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Volumetric properties of H2O, D2O, and methanol in acetonitrile at 278.15—318.15 K

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Abstract

The densities of H2O, D2O, and MeOH solutions in acetonitrile with the solute concentrations up to 0.07 molar fractions at 278.15, 288.15, 298.15, 308.15, and 318.15 K were measured using vibrating-tube densimetry with an error ≤8·10–6 g cm–3. The limiting partial molar volumes for the H/D isotopomers of water and IaII in acetonitrile (V– 2 ∞) and the isotope effects in V– 2 ∞ and in excess molar volumes of acetonitrile—water mixtures were calculated. Molecules of H2O, D2O, and IaII form associates with acetonitrile molecules via hydrogen bonds. The associates have the packing volumes close to those in the individual solute. The water and methanol molecules were assumed to be incorporated into the acetonitrile structure without substantial changes in the latter. However, this process results in some compression of the system with a simultaneous increase in its expansibility.

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References

  1. V. K. Abrosimov, in Termodinamika rastvorov neelektrolitov [Thermodynamics of Solutions of Nonelectrolytes], Institute of Nonaqueous Solution Chemistry, Acad. Sci. USSR, Ivanovo, 1989, p. 66 (in Russian).

    Google Scholar 

  2. V. P. Belousov and M. Yu. Panov, Termodinamika vodnykh rastvorov neelektrolitov [Thermodynamics of Aqueous Solutions of Nonelectrolytes], Khimiya, Leningrad, 1983, 265 pp. (in Russian).

    Google Scholar 

  3. M. Sakurai and T. Nakagawa, J. Chem. Thermodyn., 1984, 16, 171.

    Google Scholar 

  4. S.-O. Nilsson, J. Chem. Thermodyn., 1986, 18, 877, 1115.

    Google Scholar 

  5. W. A. P. Luck, Pure Appl. Chem., 1987, 59, 1215.

    Google Scholar 

  6. M. Sakurai, Bull. Chem. Soc. Jpn., 1990, 63, 1695.

    Google Scholar 

  7. V. I. Grasin and V. K. Abrosimov, Izv. Akad. Nauk SSSR, Ser. Khim., 1991, 317 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40, 263 (Engl. Transl.)].

  8. V. P. Korolev, D. V. Batov, and G. A. Krestov, Zh. Obshch. Khim., 1991, 61, 1921 [J. Gen. Chem. USSR, 1991, 61 (Engl. Transl.)].

    Google Scholar 

  9. M. Sakurai, J. Chem. Eng. Data, 1992, 37, 358.

    Google Scholar 

  10. V. I. Grasin and V. K. Abrosimov, Izv. Akad. Nauk, Ser. Khim., 1992, 568 [Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992, 41, 441 (Engl. Transl.)].

  11. E. V. Ivanov and V. K. Abrosimov, Zh. Neorg. Khim., 1995, 40, 1047 [Russ. J. Inorg. Chem., 1995, 40 (Engl. Transl.)].

    Google Scholar 

  12. V. A. Sirotkin, B. N. Solomonov, D. A. Faizullin, and V. D. Fedotov, Zh. Strukt. Khim., 2000, 41, 1206 [Russ. J. Struct. Chem., 2000, 41 (Engl. Transl.)].

    Google Scholar 

  13. V. I. Grasin, Ph. D. (Chem.) Thesis, Institute of Solution Chemistry, RAS, Ivanovo, 2002, 175 pp. (in Russian).

  14. Y. Markus, Ion Solvation, Wiley, Chichester, 1985, 306 pp.

    Google Scholar 

  15. V. Gutmann, Electrochim. Acta, 1976, 21, 661.

    Google Scholar 

  16. M. F. Vuks, Zh. Strukt. Khim., 1971, 12, 3 [J. Struct. Chem. (USSR), 1971, 12 (Engl. Transl.)].

    Google Scholar 

  17. E. N. Zil´berman, Reaktsii nitrilov [Reactions of Nitriles], Khimiya, Moscow, 1972, 447 pp. (in Russian).

    Google Scholar 

  18. M. I. Shakhparonov, Vvedenie v sovremennuyu teoriyu rastvorov [The Introduction into the Modern Theories of Solutions], Vysshaya Shkola, Moscow, 1976, 296 pp. (in Russian).

    Google Scholar 

  19. O. Steinhauser and H. Bertagnolli, Chem. Phys. Lett., 1981, 78, 555.

    Google Scholar 

  20. T. Radnai, S. Itoh, and H. Ohtaki, Bull. Chem. Soc. Jpn., 1988, 61, 3845.

    Google Scholar 

  21. H. Ohtaki and S. Ishiguro, in Chemistry of Nonaqueos Solutions: Current Progress, Eds. G. Mamantov and A. I. Popov, VCH Publishers, New York, 1994, p. 179.

    Google Scholar 

  22. N. van Meurs and G. Somsen, J. Solut. Chem., 1993, 22, 427.

    Google Scholar 

  23. J. E. Bertie and Z. Lan, J. Phys. Chem., 1997, 101, 4111.

    Google Scholar 

  24. A. Wakisaka, H. Abdoult-Carime, Y. Yamamoto, and Y. Kiyozumi, J. Chem. Soc., Faraday Trans. 1, 1998, 94, 369.

    Google Scholar 

  25. T. Takamuku, M. Tabata, A. Yamaguchi, J. Nishimoto, M. Kumamoto, H. Wakita, and T. Yamaguchi, J. Phys. Chem., B, 1998, 102, 8880.

    Google Scholar 

  26. M. Nakamura, K. Tamura, and S. Murakami, Thermochim. Acta, 1995, 253, 127.

    Google Scholar 

  27. V. K. Abrosimov and V. V. Korolev, in Eksperimental´nye metody khimii rastvorov: Densimetriya, viskozimetriya, konduktometriya i drugie metody. Ser. "Problemy khimii rastvorov" [Experimental Methods of Solution Chemistry: Densimetry, Viscosimetry, and Other Methods. Ser. "Problems of Solution Chemistry"], Ed. A. M. Kutepov, Nauka, Moscow, 1997, p. 5 (in Russian).

    Google Scholar 

  28. V. K. Abrosimov, in Sovremennye problemy khimii rastvorov [Modern Problems of Solution Chemistry], Ed. B. D. Berezin, Nauka, Moscow, 1986, p. 97 (in Russian).

    Google Scholar 

  29. V. K. Abrosimov and Al. G. Krestov, in Dostizheniya i problemy teorii sol´vatatsii: Strukturno-termodinamicheskie aspekty. Ser. "Problemy khimii rastvorov" [Advance and Problems of the Theory of Solvation: Structural Thermodynamic Aspects. Ser. "Problems of Solution Chemistry"], Ed. A. M. Kutepov, Nauka, Moscow, 1998, p. 5 (in Russian).

    Google Scholar 

  30. K. Burger, Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents, Akademiai Kiado, Budapest, 1983.

    Google Scholar 

  31. V. V. Korolev, Zh. Fiz. Khim., 1989, 63, 1701 [Russ. J. Phys. Chem., 1989, 63 (Engl. Transl.)].

    Google Scholar 

  32. V. I. Grasin, V. K. Abrosimov, E. Yu. Lebedeva, and E. V. Ivanov, Plotnost´ razbavlennykh rastvorov H/D-izotopomerov vody i metanola v atsetonitrile pri 278.15 K-318.15 K [Densities of Dilute Solutions of H/D isotopomers of Water and Methanol in Acetonitrile at 278.15 K-318.15 K], Moscow, 2001, 9 pp.; deposited at VINITI 12.09.01, No. 1952-V2001 (in Russian).

  33. A. J. Easteal and L. A. Woolf, J. Chem. Thermodyn., 1988, 20, 693.

    Google Scholar 

  34. Y. P. Handa and G. C. Benson, J. Solut. Chem., 1981, 10, 291.

    Google Scholar 

  35. N. K. Levitskaya, L. I. Tkachenko, and O. I. Shkodin, Vestn. Khar´k. Un-ta [Kharkov University Bulletin], 1971, 2, 27 (in Russian).

    Google Scholar 

  36. V. K. Abrosimov, Zh. Fiz. Khim., 1988, 62, 1913 [Russ. J. Phys. Chem., 1988, 62 (Engl. Transl.)].

    Google Scholar 

  37. E. V. Ivanov and V. K. Abrosimov, Zh. Neorg. Khim., 2000, 45, 1074 [Russ. J. Inorg. Chem., 2000, 45 (Engl. Transl.)].

    Google Scholar 

  38. A. Bondi, J. Phys. Chem., 1964, 68, 441.

    Google Scholar 

  39. M. R. Dack, Austr. J. Chem., 1975, 28, 1643.

    Google Scholar 

  40. G. A. Krestov, V. P. Korolev, and D. V. Batov, Dokl. Akad. Nauk SSSR, 1987, 293, 882 [Dokl. Chem., 1987 (Engl. Transl.)].

    Google Scholar 

  41. G. S. Kell, J. Phys. Chem. Ref. Data, 1977, 6, 1109.

    Google Scholar 

  42. A. A. Stolov, M. D. Borisover, B. N. Solomonov, D. I. Kamalova, S. V. Izosimova, and I. S. Pominov, Zh. Fiz. Khim., 1992, 66, 620 [Russ. J. Phys. Chem., 1992, 66 (Engl. Ttansl.)].

    Google Scholar 

  43. Sh. D. Christian, A. A. Taha, and B. W. Gash, Quarterly Rev., 1970, 24, 20.

    Google Scholar 

  44. A. Ben-Naim, Solvation Thermodynamics, Plenum Press, New York, 1987, 251 p?.

    Google Scholar 

  45. Yu. G. Bushuev and T. A. Dubinkina, Zh. Fiz. Khim., 1996, 70, 1628 [Russ. J. Phys. Chem., 1996, 70 (Engl. Transl.)].

    Google Scholar 

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  1. Institute of Solution Chemistry, Russian Academy of Sciences, 1 ul. Akademicheskaya, 153045, Ivanovo, Russian Federation

    E. V. Ivanov, V. K. Abrosimov & E. Yu. Lebedeva

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  1. E. V. Ivanov
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  2. V. K. Abrosimov
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  3. E. Yu. Lebedeva
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Ivanov, E.V., Abrosimov, V.K. & Lebedeva, E.Y. Volumetric properties of H2O, D2O, and methanol in acetonitrile at 278.15—318.15 K. Russian Chemical Bulletin 52, 1326–1332 (2003). https://doi.org/10.1023/A:1024866825233

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