Abstract
The photoconductivity characteristics of films of polymeric compositions based on polystyrene and containing substituted tetrathiafulvalenes (electron donors 2,4,5,7-tetranitro-9-fluorenone, electron acceptors cationic and neutral polymethine dyes) were studied in the spectral region from 400 to 1000 nm. It was established that on account of the low ionization potential the selected electron donors create conditions for the photogeneration of charge carriers in the near IR region. It was shown that the photoconductivity in the absorption region of the dye increases with substitution of the ionic dye by a neutral dye.
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REFERENCES
V. D. Pokhodenko and N. F. Guba, Teor. Éksp. Khim., 30, No. 5, 241-263 (1994).
J. Rostalski and D. Meissner, Solar Energy Mater. Solar Cells, 61, 87-96 (2000).
J. M. Nunzi, Compt. Rend. Physique, 3, 1-20 (2002).
W. U. Huynh, J. J. Dittmer, and A. P. Alivisatos, Science, 295, 2425-2438 (2002).
N. G. Kuvshinskii, N. A. Davidenko, and V. M. Komko, Physics of Amorphous Molecular Semiconductors [in Russian], Lybid', Kiev (1994).
N. A. Davidenko and A. A. Ishchenko, Teor. Éksp. Khim., 38, No. 2, 84-101 (2002).
R. Danovich, Y. Apeloig, and S. Shaik, J. Chem. Soc., Perkin Trans., No. 3, 321-330 (1993).
E. L. Frankevich, A. N. Chaban, and D. I. Kadyrov, Khim. Fiz., 21, No. 4, 103-106 (2002).
P. Peumans and S. R. Forrest, Appl. Phys. Lett., 79, 126-130 (2001).
A. A. Ishchenko, Structure and Luminescence-Spectral Characteristics of Polymethine Dyes [in Russian], Naukova Dumka, Kiev (1994).
M. Pope and C. Svenberg, Electronic Processes in Organic Crystals [Russian translation], Vol. 2, Mir, Moscow (1985).
V. D. Filimonov and E. E. Sirotkina, Chemistry of Monomers Based on Carbazole [in Russian], Nauka, Novosibirsk (1995).
Ya. N. Kreitsberga, D. V. Bite, V. É. Kampar, et al., Zh. Org. Khim., 17, No. 5, 1055-1062 (1981).
J. J. P. Stewart, J. Computer-Aided Design, 4, 1-105 (1990).
N. A. Davidenko and N. G. Kuvshinsky, J. Inf. Rec. Mats., 21, 185-197 (1993).
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Davidenko, N.A., Ishchenko, A.A. & Neiland, O.Y. Photoconductivity of Compositions Based on Polystyrene in the Near IR Region of the Spectrum. Theoretical and Experimental Chemistry 39, 152–157 (2003). https://doi.org/10.1023/A:1024980906945
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DOI: https://doi.org/10.1023/A:1024980906945