Abstract
Experimental and theoretical data on the chlorine evolution in the region of large anodic currents, where a low-polarizability portion emerges in polarization curves, are exhaustively analyzed. It is shown that this practically horizontal portion must emerge upon reaching an overvoltage at which practically all macropores, rather than only the largest of them, are filled with gas. The dramatic increase in the current, observed in this case, is connected with the chlorine evolution reaction penetrating through the entire depth of the coating and results from the formation of a unified system of gas channels in the porous space of the coating. Chlorine evolved in micropores moves via these channels at a high speed to the front side of the electrode, moving away from it in the form of gas bubbles.
Similar content being viewed by others
References
Gorodetskii, V.V., Pecherskii, M.M., Yanke, V.B., et al., Elektrokhimiya, 1981, vol. 17, p. 513.
Gorodetskii, V.V., Doctoral (Chem.) Dissertation, Moscow: Russian Federation Scientific Center “Karpov Research Institute of Physical Chemistry,” 1991.
Evdokimov, S.V., Gorodetskii, V.V., and Losev, V.V., Elektrokhimiya, 1985, vol. 21, p. 1427.
Erenburg, R.G., IV Simpozium “Dvoinoi sloi i adsorbtsiya na tverdykh elektrodakh” (VI Symp. on Double Layer and Adsorption at Solid Electrodes), Tartu: Tartus. Gos. Univ., 1981, p. 382.
Krishtalik, L.I., Kokoulina, D.V., and Erenburg, R.G., Itogi Nauki Tekh., Ser.: Elektrokhimiya, 1982, vol. 20, p. 44.
Uzbekov, A.A. and Klement'eva, V.S., Elektrokhimiya, 1985, vol. 21, p. 758.
Zhinkin, N.V., Novikov, E.A., and Fedotova, N.S., Elektrokhimiya, 1989, vol. 26, p. 1094.
Bune, N.Ya., Serebrikova, E.V., and Losev, V.V., Elektrokhimiya, 1973, vol. 9, p. 894.
Gorodetskii, V.V., Evdokimov, S.V., and Kolotyrkin, Ya.M., Itogi Nauki Tekh., Ser.: Elektrokhimiya, 1991, vol. 34, p. 84.
Pecherskii, M.M., Gorodetskii, V.V., Evdokimov, S.V., and Losev, V.V., Elektrokhimiya, 1981, vol. 17, p. 1087.
Evdokimov, S.V., Yanovskaya, M.I., Roginskaya, Yu.E., et al., Elektrokhimiya, 1987, vol. 23, p. 1509.
Evdokimov, S.V., Gorodetskii, V.V., Yanovskaya, M.I., and Roginskaya, Yu.E., Elektrokhimiya, 1987, vol. 23, p. 1516.
Erenburg, R.G. and Krishtalik, L.I., Elektrokhimiya, 1987, vol. 23, p. 8.
Erenburg, R.G., Krishtalik, L.I., and Rogozhin, N.P., Elektrokhimiya, 1984, vol. 20, p. 1183.
Evdokimov, S.V. and Gorodetskii, V.V., Elektrokhimiya, 1987, vol. 23, p. 1587.
Losev, V.V., Elektrokhimiya, 1981, vol. 17, p. 733.
Losev, V.V. and Selina, L.E., Elektrokhimiya, 1989, vol. 25, p. 1155.
Evdokimov, S.V. and Gorodetskii, V.V., Elektrokhimiya, 1989, vol. 25, p. 1139.
Chirkov, Yu.G., Elektrokhimiya, 2000, vol. 36, p. 526.
Rostokin, V.I. and Chirkov, Yu.G., Elektrokhimiya, 2000, vol. 36, p. 735.
Chirkov, Yu.G. and Chernenko, A.A., Elektrokhimiya, 2001, vol. 37, p. 546.
Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2001, vol. 37, p. 557.
Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2001, vol. 37, p. 336.
Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2001, vol. 37, p. 409.
Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2001, vol. 37, p. 987.
Chirkov, Yu.G. and Rostokin, V.I., Elektrokhimiya, 2001, vol. 37, p. 1107.
Markin, V.S., Chizmadzhev, Yu.A., and Chirkov, Yu.G., Dokl. Akad. Nauk SSSR, 1963, vol. 150, p. 596.
Pshenichnikov, A.G., Dokl. Akad. Nauk SSSR, 1963, vol. 148, p. 1121.
Chirkov, Yu.G. and Pshenichnikov, A.G., Elektrokhimiya, 1990, vol. 26, p. 1545.
Chirkov, Yu.G., Rostokin, V.I., and Pshenichnikov, A.G., Elektrokhimiya, 1991, vol. 27, p. 235.
Chirkov, Yu.G., Rostokin, V.I., and Pshenichnikov, A.G., Elektrokhimiya, 1993, vol. 29, p. 892.
Chirkov, Yu.G., Rostokin, V.I., and Pshenichnikov, A.G., Elektrokhimiya, 1996, vol. 32, p. 1090.
Roginskaya, Yu.E. and Morozova, O.V., Electrochim. Acta, 1995, vol. 40, p. 817.
Chirkov, Yu.G. and Pshenichnikov, A.G., Elektrokhimiya, 1984, vol. 20, p. 1542.
Chirkov, Yu.G. and Pshenichnikov, A.G., Itogi Nauki Tekh., Ser.: Elektrokhimiya, 1988, vol. 27, p. 199.
Burshtein, R.Kh., Vakhonin, V.A., Tarasevich, M.R., et al., in Toplivnye elementy (The Fuel Cells), Moscow: Nauka, 1968, p. 306.
Evdokimov, S.V., Mishenina, K.A., and Gorodetskii, V.V., Elektrokhimiya, 1988, vol. 24, p. 1475.
Pasmanik, M.I., Sass-Tisovskii, B.A., and Yakimenko, L.M., Spravochnik (A Reference Book), Moscow: Khimiya, 1966, p. 101.
Kokoulina, D.V., Ivanova, T.V., Krasovitskaya, Yu.I., et al., Elektrokhimiya, 1977, vol. 13, p. 1511.
Evdokimov, S.V., Elektrokhimiya, 1998, vol. 34, p. 979.
Evdokimov, S.V., Elektrokhimiya, 2000, vol. 36, p. 265.
Evdokimov, S.V., Elektrokhimiya, 2000, vol. 36, p. 552.
Evdokimov, S.V., Elektrokhimiya, 2000, vol. 36, p. 677.
Evdokimov, S.V., Elektrokhimiya, 2000, vol. 36, p. 687.
Korovin, N.V. and Feoktistov, A.F., Elektrokhimiya, 1970, vol. 6, p. 335.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gorodetskii, V.V. Chlorine Evolution on Highly Porous Metal Oxide Anodes and the Origin of the Low-Polarizability Portion in Polarization Curves at Large Currents. Russian Journal of Electrochemistry 39, 650–659 (2003). https://doi.org/10.1023/A:1024109512607
Issue Date:
DOI: https://doi.org/10.1023/A:1024109512607