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Synthesis of Monodisperse Polymethyl Methacrylate Particles in Buffer Solutions under the Action of Carboxyl-Containing Initiator

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Abstract

Influence exerted by salts with buffering action and by the initial pH of the reaction mixture on the polymerization kinetics, viscosity-average molecular weight, and amount and degree of surface carboxylation of polymethyl methacrylate particles formed in the course of emulsifier-free emulsion polymerization of methyl methacrylate initiated by 4,4'-azobis(4-cyanoisovaleric acid) was studied.

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Men'shikova, A.Y., Evseeva, T.G., Chekina, N.A. et al. Synthesis of Monodisperse Polymethyl Methacrylate Particles in Buffer Solutions under the Action of Carboxyl-Containing Initiator. Russian Journal of Applied Chemistry 75, 1993–1998 (2002). https://doi.org/10.1023/A:1023303918791

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  • DOI: https://doi.org/10.1023/A:1023303918791

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