Skip to main content
SpringerLink
Log in

Theory of the Relaxation Spectra of Cross‐Linked Polymers in the Presence of Structural and Dynamic Heterogeneity

  • Published:
Journal of Engineering Physics and Thermophysics Aims and scope

Abstract

The spectra of relaxation times of polymer meshes in the presence of various types of structural and dynamic heterogeneity have been considered. The influence of the orientation ordering of elements of macromolecules between the mesh nodes on the intrachain spectrum has been investigated. Analysis of the interchain large‐scale processes in polymer meshes containing rodlike inclusions has been carried out. It has been shown that the presence of structural and dynamic heterogeneity of the above types along with the previously considered domain structure of cross‐linked polymers leads to a fine structure of the relaxation spectra of polymer meshes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. A. A. Gurtovenko and Yu. Ya. Gotlib, Macromolecules, 31, No. 17, 5756–5770 (1998).

    Google Scholar 

  2. A. A. Gurtovenko and Yu. Ya. Gotlib, Macromolecules, 33, No. 17, 6578–6587 (2000).

    Google Scholar 

  3. Yu. Ya. Gotlib and A. A. Gurtovenko, Macromol. Symposia, 171, 69–78 (2001).

    Google Scholar 

  4. A. A. Gurtovenko and Yu. Ya. Gotlib, Macromol. Theory Simul., 9, No. 7, 407–427 (2000).

    Google Scholar 

  5. A. A. Gurtovenko, Yu. Ya. Gotlib, and H.-G. Kilian, Macromol. Theory Simul., 9, No. 7, 388–397 (2000).

    Google Scholar 

  6. A. A. Gurtovenko, Yu. Ya. Gotlib, and H.-G. Kilian, Polymer Sci., Ser. A, 43, No. 3, 308–314 (2001).

    Google Scholar 

  7. A. A. Gurtovenko and Yu. Ya. Gotlib, J. Chem. Phys., 115, No. 14, 6785–6793 (2001).

    Google Scholar 

  8. J.-U. Sommer, J. Chem. Phys., 95, No. 2, 1316–1317 (1991).

    Google Scholar 

  9. H. G. Kilian, B. Zink, and R. Metzler, J. Chem. Phys., 107, No. 20, 8697–8705 (1997).

    Google Scholar 

  10. H. G. Kilian, W. Oppermann, B. Zink, and O. Marti, Comput. Theor. Polymer Sci., 8, No. 1, 99–111 (1998).

    Google Scholar 

  11. M. Kopf and H. G. Kilian, Acta Polym., 50, No. 4, 109–121 (1999).

    Google Scholar 

  12. K. L. Ngai, in R. Richert and A. Blumen (eds.), Disorder Effects on Relaxation Processes, Berlin (1994), pp. 89–151.

  13. G. Glatting, R. G. Winkler, and P. Reineker, Macromolecules, 28, No. 17, 5906–5909 (1995).

    Google Scholar 

  14. R. Richert and A. Blumen, in: R. Richert and A. Blumen (eds.), Disorder Effects on Relaxation Processes, Berlin (1994), pp. 1–7.

  15. Yu. Ya. Gotlib and V. P. Toshchevikov, Vysokomolek. Soed. A, 43, No. 5, 833–843 (2001).

    Google Scholar 

  16. Yu. Ya. Gotlib and V. P. Toshchevikov, Vysokomolek. Soed., Ser. A, 43, No. 10, 1844–1855 (2001).

    Google Scholar 

  17. P.-G. De Gennes, Macromolecules, 35, No. 9, 3785–3786 (2002).

    Google Scholar 

  18. J. P. Jarry and L. Monnerie, Macromolecules, 12, No. 2, 316–320 (1979).

    Google Scholar 

  19. V. V. Rusakov, Orientational Phase Transitions in Linear and Comblike Polymers, Candidate's Dissertation (in Physics and Mathematics), Perm' (1987).

  20. S. A. Abramchuk, I. A. Nyrkova, and A. R. Khokhlov, Vysokomolek. Soed. A, 31, No. 8, 1759–1765 (1989).

    Google Scholar 

  21. M. Warner and E. M. Terentjev, Progr. Polym. Sci., 21, 853–891 (1996).

    Google Scholar 

  22. X. J. Wang, Progr. Polym. Sci., 22, 735–764 (1997).

    Google Scholar 

  23. O. E. Philippova, R. Rulkens, B. Y. Kovtunenko, S. S. Abramchuk, A. R. Khokhlov, and G. Wegner, Macromolecules, 31, No. 4, 1168–1179 (1998).

    Google Scholar 

  24. Yu. Ya. Gotlib, I. A. Torchinskii, and V. P. Toshchevikov, in: Book of Abstracts of Papers Presented at 4th Int. Symp. "Molecular Order and Mobility in Polymer Systems," St. Petersburg, Russia, June 3–7 (2002), p. 106.

  25. Yu. Ya. Gotlib, I. A. Torchinskii, and V. P. Toshchevikov, Macromol. Theory Simul., 11, No. 8, 898–912 (2002).

    Google Scholar 

  26. Yu. Ya. Gotlib, Progr. Colloid Polym. Sci., 80, 245–253 (1989).

    Google Scholar 

  27. Yu. Ya. Gotlib, G. A. Medvedev, and S. V. Fridrikh, Macromol. Chem., Macromol. Symp., 65, 153–162 (1993).

    Google Scholar 

  28. Yu. Ya. Gotlib, A. A. Darinsky, L. I. Klushin, and I. M. Neelov, Acta Polymerica, 35, No. 3, 124–129 (1984).

    Google Scholar 

  29. A. A. Darinsky, Yu. Ya. Gotlib, A. V. Lyulin, and I. M. Neelov, Vysokomolek. Soed., Ser. A, 34, No. 1, 18–26 (1992).

    Google Scholar 

  30. Yu. Ya. Gotlib, A. A. Darinsky, and Yu. E. Svetlov, Physical Kinetics of Macromolecules [in Russian], Leningrad (1986).

  31. V. P. Toshchevikov, Orientational Order in Fine Cross-Linked Polymer Meshes: Electrolytic and Relaxation Characteristics, Candidate's Dissertation (Physics and Mathematics), St. Petersburg (2002).

Download references

Author information

Authors and Affiliations

  1. Russian Academy of Sciences, Institute of High‐Molecular Compounds, St. Petersburg

    Ya. Ya. Gotlib, A. A. Gurtovenko, I. A. Torchinskii, V. V. Toshchevikov & V. A. Shevelev

Authors
  1. Ya. Ya. Gotlib
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Gurtovenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Torchinskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Toshchevikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. A. Shevelev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gotlib, Y.Y., Gurtovenko, A.A., Torchinskii, I.A. et al. Theory of the Relaxation Spectra of Cross‐Linked Polymers in the Presence of Structural and Dynamic Heterogeneity. Journal of Engineering Physics and Thermophysics 76, 480–487 (2003). https://doi.org/10.1023/A:1024740124015

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024740124015

Keywords

Search

Navigation