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Texture of zirconia obtained by forced hydrolysis of ZrOCl2 solutions

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Abstract

The structure and surface properties of ZrO2 strongly depend on its preparation. In the present work the impact of prolonged aging at basic conditions (pH = 9, T = 100°C, t = 48 h), on the phase composition and textural properties, obtained by calcination of the precipitate, was investigated using several techniques conjointly (DTA/TG, DSC, XRD, porosimetry). The thermal effects accompanying the ZrO2·xH2O gel formation, the coalescence of the particles and crystallization were evaluated and discussed in terms of the structural differences between the aged and non-aged samples.

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Authors and Affiliations

  1. Institute of Chemistry and Environment Protection, Szczecin Technical University, al. Piastów 42, 71-065, Szczecin, Poland

    P. Jakubus & M. Kurzawa

  2. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Cracow, Poland

    A. Adamski & Z. Sojka

Authors
  1. P. Jakubus
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  2. A. Adamski
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  3. M. Kurzawa
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  4. Z. Sojka
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Correspondence to P. Jakubus.

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Jakubus, P., Adamski, A., Kurzawa, M. et al. Texture of zirconia obtained by forced hydrolysis of ZrOCl2 solutions. Journal of Thermal Analysis and Calorimetry 72, 299–310 (2003). https://doi.org/10.1023/A:1023952627054

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