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Effect of alumina in multicomponent bismuth phosphate catalyst supported on silica-alumina for propylene ammoxidation reaction

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Abstract

The effect of compositions of silica-alumina support on multicomponent bismuth phosphate catalyst (MBP) was investigated for the propylene ammoxidation. It is appears that small amounts of Al2O3 cause retardation of the ammoxidation reaction, which would be due to activation of the selective oxidation pathway. It is understood from such results that the catalytic action of the MBP is essentially different with that of the multicomponent bismuth molybdate catalyst (MBM), which is generally used as propylene ammoxidation catalyst.

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Authors and Affiliations

  1. Division of Advanced Chemical Technology, Korea Research Institute of Chemical Technology, Daejeon, 305-600, Korea

    Tae-Sun Chang, Dong-Koo Lee, Deug-Hee Cho & Sock-Sung Yun

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  1. Tae-Sun Chang
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  2. Dong-Koo Lee
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  3. Deug-Hee Cho
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  4. Sock-Sung Yun
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Chang, TS., Lee, DK., Cho, DH. et al. Effect of alumina in multicomponent bismuth phosphate catalyst supported on silica-alumina for propylene ammoxidation reaction. Reaction Kinetics and Catalysis Letters 78, 35–40 (2003). https://doi.org/10.1023/A:1022549529702

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  • DOI: https://doi.org/10.1023/A:1022549529702

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