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μ-(2,2,9,9-tetramethyl-3,7-dithiadecane) decacarbonylditungsten(0)

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Abstract

The title compound crystallizes in the centrosymmetric triclinic unit cell, a = 6.6662(8) Å, b = 8.8584(6) Å, c = 13.574(2) Å, α = 71.468(7)°, β = 82.182(9)°, γ = 75.270(7)°, Z = 1. Refinement converged at R = 0.0396 for 1383 observed reflections. The molecule consists of two W(CO)5 fragments bridged centrosymmetrically by the 2,2,9,9-tetramethyl-3,7-dithiadecane ligand.

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Authors and Affiliations

  1. Department of Chemistry, University of North Texas, Denton, Texas, 76203

    Khalil J. Asali, Tino Ladogana, Simon G. Bott & Gerard R. Dobson

  2. Department of Chemistry, Jordan University of Science and Technology, Irbid, Jordan

    Khalil J. Asali

  3. Department of Chemistry, University of Houston, Houston, Texas, 77204

    Simon G. Bott

Authors
  1. Khalil J. Asali
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  2. Tino Ladogana
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  3. Simon G. Bott
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  4. Gerard R. Dobson
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Correspondence to Simon G. Bott.

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Asali, K.J., Ladogana, T., Bott, S.G. et al. μ-(2,2,9,9-tetramethyl-3,7-dithiadecane) decacarbonylditungsten(0). Journal of Chemical Crystallography 33, 701–704 (2003). https://doi.org/10.1023/A:1025345626604

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  • DOI: https://doi.org/10.1023/A:1025345626604

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