Abstract
The molar and single-ion conductivities of dilute solutions of sodium chloride (C<0.01 mol-dm−3) in binary mixtures of 1,4-dioxane with water were measured covering a broad solvent composition range at temperatures from 5 to 35°C. Accurate viscosity and permittivity data were determined for the organic solvent system. Evaluation of the limiting molar conductivity Λ∞, ionic conductivities.Λ ∞+ , and Λ ∞− , and the association constant K A is based on the chemical model of electrolyte solutions, including short-range forces.
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REFERENCES
R. L. Kay and T. L. Broadwater, Electrochim. Acta 16, 667 (1971).
J. E. Lind and R. M. Fuoss, J. Phys. Chem. 65, 999, 1414 (1961); J. Phys. Chem. 66, 1727 (1962).
R. W. Kunze and R. M. Fuoss, J. Phys. Chem. 67, 911, 914 (1963).
T. M. Fabry and R. M. Fuoss, J. Phys. Chem. 68, 971 (1963).
J. C. Justice and R. M. Fuoss, J. Phys. Chem. 67, 1707 (1963).
C. F. Mattina and R. M. Fuoss, J. Phys. Chem. 79, 1604 (1975).
A. D'Aprano, F. Accasina, and R. M. Fuoss, J. Solution Chem. 19, 65 (1990).
M. C. Justice, J. C. Justice, and R. L. Kay J. Solution Chem. 19, 1211 (1990).
B. Das, Thermochim. Acta 44, 379 (1981).
L. A. Dunn and W. L. Marshall, J. Phys. Chem. 73, 2619 (1969).
E. Rousset, J. Barthel, and J. C. Justice, J. Solution Chem. 22, 571 (1993).
R. A. Robinson and R. H. Stokes, Electrolyte solutions, 2nd edn. (Butterworths, London, 1970).
J. Barthel, R. Wachter, and H.-J. Gores, in “Modern Aspects of Electrochemistry,” Vol. 13, B. E. Conway and J. O'M. Bockris, eds. (Plenum Press, New York, 1979).
D. E. Gray, American Institut of Physics and Handbook, 3rd edn. (McGraw-Hill, New York, 1972).
R. Wachter and J. Barthel, Ber. Bunsenges. Phys. Chem. 83, 634 (1979).
J. Barthel, F. Feuerlein, R. Neueder, and R. Wachter, J. Solution Chem. 9, 209 (1980).
M. Sakurai, J. Chem. Eng. Data 37, 492 (1992).
O. Kratky, H. Leopold, and H. Stabinger, Z. Angew. Phys. 27, 273 (1969).
J. Barthel, H. Krienke, and W. Kunz, Physical Chemistry of Electrolyte Solutions-Modern Aspects (Steinkoppf/Darmstadt, and Springer, New York, 1998).
J. Barthel and R. Neueder, in Electrolyte Data Collection, Part I, R. Eckermann and G. Kreysa, eds., (DECHEMA Chem. Data Ser., Vol VII, Frankfurt, 1992).
J. Barthel, J. C. Justice, and R. Wachter, Z. Phys. Chem. NF 84, 100 (1973).
S. B. Brummer and G. J. Hills, J. Chem. Soc. Faraday Trans. 57, 1816 (1961).
A. Fratiello and R. L. Kay, J. Solution Chemistry 3, 857 (1974).
J. Barthel, U. Ströder, L. Iberl, and H. Hammer, Ber. Bunsenges. Phys. Chem. 86, 636 (1982).
T. Erdey-Gruz, E. Kugler, I. Nagy-Czako, and K. Balthazar-Vass, Rev. Roum. Chim. 17, 137 (1972).
H. S. Harned and E. C. Dreby, J. Amer. Chem. Soc. 61, 3113 (1939).
J. E. Smith and E. B. Dismukes, J. Phys. Chem. 68, 1603 (1964).
R. Gopal and O. N. Bhatnagar, J. Phys. Chem. 71, 3007 (1967).
M. Ueno, S. I. and K. Shimizu, Bull. Chem. Soc. Jpn. 58, 1225 (1985).
J. S. Banait and G. S. Bhatti, J. Chem. Eng. Data 36, 121 (1991).
R. Gopal and J. S. Jha, Indian J. Chem. Sect. A 15, 80 (1977).
V. Vitagliano, Gazz. Chim. Ital. 90, 1847 (1960).
J. Perie, M. Perie, and J. C. Justice, J. Solution Chem. 9, 395 (1980).
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Bešter-Rogač, M., Neueder, R. & Barthel, J. Conductivity of Sodium Chloride in Water + 1,4-Dioxane Mixtures at Temperatures from 5 to 35°C I. Dilute Solutions. Journal of Solution Chemistry 28, 1071–1086 (1999). https://doi.org/10.1023/A:1022625310402
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DOI: https://doi.org/10.1023/A:1022625310402