Skip to main content
SpringerLink
Log in

Synthesis and X-ray crystallographic characterization of [Cd(NO3)2(15-Crown-5)] and [Cd(NO3)2(18-Crown-6)]

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Reaction of 15-crown-5 or 18-crown-6 in 3:1 (v/v) CH3CN:CH3OH with Cd(NO3)2·4H2O followed by slow evaporation produces [Cd(NO3)2(15-crown-5)] or [Cd(NO3)2(18-crown-6)]. Crystals of [Cd(NO3)2(15-crown-5)] are orthorhombic with space group Pbca and cell parameters a = 13.562(5), b = 15.941(9), and c = 15.011(7) Å at 295 K. [Cd(NO3)2(18-crown-6)] crystallizes in the monoclinic space group C2/c with a = 11.235(2), b = 11.196(5), c = 15.385(3) Å, and β = 99.89(2)° at 295 K. The metal center in [Cd(NO3)2(15-crown-5)] rests atop the macrocyclic donor array with two cis-bound nitrate anions and adopts a distorted tricapped trigonal prismatic geometry. [Cd(NO3)2(18-crown-6)] resides on an equatorial two-fold rotation axis with Cd2+ coordinated in the 18-crown-6 cavity and the nitrate anions oriented in twisted trans positions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Domingo, J.L. J. Toxicol. Environ. Health 1994, 42, 123.

    Google Scholar 

  2. Liu, G.; Elsner, J. Soz. Praventivmed. 1995, 40, 209.

    Google Scholar 

  3. Sekine, T.; Hasegawa, Y. Solvent Extraction Chemistry; Marcel Dekker: New York, 1977.

    Google Scholar 

  4. Principles and Practices of Solvent Extraction; Rydberg, J.; Musikas, C.; Choppin, G.R., Eds.; Marcel Dekker: New York, 1992.

    Google Scholar 

  5. Rogers, R.D.; Bond, A.H.; Bauer, C.B.; Zhang, J.; Jezl, M.L.; Roden, D.M.; Rein, S.D.; Chomko, R.R. In Aqueous Biphasic Separations: Biomolecules to Metal Ions; Rogers, R.D., Eiteman, M.A., Eds.; Plenum: New York, 1995; p 1.

    Google Scholar 

  6. Batterham, G.J.; Parry, D.L. Marine Chem. 1996, 55, 381.

    Google Scholar 

  7. Massart, D.L. “Nuclear Science Series, Radiochemical Techniques: Cation-Exchange Techniques in Radiochemistry” NAS-NS 3113; National Academy of Sciences, 1971.

  8. Kubova, J.; Hanakova, V.; Medved, J.; Stresko, V. Anal. Chim. Acta 1997, 337, 329.

    Google Scholar 

  9. Srivastava, S.K.; Gupta, V.K.; Jain, S. Electroanalysis 1996, 8, 938.

    Google Scholar 

  10. Mickler, W.; Reich, A.; Uhlemann, E.; Bart, H.J. J. Membr. Sci. 1996, 119, 91.

    Google Scholar 

  11. Smith, R.M.; Martell, A.E. Critical Stability Constants; Plenum Press: New York, 1974–77, 82, 89; Vols. 1–6.

    Google Scholar 

  12. Adam, K.R.; Dancey, K.P.; Harrison, B.A.; Leong, A.J.; Lindoy, L.F.; McPartlin, M.; Tasker, P.A. J. Chem. Soc., Chem. Commun. 1983, 1351.

  13. Adam, K.R.; Dancey, K.P.; Leong, A.J.; Lindoy, L.F.; McCool, B.J.; McPartlin, M.; Tasker, P.A. J. Am. Chem. Soc. 1988, 110, 8471.

    Google Scholar 

  14. Sessler, J.L.; Murai, T.; Lynch, V. Inorg. Chem. 1989, 28, 1333.

    Google Scholar 

  15. Thompson, J.A.; Barr, M.E.; Ford, D.K.; Silks, L.A., III; McCormick, J.; Smith, P.H. Inorg. Chem. 1996, 35, 2025.

    Google Scholar 

  16. Adam, K.R.; McCool, B.J.; Leong, A.J.; Lindoy, L.F.; Ansell, C.W.G.; Baillie, P.J.; Dancey, K.P.; Drummond, L.A.; Henrick, K.; McPartlin, M.; Uppal, D.K.; Tasker, P.A. J. Chem. Soc. Dalton Trans. 1990, 3435.

  17. Adam, K.R.; Donnelly, S.; Leong, A.J.; Lindoy, L.F.; McCool, B.J.; Bashall, A.; Dent, M.R.; Murphy, B.P.; McPartlin, M.; Fenton, D.E.; Tasker, P.A. J. Chem. Soc. Dalton Trans. 1990, 1635.

  18. Kimura, E.; Koike, T.; Shiota, T.; Iitaka, Y. Inorg. Chem. 1990, 29, 4621.

    Google Scholar 

  19. Adams, H.; Bailey, N.A.; Fenton, D.E.; Ford, I.G.; Kitchen, S.J.; Williams, M.G.; Tasker, P.A.; Leong, A.J.; Lindoy, L.F. J. Chem. Soc., Dalton Trans. 1991, 1665.

  20. Byriel, K.A.; Dunster, K.R.; Gahan, L.R.; Kennard, C.H.L.; Latten, J.L.; Swann, I.L.; Duckworth, P.A. Inorg. Chim. Acta 1993, 205, 191.

    Google Scholar 

  21. Wulfsberg, G.; Weiss, A. J. Chem. Soc. Dalton Trans. 1977, 1640.

  22. Murphy, P.D.; Stevens, W.C.; Cheung, T.T.P.; Lacelle, S.; Gerstein, B.C.; Kurtz, D.M., Jr. J. Am. Chem. Soc. 1981, 103, 4400.

    Google Scholar 

  23. Richardson, M.F. Inorg. Chem. 1990, 29, 3620.

    Google Scholar 

  24. Paige, C.R.; Richardson, M.E. Can. J. Chem. 1984, 62, 332.

    Google Scholar 

  25. Hazell, A. Acta Crystallogr. Sect. C 1988, 44, 88.

    Google Scholar 

  26. Hazell, A.; Hazell, R.G.; Holm, M.F.; Krogh, L. Acta Crystallogr. Sect. B 1991, 47, 234.

    Google Scholar 

  27. Hazell, A.; Hazell, R.G. Acta Crystallogr. Sect. C 1991, 47, 730.

    Google Scholar 

  28. Drew, M.G.B.; McFall, S.G.; Nelson, S.M. J. Chem. Soc. Dalton Trans. 1979, 575.

  29. Nazarenko, A.Y.; Rusanov, E.B. Pol. J. Chem 1995, 69, 1417.

    Google Scholar 

  30. Ito, H.; Ito, T. Acta Crystallogr. Sect. C 1985, 41, 1598.

    Google Scholar 

  31. Byriel, K.A.; Gahan, L.R.; Kennard, C.H.L.; Latten, J.L.; Healy, P.C. Aust. J. Chem. 1993, 46, 713.

    Google Scholar 

  32. Setzer, W.N.; Tang, Y.; Grant, G.J.; VanDerveer, D.G. Inorg. Chem. 1991, 30, 3652.

    Google Scholar 

  33. Malmsten, L.Å. Acta Crystallogr. Sect. B 1979, 35, 1702.

    Google Scholar 

  34. Rogers, R.D.; Bond, A.H.; Aguinaga, S.; Reyes, A. Inorg. Chim. Acta 1993, 212, 225.

    Google Scholar 

  35. Rogers, R.D.; Bond, A.H.; Aguinaga, S. J. Cryst. Spec. Res. 1993, 23, 857.

    Google Scholar 

  36. Rogers, R.D.; Bond, A.H. Inorg. Chim. Acta 1996, 250, 105.

    Google Scholar 

  37. Rogers, R.D.; Bond, A.H.; Wolff, J.L. J. Coord. Chem. 1993, 29, 187.

    Google Scholar 

  38. Rogers, R.D.; Bond, A.H. Inorg. Chim. Acta 1992, 192, 163.

    Google Scholar 

  39. Rogers, R.D.; Bond, A.H.; Roden, D.M. Inorg. Chem. 1996, 35, 6964.

    Google Scholar 

  40. Rogers, R.D.; Bond, A.H. J. Chem. Crystallogr. 1997, 27, 263.

    Google Scholar 

  41. Rogers, R.D.; Bond, A.H., Aguınaga, S. J. Am. Chem. Soc. 1992, 114, 2960.

    Google Scholar 

  42. Rogers, R.D.; Bond, A.H.; Aguınaga, S.; Reyes, A. J. Am. Chem. Soc. 1992, 114, 2967.

    Google Scholar 

  43. Luckay, R.; Cukrowskı, I.; Mashishı, J.; Reibenspıes, J.H., Bond, A.H.; Rogers, R.D.; Hancock, R.D. J. Chem. Soc. Dalton Trans. 1997, 901.

  44. Sheldrıck, G.M.; SHELX76 A System of Computer Programs as Locally Modified; University of Cambridge: Cambrıdge, England, 1976.

    Google Scholar 

  45. Sheldrıck, G.M.; SHELXS Acta Crystallogr. Sect. A 1990, 46, 467.

    Google Scholar 

  46. International Tables for X-Ray Crystallography; Kynoch Press: Birmingham, England (Present distributor: Kluwer Academıc Publıshers, Dordrecht); 1974; Vol. IV, p 72.

  47. Shannon, R.D. Acta Crystallogr. Sect. A 1976, 32, 751.

    Google Scholar 

  48. Fyles, T.M.; Gandour, R.D. J. Inclusıon Phenom. Mol. Recognıt. Chem. 1992, 12, 313.

    Google Scholar 

  49. Tkachev, V.V.; Atovmyan, L.O.; Zubareva, V.E.; Raevskıi, O.A. Koord. Khim. 1987, 13, 264.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Division, Argonne National Laboratory, 9700 S. Cass Ave., Argonne, Illinois, 60439

    Andrew H. Bond

  2. Department of Chemistry, The University of Alabama, Tuscaloosa, Alabama, 35487

    Robin D. Rogers

Authors
  1. Andrew H. Bond
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Robin D. Rogers
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bond, A.H., Rogers, R.D. Synthesis and X-ray crystallographic characterization of [Cd(NO3)2(15-Crown-5)] and [Cd(NO3)2(18-Crown-6)]. Journal of Chemical Crystallography 28, 521–527 (1998). https://doi.org/10.1023/A:1023239921542

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1023239921542

Search

Navigation