Abstract
The composition and structure of (M,Cu)(Sr,Ln)2(Ln,Ca,Sr)Cu2O8−δ phases, where M = B, Al, Cr, Pb, Bi, Ru, or Mo (1212 type), and (M,Cu)(Sr,Ln(2(Ln,Ce4+)2Cu2O10−δ phases, where M = V, Cr, Mn, Ru, or Mo (1222 type), have been determined. The role of the M cation in the formation of the crystal structures and the superconductivity phenomenon was analyzed. The relationship between the type of M cation and structural parameters was discovered.
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Kuz'micheva, G.M., Afanas'eva, I.N., Ésaulova, Y.V. et al. Dependence of the Structure and Properties of (M,Cu)Sr2(Ln,Ca)Cu2O8−δ (1212) and (M,Cu)Sr2(Ln,Ce4+)2Cu2O10−δ (1222) Phases on the Cation M. Journal of Structural Chemistry 43, 809–827 (2002). https://doi.org/10.1023/A:1022881409201
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DOI: https://doi.org/10.1023/A:1022881409201