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Surface Chemistry Studies of Quantum Dots (QDs) Modified with Surfactants

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Abstract

Since luminescent CdSe quantum dots (QDs) have shown great potential in biological labeling, the surface chemistry behavior of QDs at interfaces is of great research interest. In the present study, CdSe QDs with green luminescence were modified with hydrophobic chains of varying lengths [from C6 to C18]. These modified QDs can be utilized to form stable monolayers at the air/water interface. Surface pressure-area isotherms of modified QDs have been measured and limiting molecular areas have also been extrapolated in order to analyze the size of the QDs. UV absorption spectra of modified QDs at various surface pressures were also determined. Surface chemistry, as well as the topographic properties, of modified QDs in Langmuir and L-B films was discussed.

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References

  1. S. Empedocles and M. G. Bawendi (1999). Accounts Chem. Res. 32, 389.

    Google Scholar 

  2. J. R. Heath (1995). Science 270, 1315.

    Google Scholar 

  3. M. Nirmal, B. O. Dabbousi, M. G. Bawendi, J. J. Macklin, J. K. Trautman, T. D. Harris, and L. E. Brus (1996). Nature 383, 802.

    Google Scholar 

  4. M. G. Bawendi, P. J. Carroll, W. L. Wilson, and L. E. Brus (1992). J. Chem. Phys. 96, 946.

    Google Scholar 

  5. M. G. Bawendi, M. L. Steigerwald, and L. E. Brus (1990). Annu. Rev. Phys. Chem. 41, 477.

    Google Scholar 

  6. M. Nirmal and L. Brus (1999). Accounts Chem. Res. 32, 407.

    Google Scholar 

  7. J. E. B. Katari, V. L. Colvin, and A. P. Alivisatos (1994). J. Phys. Chem. 98, 4109.

    Google Scholar 

  8. J. Tittel, W. Gohde, F. Koberling, T. Basche, A. Kornowski, H. Weller, and A. Eychmuller (1997). J. Phys. Chem. B 101, 3013.

    Google Scholar 

  9. F. V. Mikulec, M. Kuno, M. Bennati, D. A. Hall, R. G. Griffin, and M. G. Bawendi (2000). J. Amer. Chem. Soc. 122, 2532.

    Google Scholar 

  10. C. P. Collier, T. Vossmeyer, and J. R. Heath (1998). Annu. Rev. Phys. Chem. 49, 371.

    PubMed  Google Scholar 

  11. W. C. W. Chan and S. M. Nieb (1998). Science 281, 2016.

    PubMed  Google Scholar 

  12. S. R. Cordero, P. J. Carson, R. A. Estabrook, G. F. Strouse, and S. K. Buratto (2000). J. Phys. Chem. B 104, 12137.

    Google Scholar 

  13. X. Y. Wu, H. J. Liu, J. Q. Liu, K. N. Haley, J. A. Treadway, J. P. Larson, N. F. Ge, F. Peale, and M. P. Bruchez (2003). Nat. Biotechnol. 21, 41.

    PubMed  Google Scholar 

  14. S. Coe, W. K. Woo, M. Bawendi, and V. Bulovic (2002). Nature 420, 800.

    PubMed  Google Scholar 

  15. Z. A. Peng and X. G. Peng (2001). J. Amer. Chem. Soc. 123, 183.

    Google Scholar 

  16. X. G. Peng, M. C. Schlamp, A. V. Kadavanich, and A. P. Alivisatos (1997). J. Amer. Chem. Soc., 119, 7019.

    Google Scholar 

  17. C. A. Leatherdale, W. K. Woo, F. V. Mikulec, and M. G. Bawendi (2002). J. Phys. Chem. B 106, 7619.

    Google Scholar 

  18. O. Schmelz, A. Mews, T. Basche, A. Herrmann, and K. Mullen (2001). Langmuir 17, 2861.

    Google Scholar 

  19. J. H. Fendler (2001). Chem. Mater. 13, 3196.

    Google Scholar 

  20. J. Jiang, T. D. Krauss, and L. E. Brus (2000). J. Phys. Chem. B 104, 11936.

    Google Scholar 

  21. C. B. Murray, D. J. Norris, and M. G. Bawendi (1993). J. Amer. Chem. Soc. 115, 8706.

    Google Scholar 

  22. A. P. Alivisatos (1996). J. Phys. Chem. 100, 13226.

    Google Scholar 

  23. G. Sui, M. Micic, Q. Huo, and R. M. Leblanc (2000). Colloid Surf. A-Physicochem. Eng. Asp. 168, 193.

    Google Scholar 

  24. G. Sui, J. Orbulescu, M. Mabrouki, R. M. Leblanc, S. G. Liu, and B. A. Gregg (2002). Chem. Phys. Chem 3, 1041.

    PubMed  Google Scholar 

  25. G. Sui, J. Orbulescu, M. Mabrouki, M. Micic, R. M. Leblanc, S. G. Liu, R. A. Cormier, and B. A. Gregg (2002). J. Phys. Chem. B 106, 9335.

    Google Scholar 

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Correspondence to Roger M. Leblanc.

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Sui, G., Orbulescu, J., Ji, X. et al. Surface Chemistry Studies of Quantum Dots (QDs) Modified with Surfactants. Journal of Cluster Science 14, 123–133 (2003). https://doi.org/10.1023/A:1024889504216

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  • DOI: https://doi.org/10.1023/A:1024889504216

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