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Decomposition of organic salts of some d and f metals

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Abstract

The thermal decomposition in non-isothermal conditions of formates, acetates, propionates and butyrates of Mn, Co, Zn, Cd, Eu, Sm and Ni was studied. The observed compensation effect allows us to calculate the isokinetic temperature. A selective activation mechanism was suggested. This leads to a good agreement between kinetic and spectroscopic data.

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Vlase, T., Vlase, G., Chiriac, A. et al. Decomposition of organic salts of some d and f metals. Journal of Thermal Analysis and Calorimetry 72, 839–845 (2003). https://doi.org/10.1023/A:1025066131365

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  • DOI: https://doi.org/10.1023/A:1025066131365

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