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Steric Effect of an ortho-Alkyl Group on the Stretching Vibration Frequency of Phenol Hydroxyl

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Abstract

It is shown that the derivatives of mono-ortho-alkylsubstituted phenols, which in the ortho-position have primary and secondary alkyl groups, and also tertiary alkyl groups have different correlations between the frequencies of the stretching vibration of the OH bond and Pal'm's steric constants E s 0.

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Karpov, O.N. Steric Effect of an ortho-Alkyl Group on the Stretching Vibration Frequency of Phenol Hydroxyl. Journal of Applied Spectroscopy 70, 465–469 (2003). https://doi.org/10.1023/A:1025106227205

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  • DOI: https://doi.org/10.1023/A:1025106227205

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