Abstract
The key factors influencing the Diels—Alder reaction rate at ambient and elevated pressures were elucidated using data on the reactivity of various diene—dienophile systems in usual and Lewis acid-catalyzed Diels—Alder reactions, the reaction enthalpy, complex formation, dissolution, and solvation, and the donor-acceptor properties of the reactants. It was found that taking account of both the orbital interaction energy and the balance of bond rupture and formation energies allows correct prediction of the reaction rate in the absence or in the presence of Lewis acids.
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References
A. S. Onishchenko, Dienovyi sintez [Diene Synthesis], Izd. Akad. Nauk SSSR, Moscow, 1963, 650 pp. (in Russian).
F. Fringuelli and A. Taticchi, The Diels-Alder Reaction: Selected Practical Methods, Wiley, New York, 2002, 340 pp.
S. Kobayashi and K. A. Jorgensen, Cycloaddition Reaction in Organic Synthesis, Wiley, New York, 2001, 332 pp.
O. Diels and K. Alder, Liebigs Ann. Chem., 1928, 98.
J. Sauer, Angew. Chem., 1966, 78, 233.
J. Sauer and R. Sustmann, Angew. Chem., 1980, 92, 773.
J. Sauer, H. Wiest, and A. Mielert, Chem. Ber., 1964, 97, 3183.
U. Rohr, J. Schatz, and J. Sauer, Eur. J. Org. Chem., 1998, 1, 2875.
F. G. Klarner and M. K. Diedrich, in The Chemistry of Dienes and Polyenes, J. Wiley, New York, 1997, 547.
U. Deiters, F. G. Klarner, B. Krawczyk, and V. Ruster, J. Am. Chem. Soc., 1994, 116, 7646.
K. N. Houk and L. L. Munchausen, J. Am. Chem. Soc., 1976, 98, 937.
K. N. Houk, Y. Li, and J. D. Ivanchek, Angew. Chem., Int. Ed. Engl., 1992, 31, 682.
R. Sustmann, M. Bohm, and J. Sauer, Chem. Ber., 1979, 112, 883.
R. Sustmann and R. Schubert, Angew. Chem., 1972, 89, 888.
A. I. Konovalov, D.Sc. Thesis (chem.), Kazan. State Univ., Kazan, 1973, 306 pp. (in Russian).
V. D. Kiselev, D.Sc. Thesis (chem.), Kazan. State Univ., Kazan, 1986, 373 pp. (in Russian).
Ya. D. Samuilov, D.Sc. Thesis (chem.), Kazan. State Univ., Kazan, 1984, 387 pp. (in Russian).
A. I. Konovalov, in Stroenie i reaktsionnaya sposobnost' organicheskikh soedinenii [Structure and Reactivity of Organic Compounds], Nauka, Moscow, 1978, 259 (in Russian).
A. I. Konovalov, Usp. Khim., 1983, 52, 1852 [Russ. Chem. Rev., 1983, 52 (Engl. Transl.)].
V. D. Kiselev and A. I. Konovalov, Usp. Khim., 1989, 58, 383 [Russ. Chem. Rev., 1989, 58 (Engl. Transl.)].
A. I. Konovalov, Zh. Org. Khim., 1969, 5, 1713 [J. Org. Chem. USSR, 1969, 5 (Engl. Transl.)].
B. A. Arbuzov, A. I. Konovalov, and Yu. Yu. Samitov, Dokl. Akad. Nauk SSSR, 1963, 143, 109 [Dokl. Chem., 1963 (Engl. Transl.)].
A. I. Konovalov, Dokl. Akad. Nauk SSSR, 1965, 162, 343 [Dokl. Chem., 1965 (Engl. Transl.)].
A. I. Konovalov and B. N. Solomonov, Dokl. Akad. Nauk SSSR, 1972, 202, 1331 [Dokl. Chem., 1972 (Engl. Transl.)].
A. I. Konovalov, B. N. Solomonov, and A. N. Ustyugov, Dokl. Akad. Nauk SSSR, 1973, 211, 102 [Dokl. Chem., 1973 (Engl. Transl.)].
A. I. Konovalov, Dokl. Akad. Nauk SSSR, 1963, 149, 1334 [Dokl. Chem., 1963 (Engl. Transl.)].
A. I. Konovalov, A. N. Vereshchagin, and G. I. Kamasheva, Dokl. Akad. Nauk SSSR, 1969, 185, 597 [Dokl. Chem., 1969 (Engl. Transl.)].
A. I. Konovalov, G. I. Kamasheva, and M. P. Loskutov, Dokl. Akad. Nauk SSSR, 1971, 201, 363 [Dokl. Chem., 1971 (Engl. Transl.)].
A. I. Konovalov, G. I. Kamasheva, and M. P. Loskutov, Zh. Org. Khim., 1972, 8, 2088 [J. Org. Chem. USSR, 1972, 8 (Engl. Transl.)].
A. I. Konovalov and G. I. Kamasheva, Zh. Org. Khim., 1972, 8, 1446 [J. Org. Chem. USSR, 1972, 8 (Engl. Transl.)].
A. I. Konovalov and G. I. Kamasheva, Zh. Org. Khim., 1972, 8, 1831 [J. Org. Chem. USSR, 1972, 8 (Engl. Transl.)].
A. I. Konovalov and G. I. Kamasheva, Zh. Org. Khim., 1973, 9, 2048 [J. Org. Chem. USSR, 1973, 9 (Engl. Transl.)].
N. R. Adigezalov, V. D. Kiselev, and A. I. Konovalov, Zh. Org. Khim., 1989, 25, 542 [J. Org. Chem. USSR, 1989, 25 (Engl. Transl.)].
V. D. Kiselev, N. R. Adigezalov, I. A. Akhmedov, and A. I. Konovalov, Zh. Org. Khim., 1989, 25, 548 [J. Org. Chem. USSR, 1989, 25 (Engl. Transl.)].
N. R. Adigezalov, V. D. Kiselev, and A. I. Konovalov, Zh. Org. Khim., 1989, 25, 1147 [J. Org. Chem. USSR, 1989, 25 (Engl. Transl.)].
V. D. Kiselev, A. G. Sakhabutdinov, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1990, 26, 2625 [J. Org. Chem. USSR, 1990, 26 (Engl. Transl.)].
V. D. Kiselev, V. B. Malkov, G. V. Akhmetzyanova, and A. I. Konovalov, Zh. Org. Khim., 1990, 26, 240 [J. Org. Chem. USSR, 1990, 26 (Engl. Transl.)].
V. D. Kiselev, A. G. Sakhabutdinov, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1991, 27, 1641 [J. Org. Chem. USSR, 1991, 27 (Engl. Transl.)].
V. D. Kiselev, A. G. Sakhabutdinov, I. M. Shakirov, V. V. Zverev, and A. I. Konovalov, Zh. Org. Khim., 1992, 28, 2244 [Russ. J. Org. Chem., 1992, 28 (Engl. Transl.)].
R. B. Woodward and R. Hoffmann, Angew. Chem., 1969, 81, 797.
H. Fujimoto, S. Inagaki, and K. Fukui, J. Am. Chem. Soc., 1976, 98, 2670.
J. Sauer and H. Wiest, Angew. Chem., 1962, 74, 353.
A. I. Konovalov, Ya. D. Samuilov, L. F. Slepova, and V. A. Breus, Zh. Org. Khim., 1973, 9, 2086 [J. Org. Chem. USSR, 1973, 9 (Engl. Transl.)].
A. I. Konovalov, Ya. D. Samuilov, L. F. Slepova, and V. A. Breus, Zh. Org. Khim., 1973, 9, 2519 [J. Org. Chem. USSR, 1973, 9 (Engl. Transl.)].
A. I. Konovalov, L. F. Uryadova, and Ya. D. Samuilov, Zh. Org. Khim., 1976, 12, 2610 [J. Org. Chem. USSR, 1976, 12 (Engl. Transl.)].
Yu. A. Arbuzov, Usp. Khim., 1964, 33, 913 [Russ. Chem. Rev., 1964, 33 (Engl. Transl.)].
K. Alder and G. Shtein, Angew. Chem., 1937, 50, 510.
G. Briegleb, Angew. Chem., Int. Ed. Engl., 1964, 3, 617.
M. V. Basilevsky, A. G. Shamov, and V. A. Tikhomirov, J. Am. Chem. Soc., 1977, 99, 1369.
R. Foster, Organic Charge-Transfer-Complexes, Academic Press, London-New York, 1960, 470 pp.
A. I. Konovalov, V. D. Kiselev, and O. A. Vigdorovich, Zh. Org. Khim., 1967, 3, 2085 [J. Org. Chem. USSR, 1967, 3 (Engl. Transl.)].
A. I. Konovalov, V. D. Kiselev, and Ya. D. Samuilov, Dokl. Akad. Nauk SSSR, 1968, 179, 866 [Dokl. Chem., 1968 (Engl. Transl.)].
A. I. Konovalov and V. D. Kiselev, Zh. Org. Khim., 1974, 10, 6 [J. Org. Chem. USSR, 1974, 10 (Engl. Transl.)].
A. Mielert, C. Braig, J. Sauer, J. Martelli, and R. Sustmann, Liebigs Ann. Chem., 1980, 954.
V. D. Kiselev, A. N. Ustyugov, I. P. Breus, and A. I. Konovalov, Dokl. Akad. Nauk SSSR, 1977, 234, 1089 [Dokl. Chem., 1977 (Engl. Transl.)].
A. I. Konovalov, B. N. Solomonov, and A. N. Ustyugov, Dokl. Akad. Nauk SSSR, 1973, 213, 349 [Dokl. Chem., 1973 (Engl. Transl.)].
S. Rucker, D. Lang, J. Sauer, H. Friege, and R. Sustmann, Chem. Ber., 1980, 113, 1663.
A. I. Konovalov and V. D. Kiselev, Zh. Org. Khim., 1966, 2, 142 [J. Org. Chem. USSR, 1966, 2 (Engl. Transl.)].
A. I. Konovalov and V. D. Kiselev, Zh. Org. Khim., 1986, 22, 1133 [J. Org. Chem. USSR, 1986, 22 (Engl. Transl.)].
A. Streitwieser, Molecular Orbital Theory for Organic Chemists, J. Wiley, New York-London, 1961, 436 pp.
L. V. Gurvich, G. V. Karachentsev, V. N. Kondrat'ev, Yu. A. Lebedev, V. A. Medvedev, V. K. Potapov, and Yu. S. Khodeev, Energii razryva svyazei. Potentsialy ionizatsii i srodstvo k elektronu [Bond Cleavage Energies. Ionization Potentials and Electron Affinity], Nauka, Moscow, 1974, 351 pp. (in Russian).
V. D. Kiselev, A. I. Konovalov, E. A. Weisman, and A. N. Ustyugov, Zh. Org. Khim., 1978, 14, 128 [J. Org. Chem. USSR, 1978, 14 (Engl. Transl.)].
V. D. Kiselev, A. N. Ustyugov, and A. I. Konovalov, Kinetika i termokhimiya reaktsii Dil'sa-Al'dera [Kinetics and Thermochemistry of the Diels-Alder Reaction], Moscow, 1977, 8 pp.; dep. in VINITI 23.06.77, 2503–77 (in Russian).
V. D. Kiselev, I. P. Breus, and A. I. Konovalov, Kineticheskoe i termokhimicheskoe izuchenie reaktsii Dil'sa-Al'dera [Kinetic and Thermochemical Study of the Diels-Alder Reaction], Part 1, Moscow, 1977, 15 pp.; dep. in VINITI 28.06.77, 2606 (in Russian).
V. D. Kiselev, G. V. Mavrin, and A. I. Konovalov, Kineticheskoe i termokhimicheskoe izuchenie reaktsii Dil'sa-Al'dera [Kinetic and Thermochemical Study of the Diels-Alder Reaction], Part 3, Cherkassy, 1980, 4 pp.; dep. in ONIITEKhIM2.01.80, 10-khp-D-80 (in Russian).
R. P. Bell, Acid-Base Catalysis, Oxford Univ. Press, New York, 1941, 212 pp.
M. G. Evans and M. Polanyi, Trans. Faraday Soc., 1936, 32, 1333.
N. N. Semenov, O nekotorykh problemakh khimicheskoi kinetiki i reaktsionnoi sposobnosti [Some Problems of Chemical Kinetics and Reactivity], Izd. Akad. Nauk SSSR, Moscow, 1958, 68 pp. (in Russian).
G. E. Leffler and E. Grundwald, Rates and Equilibria of Organic Reactions, J. Wiley, New York, 1963, 350 pp.
L. J. Andrews and R. M. Keefer, J. Am. Chem. Soc., 1955, 75, 3776.
V. D. Kiselev and J. G. Miller, J. Am. Chem. Soc., 1975, 97, 4036.
B. A. Arbuzov and A. I. Konovalov, Izv. Akad. Nauk SSSR, Ser. Khim., 1959, 2130 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1959, 8 (Engl. Transl.)].
B. A. Arbuzov and A. I. Konovalov, Izv. Akad. Nauk SSSR, Ser. Khim., 1960, 68 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1960, 9, 59 (Engl. Transl.)].
B. A. Arbuzov and A. I. Konovalov, Izv. Akad. Nauk SSSR, Ser. Khim., 1965, 1290 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1965, 14, 1260 (Engl. Transl.)].
A. I. Konovalov, V. D. Kiselev, and Ya. D. Samuilov, Dokl. Akad. Nauk SSSR, 1969, 186, 347 [Dokl. Chem., 1969 (Engl. Transl.)].
A. I. Konovalov, V. D. Kiselev, and M. B. Metelina, Zh. Org. Khim., 1970, 6, 1548 [J. Org. Chem. USSR, 1970, 6 (Engl. Transl.)].
V. D. Kiselev, G. V. Mavrin, and A. I. Konovalov, Zh. Org. Khim., 1980, 16, 1435 [J. Org. Chem. USSR, 1980, 16 (Engl. Transl.)].
V. D. Kiselev, O. A. Zabotina, E. A. Weisman, and A. I. Konovalov, Zh. Org. Khim., 1983, 19, 1617 [J. Org. Chem. USSR, 1983, 19 (Engl. Transl.)].
V. D. Kiselev, E. A. Weisman, and A. I. Konovalov, Zh. Org. Khim., 1985, 21, 1145 [J. Org. Chem. USSR, 1985, 21 (Engl. Transl.)].
V. D. Kiselev, V. B. Malkov, and A. I. Konovalov, Zh. Org. Khim., 1991, 27, 922 [J. Org. Chem. USSR, 1991, 27 (Engl. Transl.)].
E. A. Kashaeva, Ph.D. Thesis (chem.), Kazan State Univ., Kazan, 1987, 211 pp. (in Russian).
I. M. Shakirov, Ph.D. Thesis (chem.), Kazan State Univ., Kazan, 1985, 143 pp. (in Russian).
V. D. Kiselev, A. I. Konovalov, G. V. Mavrin, E. E. Korshin, and M. N. Dimukhametov, Kineticheskoe i termokhimicheskoe izuchenie reaktsii Dil'sa-Al'dera [Kinetic and Thermochemical Study of the Diels-Alder Reaction], Part 4, Cherkassy, 1980, 18 pp.; dep. in ONIITEKhIM 24.06.80, 60-khp-D-80 (in Russian).
G. V. Mavrin, Ph.D. Thesis (chem.), Kazan State Univ., Kazan, 1980, 157 pp. (in Russian).
V. D. Kiselev, G. V. Mavrin, and A. I. Konovalov, Zh. Org. Khim., 1982, 18, 2505 [J. Org. Chem. USSR, 1982, 18 (Engl. Transl.)].
V. D. Kiselev, D. G. Khuzyasheva, and A. I. Konovalov, Zh. Org. Khim., 1983, 19, 1268 [J. Org. Chem. USSR, 1983, 19 (Engl. Transl.)].
V. D. Kiselev, I. M. Shakirov, D. G. Khuzyasheva, and A. I. Konovalov, Zh. Org. Khim., 1983, 19, 2064 [J. Org. Chem. USSR, 1983, 19 (Engl. Transl.)].
V. D. Kiselev, D. G. Khuzyasheva, and A. I. Konovalov, Zh. Org. Khim., 1983, 19, 884 [J. Org. Chem. USSR, 1983, 19 (Engl. Transl.)].
V. D. Kiselev, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1984, 20, 1454 [J. Org. Chem. USSR, 1984, 20 (Engl. Transl.)].
V. D. Kiselev, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1985, 21, 1215 [J. Org. Chem. USSR, 1985, 21 (Engl. Transl.)].
V. D. Kiselev, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1985, 21, 665 [J. Org. Chem. USSR, 1985, 21 (Engl. Transl.)].
V. D. Kiselev, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1986, 22, 311 [J. Org. Chem. USSR, 1986, 22 (Engl. Transl.)].
V. D. Kiselev, I. M. Shakirov, and A. I. Konovalov, Zh. Org. Khim., 1986, 22, 1034 [J. Org. Chem. USSR, 1986, 22 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, and A. I. Konovalov, Zh. Obshch. Khim., 2002, 72, 1898 [Russ. J. Gen. Chem., 2002, 72 (Engl. Transl.)].
J. Sauer and J. Kredel, Angew. Chem., 1965, 77, 1037.
Yu. G. Shtyrlin, V. D. Kiselev, D. G. Murzin, O. N. Sadyukova, and A. I. Konovalov, Zh. Org. Khim., 1993, 29, 1713 [Russ. J. Org. Chem., 1993, 29 (Engl. Transl.)].
D. G. Murzin, Yu. G. Shtyrlin, O. N. Sadyukova, V. D. Kiselev, and A. I. Konovalov, Zh. Org. Khim., 1994, 30, 150 [Russ. J. Org. Chem., 1994, 30 (Engl. Transl.)].
V. D. Kiselev, Yu. G. Shtyrlin, D. G. Murzin, and A. I. Konovalov, Dokl. Akad. Nauk, 1995, 345, 64 [Dokl. Chem., 1995 (Engl. Transl.)].
Yu. G. Shtyrlin, D. G. Murzin, G. G. Iskhakova, N. F. Luzanova, V. D. Kiselev, and A. I. Konovalov, Tetrahedron, 1998, 54, 2631.
V. D. Kiselev, E. A. Kashaeva, N. A. Luzanova, and A. I. Konovalov, Zh. Obshch. Khim., 1997, 67, 1449 [Russ. J. Gen. Chem., 1997, 67 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, N. A. Luzanova, and A. I. Konovalov, Thermochim. Acta, 1997, 303, 225.
M. G. Gonikberg, Khimicheskoe ravnovesie i skorost' reaktsii pri vysokikh davleniyakh [Chemical Equilibrium and Reaction Rate at High Pressures], Khimiya, Moscow, 1969, 427 pp. (in Russian).
A. Drljaca, C. D. Hubbard, R. van Eldik, T. Asano, M. A. Basilevsky, and W. J. le Noble, Chem. Rev., 1998, 98, 2167.
O. Exner, in Organic High Pressure Chemistry, Elsevier, Amsterdam-Oxford-New York-Tokyo, 1988, 50.
F. J. Millero, Chem. Rev., 1971, 71, 147.
R. E. Merrifield and W. D. Phillips, J. Am. Chem. Soc., 1958, 80, 2778.
V. D. Kiselev, E. A. Kashaeva, and A. I. Konovalov, Zh. Obshch. Khim., 1999, 69, 1401 [Russ. J. Gen. Chem., 1999, 69 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, M. S. Shikhab, M. D. Medvedeva, and A. I. Konovalov, Izv. Akad. Nauk, Ser. Khim., 2000, 1040 [Russ. Chem. Bull., Int. Ed., 2000, 49, 1046].
V. D. Kiselev, E. A. Kashaeva, M. S. Shihab, and A. I. Konovalov, Mendeleev Commun., 2000, 49.
V. D. Kiselev, A. I. Konovalov, T. Asano, G. G. Iskhakova, E. A. Kashaeva, M. S. Shihab, and M. D. Medvedeva, J. Phys. Org. Chem., 2001, 14, 636.
V. D. Kiselev, M. S. Shikhab, G. G. Iskhakova, and A. I. Konovalov, Zh. Obshch. Khim., 2002, 72, 106 [Russ. J. Gen. Chem., 2002, 72 (Engl. Transl.)].
RF Pat. 2161790, 2001.
RF. Pat. 2188408, 2002.
V. D. Kiselev, E. A. Kashaeva, V. P. Dmitriev, and A. I. Konovalov, Zh. Obshch. Khim., 1998, 68, 1690 [Russ. J. Gen. Chem., 1998, 68 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, and A. I. Konovalov, Mendeleev Commun., 1998, 192.
V. D. Kiselev and A. I. Konovalov, Dokl. Akad. Nauk, 1998, 363, 780 [Dokl. Chem., 1998 (Engl. Transl.)].
V. D. Kiselev and A. I. Konovalov, Ros. Khim. Zh., 1999, 43, 94 [Mendeleev Chem. J., 1999, 43 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, and A. I. Konovalov, Tetrahedron, 1999, 55, 1153.
V. D. Kiselev, M. D. Medvedeva, E. A. Kashaeva, M. S. Shikhab, G. G. Iskhakova, and A. I. Konovalov, Zh. Org. Khim., 2002, 72, 465 [Russ. J. Org. Chem., 2002, 72 (Engl. Transl.)].
Y. Goto, T. Takahashi, Y. Ohga, and T. Asano, Abstr. of 16th IUPAC Conf. on Physical-Organic Chemistry, San Diego (USA), 2002, LD11.
B. S. El'yanov and E. M. Gonigberg, J. Chem. Soc., Faraday Trans. 1, 1979, 75, 172.
B. S. El'yanov and E. M. Vasylvitskaya, Rev. Phys. Chem. Jpn., 1980, 50, 169.
V. D. Kiselev, E. A. Kashaeva, G. G. Iskhakova, M. Shihab, and A. I. Konovalov, Tetrahedron, 1999, 55, 12201.
V. D. Kiselev, G. G. Iskhakova, M. S. Shikhab, E. A. Kashaeva, and A. I. Konovalov, Dokl. Akad. Nauk, 1999, 367, 185 [Dokl. Chem., 1999 (Engl. Transl.)].
K. Jurczak, in Organic High Pressure Chemistry, Elsevier, Amsterdam-Oxford-New York-Tokyo, 1988, 304.
W. G. Dauben, J. M. Gerdes, and D. B. Smith, J. Org. Chem., 1985, 50, 2576.
J. Sauer, B. Schroder, and A. Mielert, Chem. Ber., 1967, 100, 315.
V. D. Kiselev, G. G. Iskhakova, Yu. G. Shtyrlin, and A. I. Konovalov, Zh. Org. Khim., 1993, 29, 1111 [Russ. J. Org. Chem., 1993, 29 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, and A. I. Konovalov, Zh. Obshch. Khim., 2001, 71, 1277 [Russ. J. Gen. Chem., 2001, 71 (Engl. Transl.)].
V. D. Kiselev, E. A. Kashaeva, G. G. Iskhakova, M. S. Shikhab, and A. I. Konovalov, Zh. Obshch. Khim., 2003, 73, 233 [Russ. J. Gen. Chem., 2003, 73 (Engl. Transl.)].
A. I. Konovalov and V. D. Kiselev, Abstr. Int. Conf. on the Reaction Mechanisms and Organic Intermediates, S. Petersburg, Russia, 2001, 71.
V. D. Kiselev, G. G. Iskhakova, E. A. Kashaeva, and A. I. Konovalov, Abstr. of 16th IUPAC Conf. on Physical-Organic Chemistry, San Diego (USA), 2002, LC22.
V. D. Kiselev and A. I. Konovalov, Abstr. of 15th IUPAC Conf. on Physical-Organic Chemistry, Göteborg (Sweden), 2000, 50.
Yu. G. Shtyrlin, V. Yu. Fedorenko, G. G. Iskhakova, V. D. Kiselev, and A. I. Konovalov, Zh. Obshch. Khim., 1996, 66, 499 [Russ. J. Gen. Chem., 1996, 66 (Engl. Transl.)].
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Konovalov, A.I., Kiselev, V.D. Diels—Alder reaction. Effect of internal and external factors on the reactivity of diene—dienophile systems. Russian Chemical Bulletin 52, 293–311 (2003). https://doi.org/10.1023/A:1023486127587
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DOI: https://doi.org/10.1023/A:1023486127587