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Limiting Currents of the Triiodide Reduction on an Inclined Disk Electrode under Conditions of Natural Convection

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Abstract

The triiodide reduction from iodine solutions in excess of potassium iodide is studied in a cell with two parallel-plate platinum electrodes. The limiting current of the reduction is determined experimentally as a function of inclination θ of electrodes to the vertical and the solution composition. The qualitative analysis of results is based on the earlier elaborated concept of regularities of natural convection in electrochemical systems.

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    L. A. Reznikova & A. D. Davydov

  2. Institute of Chemistry of Solutions, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153000, Russia

    E. E. Morgunova & S. A. Lilin

Authors
  1. L. A. Reznikova
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  2. E. E. Morgunova
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  3. S. A. Lilin
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  4. A. D. Davydov
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Correspondence to L. A. Reznikova.

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Reznikova, L.A., Morgunova, E.E., Lilin, S.A. et al. Limiting Currents of the Triiodide Reduction on an Inclined Disk Electrode under Conditions of Natural Convection. Russian Journal of Electrochemistry 39, 727–730 (2003). https://doi.org/10.1023/A:1024821918002

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