. Volodarskogo, 625000, Tyumen, Russian Federation

    S. G. Mar’inskikh

  5. LLC “Leading,”, 1a ul. Lermontova, Bol’shoe Polpino, 241903, Bryansk, Russian Federation

    A. V. Chub

  6. Vietnam Academy of Science and Technology, Institute of Environmental Technology, 650000, Hanoi, Vietnam

    Nguyen Hoai Chau

Authors
  1. A. I. Vezentsev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. M. Gorbunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. V. Sokolovskiy
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. G. Mar’inskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Chub
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Nguyen Hoai Chau
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. A. Greish
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. V. Sokolovskiy.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 651–655, April, 2022.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 20-53-54005 (QTRU 01.13/20-21)) in cooperation with the Institute of Environmental Technology of the Vietnam Academy of Science and Technology.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vezentsev, A.I., Gorbunova, N.M., Sokolovskiy, P.V. et al. On the adsorption mechanism of copper ions on bentonite clay. Russ Chem Bull 71, 651–655 (2022). https://doi.org/10.1007/s11172-022-3461-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-022-3461-y

Key words

Search

Navigation