Skip to main content
SpringerLink
Log in

Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I): a three-dimensional coordination polymer containing both molecular and anionic rod ligands

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Reaction of CuSCN with 2,5-dimethylpyrazine (2,5-me2pyz) yields a polymeric material, [Cu2(SCN)2(2,5-me2pyz)]∞, which has been crystallographically characterized. The compound crystallizes in the monoclinic space group P21/N with a = 5.6850(2) Å, b = 6.92877(3) Å, c = 14.3575(6) Å, β = 93.435(1)○, and Z = 2. It contains [Cu(SCN)]∞ sheets in which each thiocyanate ligand acts in a μ-N,S,S-bridging mode. The sheets are bridged by 2,5-dimethylpyrazine ligands to generate a three dimensional network. The compound has also been characterized by infrared spectroscopy and thermogravimetric analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Braga, D. J. Chem. Soc., Dalton Trans. 2000, 3705.

  2. Zaworotko, M.J. J. Chem. Soc., Chem. Commun. 2001, 1.

  3. Robson, R. J. Chem. Soc., Dalton Trans. 2000, 3735.

  4. Hoskins, B.F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546.

    Google Scholar 

  5. Lever, A.B.P.; Lewis, J.; Nyholm, R.S. Nature, 1961, 189, 58.

    Google Scholar 

  6. Lever, A.B.P.; Lewis, J.; Nyholm, R.S. J. Chem. Soc. 1963, 3156.

  7. Otieno, T.; Rettig, S.J.; Thompson, R.C.; Trotter, J. Can. J. Chem. 1989, 67, 1964.

    Google Scholar 

  8. Persky, N.S.; Chow, J.M.; Poschmann, K.A.; Lacuesta, N.N.; Stoll, S.L.; Bott, S.G.; Obrey, S. Inorg. Chem. 2001, 40, 29.

    PubMed  Google Scholar 

  9. Graham, M.G.; Pike, R.D.; Sabat, M.; Bailey, R.D.; Pennington, W.T. Inorg. Chem. 2000, 39, 5121.

    PubMed  Google Scholar 

  10. Roßenbeck, B.; Sheldrick, W.S. Z. Naturforsch., B 2000, 55, 467.

    Google Scholar 

  11. Teichert, O.; Sheldrick, W.S. Z. Anorg. Allg. Chem. 1999, 625, 1860.

    Google Scholar 

  12. Blake, A.J.; Brooks, N.R.; Champness, N.R.; Crew, M.; Hanton, L.R.; Hubberstey, P.; Parsons, S.; Shröder, M. J. Chem. Soc., Dalton Trans. 1999, 2813.

  13. Goher, M.A.S.; Mautner, F.A. Polyhedron, 1999, 18, 1805.

    Google Scholar 

  14. Goher, M.A.S.; Mautner, F.A. J. Chem. Soc., Dalton Trans. 1999, 1923.

  15. Siebel, E.; Ibrahim, A.M.A.; Fischer, R.D. Inorg. Chem. 1999, 38, 2530.

    Google Scholar 

  16. Kuhlman, R.; Schimek, G.L.; Kolis, J.W. Polyhedron 1999, 18, 1379.

    Google Scholar 

  17. Kawata, S.; Kitagawa, S.; Kumagai, H.; Iwabuchi, S.; Katada, M. Inorg. Chim. Acta 1998, 267, 143.

    Google Scholar 

  18. Begley, M.J.; Hubberstey, P.; Stroud, J. J. Chem. Soc., Dalton Trans. 1996, 2323.

  19. Moreno, J.M.; Suarez-Varela, J.; Colacio, E.; Avila-Rosón, J.C.; Hidalgo, M.A.; Martin-Ramos, D. Can. J. Chem. 1995, 73, 1591.

    Google Scholar 

  20. MacGillivray, L.R.; Subramanian, S.; Zaworotko, M.J. J. Chem. Soc., Chem. Commun. 1994, 1325.

  21. Otieno, T.; Rettig, S.J.; Thompson, R.C.; Trotter, J. Inorg. Chem. 1993, 32, 1607.

    Google Scholar 

  22. Kitagawa, S.; Kawata, S.; Kondo, M.; Nozaka, Y.; Munakata, M. Bull. Chem. Soc. Jpn. 1993, 66, 3387.

    Google Scholar 

  23. Kitagawa, S.; Munakata, M.; Tanimura, T. Inorg. Chem. 1992, 31, 1714.

    Google Scholar 

  24. Turnbull, M.M.; Pon, G.; Willett, R.D. Polyhedron, 1991, 10, 1835.

    Google Scholar 

  25. Otieno, T.; Rettig, S.J.; Thompson, R.C.; Trotter, J. Can. J. Chem. 1990, 68, 1901.

    Google Scholar 

  26. Otwinowski, Z.; Minor, W. In Methods of Enzymology: Macromolecular Crystallography, Part A; Carter, C.W., Jr.; Sweet, R.M., Eds.; Academic Press: New York, 1997; Vol. 276, pp. 307–326.

    Google Scholar 

  27. Sheldrick, G.M. SHELXS97, SHELXL97. Programs for the Solution and Refinement of Crystal Structures; University of Göttingen: Germany, 1997.

    Google Scholar 

  28. Healy, P.C.; Skelton, B.W.; Waters, A.F.; White, A.H. Aust. J. Chem. 1991, 44, 1049.

    Google Scholar 

  29. Gaughan, A.P.; Ziolo, R.F.; Dori, Z. Inorg. Chim. Acta, 1970, 4, 640.

    Google Scholar 

  30. Toeniskoetter, R.H.; Solomon, S. Inorg. Chem. 1968, 7, 617.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Eastern Kentucky University, Richmond, Kentucky, 40475-3102

    Tom Otieno, Jaime R. Blanton & Kena J. Lanham

  2. Department of Chemistry, University of Kentucky, Lexington, Kentucky

    Sean Parkin

Authors
  1. Tom Otieno
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jaime R. Blanton
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kena J. Lanham
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sean Parkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Tom Otieno.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Otieno, T., Blanton, J.R., Lanham, K.J. et al. Poly-μ-2,5-dimethylpyrazine-μ-dithiocyanato-N, S,S-dicopper(I): a three-dimensional coordination polymer containing both molecular and anionic rod ligands. Journal of Chemical Crystallography 33, 335–339 (2003). https://doi.org/10.1023/A:1024265611094

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1024265611094

Search

Navigation