Abstract
Conductivity measurements on aqueous solutions of sodium hydrogen tartrate and potassium hydrogen tartrate were performed in the temperature range 5–35°C. By including the dissociation equilibria, the experimental conductivities of the acidic salts can be well described using equivalent limiting conductivities of the bitartrate anion λ∞(HTar−) and the tartrate anion λ∞ (1/2 Tar2−) when applying the Quint and Viallard equations for unsymmetrical electrolytes.
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REFERENCES
M. Běster-Rogač, R. Neueder, J., Barthel, and A. Apelblat, J. Solution Chem. 26, 127 (1997).
M. Běster-Rogač, R. Neueder, J. Barthel, and A. Apelblat, J. Solution Chem. 26, 537 (1997).
C. W. Davies, J. Chem. Soc., 1850 (1939).
J. Quint and A. Viallard, J. Solution Chem. 7, 137, 525, 533 (1978).
J. Quint, Thesis, University of Clermont-Ferrand (1976).
J. Barthel, F. Feuerlein, R. Neueder, and R. Wachter, J. Solution Chem. 9, 209 (1980).
R. Wachter and J. Barthel, Ber. Bunsenges. Phys. Chem. 83, 634 (1979).
J. Barthel, R. Wachter and H.-J. Gores, in Modern Aspects of Electrochemistry, B. E. Conway and J. O'M. Bockris eds. Vol. 13 (Plenum Press, New York, 1979).
O. Kratky, H. Leopold, and H. Stabinger, Z. Angew. Phys. 27, 273 (1969).
K. N. Marsh, M. Spiro, and M. Selvaratnam, J. Phys. Chem. 67, 699 (1963).
M. Spiro and M. Selvaratnam, Rev. Port. Quim. 12, 1 (1970).
R. A. Robinson and R. H. Stokes, Electrolyte Solutions, 2nd rev. edn., (Butterworths, London, 1970).
N. E. Topp and C. W. Davies, J. Chem. Soc., 87 (1940).
M. Shamim and M. Spiro, Trans. Faraday Soc. 66, 2863 (1970).
H. S. Harned and B. B. Owen, The Physical Chemistry of Electrolytic Solutions, 3rd edn. (Reinhold, New York, 1958).
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Bešter-Rogač, M., Neueder, R., Barthel, J. et al. Conductivity Studies on Aqueous Solutions of Stereoisomers of Tartaric Acids and Tartrates. Part III. Acidic Tartrates. Journal of Solution Chemistry 27, 299–307 (1998). https://doi.org/10.1023/A:1022671414577
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DOI: https://doi.org/10.1023/A:1022671414577