Abstract
The association of dichloroanilines with different proton acceptors in CCl4 in the temperature range 290–330 K is studied using the IR absorption spectra in the region of stretching vibrations of an amino group. It is found that the position of maximum, halfwidth, and integral intensity of the ν(NH) absorbtion bands of free and H-bond molecules change almost linearly within the temperature range studied. The temperature dependence of constants of the equilibrium monomer – complex is examined, and thermodynamic characteristics of the complexes are calculated.
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Morev, A.V. A Spectroscopic Study of Thermodynamic Characteristics of Hydrogen-Bond Complexes of Dichloroanilines with Proton Acceptors. Russian Physics Journal 46, 165–168 (2003). https://doi.org/10.1023/A:1024646013285
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DOI: https://doi.org/10.1023/A:1024646013285