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Synthesis and Structure of (4-Acetyl-3-hydroxyphenoxy)tetraphenylantimony

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Abstract

Pentaphenylantimony was reacted with 4-acetyl-1,3-dihydroxybenzene in toluene at elevated temperature to obtain (4-acetyl-3-hydroxyphenoxy)tetraphenylantimony in 93% yield. According to X-ray diffraction data, the antimony atom in (4-acetyl-3-hydroxy-phenoxy)tetraphenylantimony has a distorted trigonal-bipyramidal configuration. The Sb-O and Sb-C distances are 2.237(1) and 2.112(1), 2.114(2), 2.118(2), 2.170(2) Å, respectively, and the CSbO angle is 177.86(5)°.

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  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, O. K. Sharutina, E. A. Bondar', O. V. Subacheva, A. P. Pakusina, A. V. Gerasimenko & S. S. Sergienko

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. E. A. Bondar'
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  4. O. V. Subacheva
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  5. A. P. Pakusina
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  6. A. V. Gerasimenko
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  7. S. S. Sergienko
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Sharutin, V.V., Sharutina, O.K., Bondar', E.A. et al. Synthesis and Structure of (4-Acetyl-3-hydroxyphenoxy)tetraphenylantimony. Russian Journal of General Chemistry 73, 350–353 (2003). https://doi.org/10.1023/A:1024993400389

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