Abstract
Catalytic electroreduction of several substituted gem-dihalocyclopropanes was studied in the presence of metal salen-complexes by polarography, cyclic voltammetry, and preparative electrolysis. Monohalocyclopropanes (54—59%) and the corresponding allene (5—9%) were the main reduction products. The reaction rate constants were determined. The inner-sphere electron transfer was shown to occur under these conditions.
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Yanilkin, V.V., Strunskaya, E.I., Nastapova, N.V. et al. Metal complex electrocatalytic reduction of 1,1-dihalocyclopropanes. Russian Chemical Bulletin 52, 923–928 (2003). https://doi.org/10.1023/A:1024456510964
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DOI: https://doi.org/10.1023/A:1024456510964