Skip to main content
SpringerLink
Log in

Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The complexes of six organic carboxylic acids (containing {O,O} donor atoms) with Bu2Sn(IV)2+ and Ph3Sn(IV)+ with ligand to metal ratios of 1 : 1 and 1 : 2, were prepared by two different methods. The FtIR and Raman spectra clearly demonstrated that the organotin(IV) moieties react with the {O,O} atoms of the ligands. It was found that in most cases the -COO-group was chelated to the central metal ions, but monodentate coordination was also sometimes observed. Complex formation was accompanied by a rearrangement of the hydrogen-bonding network existing in the ligands. The complexes probably have polymeric structures. Comparison of the experimental Mössbauer D values with those calculated on the basis of the point charge model formalism revealed that the organotin(IV) moiety has a trigonal-bipyramidal (tbp) geometry, and in certain cases a tetrahedral (tetr) geometry too. Finally, the local structure of the maleic acid complex formed with Bu2Sn(IV)2+ was determined by an EXAFS method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Nagy, A kémia újabb eredményei (Novel Results in Chemistry), Akadémiai Kiadó, Budapest, Vol. 92, 2002.

    Google Scholar 

  2. M. Nath S. Pokharia R. Yadav, Coord. Chem. Rev., 215 (2001) 99.

    Google Scholar 

  3. J. M. Tsangaris D. R. Williams, Appl. Organomet. Chem., 5 (1991) 1.

    Google Scholar 

  4. L. Pellerito L. Nagy, Coord. Chem. Rev., 224 (2002) 111.

    Google Scholar 

  5. L. Nagy L. Korecz I. Kiricsi L. Zsikla K. Burger, Struct. Chem., 2 (1991) 231.

    Google Scholar 

  6. J. D. Donaldson S. M. Grimes L. Pellerito M. A. Girasolo P. J. Smith A. Cambria M. Fama, Polyhedron, 6 (1987) 383.

    Google Scholar 

  7. K. Burger L. Nagy N. BuzÁs A. VÉrtes H. Mehner, J. Chem. Soc. Dalton Trans., (1993) 2499.

  8. K. Burger L. Nagy N. BuzÁs A. VÉrtes H. Mehner, Magy. Kém. Foly., 99 (1993) 410.

    Google Scholar 

  9. N. BuzÁs M. A. Pujar L. Nagy E. Kuzmann A. VÉrtes H. Mehner, J. Radioanal. Nucl. Chem., 189 (1995) 237.

    Google Scholar 

  10. L. Nagy H. Mehner A. A. Christy E. Sletten F. T. Edelmann Q. M. Anderson, J. Radioanal. Nucl. Chem., 227 (1998) 89.

    Google Scholar 

  11. N. BuzÁs B. Gyurcsik L. Nagy X.-X. Zhang L. Korecz K. Burger, Inorg. Chim. Acta, 218 (1994) 65.

    Google Scholar 

  12. L. Nagy B. Gyurcsik K. Burger S. Yamashita T. Yamaguchi H. Wakita M. Nomura, Inorg. Chim. Acta, 230 (1995) 105.

    Google Scholar 

  13. B. Gyurcsik N. BuzÁs T. Gajda L. Nagy E. Kuzmann A. VÉrtes K. Burger, Z. Naturforsch., 5B (1995) 515.

    Google Scholar 

  14. N. BuzÁs T. Gajda E. Kuzmann L. Nagy A. VÉrtes K. Burger, Main Group Metal Chem., 18 (1995) 641.

    Google Scholar 

  15. N. BuzÁs T. Gajda L. Nagy E. Kuzmann A. VÉrtes K. Burger, Inorg. Chim. Acta, 274 (1998) 167.

    Google Scholar 

  16. A. JancsÓ L. Nagy E. Mordheim E. Sletten, J. Chem. Soc. Dalton. Trans., 1587 (1998).

  17. A. JancsÓ L. Nagy E. Mordheim E. Sletten, Magy. Kém. Foly., 106 (2000) 414.

    Google Scholar 

  18. K. Gajda-Schrantz L. Nagy T. Gajda L. Pellerito, J. Chem. Soc. Dalton Trans., 152 (2002).

  19. K. Schrantz L. Nagy E. Kuzmann A. VÉrtes J. Holacek A. Lycka, J. Chem. Soc. Dalton Trans., (1997) 2201.

  20. K. Schrantz L. Nagy E. Kuzmann A. VÉrtes J. Holacek A. Lycka, Magy. Kém. Foly., 106 (2000) 487.

    Google Scholar 

  21. M. Gielen A. El Khloufi M. Biesemans R. Willem, Appl. Organomet. Chem., 7 (1993) 119.

    Google Scholar 

  22. M. Gielen M. Biesemans A. El Khloufi J. Meunier-Piret F. Kayser R. Willem, J. Fluorine Chem., 64 (1992) 279.

    Google Scholar 

  23. M. Gielen A. El Khloufi D. De Vos J. Kolker J. H. M. Schellens R. Willem, Bull. Soc. Chim. Belge, 102 (1993) 761.

    Google Scholar 

  24. M. Gielen M. Boualam A. Meriem B. Mahieu M. Biesemans R. Willem, Heteroatom Chem., 3 (1992) 449.

    Google Scholar 

  25. M. Gielen M. Acheddad E. R. T. Tiekink, Main Group Met. Chem., 16 (1993) 367.

    Google Scholar 

  26. M. Gielen E. R. T. Tiekink A. Bouhdid D. De Vos M. Biesemans I. Verbruggen R. Willem, Appl. Organomet. Chem., 9 (1995) 639.

    Google Scholar 

  27. M. Gielen M. Boualam B. Mahieu E. R. T. Tiekink, Appl. Organomet. Chem., 8 (1994) 19.

    Google Scholar 

  28. S. W. Ng V. G. Kumar Das J. Holecek A. Lycka M. Gielen M. B. G. Drew, Appl. Organomet. Chem., 11 (1977) 239.

    Google Scholar 

  29. M. Gielen A. Bouhdid F. Kayser M. Biesemans D. De Vos B. Mahieu R. Willem, Appl. Organomet. Chem., 9 (1995) 251.

    Google Scholar 

  30. M. Boualam M. Biesemans J. Meunier-Piret R. Willem M. Gielen, Appl. Organomet. Chem., 6 (1992) 197.

    Google Scholar 

  31. R. Willem M. Biesemans M. Boualam A. Delmotte A. El Khloufi M. Gielen, Appl. Organomet. Chem., 7 (1993) 311.

    Google Scholar 

  32. R. Van Lambalgen P. Lelieveld, Invest. New Drugs, 5 (1987) 161.

    Google Scholar 

  33. G. B. Deacon R. J. Phillips, Coord. Chem. Rev., 33 (1980) 227.

    Google Scholar 

  34. N. W. Alcock J. Culver S. M. Roe, J. Chem. Soc. Dalton Trans., 1447 (1992).

  35. A. G. Davies, Organotin Chemistry, Ch. 11, VCH, Meinheim, 1995, and references therein.

    Google Scholar 

  36. K. Gajda-Schrantz L. Nagy E. Kuzmann A. VÉrtes, J. Radioanal. Nucl. Chem. 232 (1998) 151, and references therein.

    Google Scholar 

  37. G. M. Bancroft V. G. Kumar Das T. K. Sham M. G. J. Clark, J. Chem. Soc. Dalton Trans., 643 (1976).

  38. R. V. Parish, Structure and bonding in tin compounds, in: Mössbauer Spectroscopy Applied to Inorganic Chemistry, Vol. 1G. J. Long (Ed.), Plenum Press, New York, 1984, p. 527.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Biocoordination Chemistry Research Group of the Hungarian Academy of Sciences, Department of Inorganic and Analytical Chemistry, Szeged University, H-6701, Szeged, P.O. Box 440, Hungary

    A. Szorcsik

  2. Department of Inorganic and Analytical Chemistry, Szeged University, H-6701, Szeged, P.O. Box 440, Hungary

    L. Nagy

  3. Department of Inorganic Chemistry, University of Palermo Parco d'Orleans, Viale della Scienze, Palermo, Italy

    L. Pellerito

  4. Department of Chemistry, Faculty of Science, Fukuoka University, Nanakuma, Jonan-ku, Fukuoka, 814-01, Japan

    T. Yamaguchi & K. Yoshida

Authors
  1. A. Szorcsik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Nagy
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Pellerito
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Yamaguchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. Yoshida
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Szorcsik, A., Nagy, L., Pellerito, L. et al. Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids. Journal of Radioanalytical and Nuclear Chemistry 256, 3–10 (2003). https://doi.org/10.1023/A:1023315704880

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1023315704880

Keywords

Search

Navigation