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C-Thiocarbamoylation of Electron-Rich Heterocycles and Enamines with Amidophosphonium Isothiocyanates

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Abstract

Amidophosphonium isothiocyanates thiocarbamoylate a series of electron-rich heterocycles and enamines at the nucleophilic carbon atom to form phosphazothiocarbonyl compounds. From the most active heterocycles, bis(phosphazothiocarbonyl) derivatives can be obtained.

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Authors and Affiliations

  1. National Academy of Sciences of Ukraine, Institute of Organic Chemistry, Kiev, Ukraine

    R. V. Smalii, G. N. Koidan, A. A. Chaikovskaya, A. P. Marchenko, A. M. Pinchuk & A. A. Tolmachev

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  1. R. V. Smalii
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  2. G. N. Koidan
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  3. A. A. Chaikovskaya
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  4. A. P. Marchenko
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  5. A. M. Pinchuk
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  6. A. A. Tolmachev
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Smalii, R.V., Koidan, G.N., Chaikovskaya, A.A. et al. C-Thiocarbamoylation of Electron-Rich Heterocycles and Enamines with Amidophosphonium Isothiocyanates. Russian Journal of General Chemistry 72, 1688–1694 (2002). https://doi.org/10.1023/A:1023372725342

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  • DOI: https://doi.org/10.1023/A:1023372725342

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