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Kinetic features of oxidative addition of organic halides to the organonickel σ-complex

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Russian Chemical Bulletin Aims and scope

Abstract

Electrochemically generated organonickel σ-complexes were used as model compounds to study the kinetics of oxidative addition of ArNiIbpy to RX, the key stage of cross-coupling of organic halides (RX). The reaction rate constants were calculated, and the sequence of relative reactivity of RX toward the electrochemically generated MesNiIbpy complex was obtained.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    D. G. Yakhvarov, Yu. H. Budnikova & O. G. Sinyashin

Authors
  1. D. G. Yakhvarov
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  2. Yu. H. Budnikova
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  3. O. G. Sinyashin
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Yakhvarov, D.G., Budnikova, Y.H. & Sinyashin, O.G. Kinetic features of oxidative addition of organic halides to the organonickel σ-complex. Russian Chemical Bulletin 52, 567–569 (2003). https://doi.org/10.1023/A:1023986118211

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  • DOI: https://doi.org/10.1023/A:1023986118211

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