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Structure effects of substituents located on the cyclohexene molecular skeleton in catalytic hydrogenations

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Abstract

Structure effects of various alkylcyclohexenes in heterogeneously catalyzed reactions are discussed. Experimentally evaluated adsorptivity and reactivity were interpreted by means of molecular modelling. Trends in these parameters are correlated with the properties of frontier orbitals.

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Author notes

  1. Leiv Låte

    Present address: Department of Industrial Chemistry, Norwegian University of Science and Technology, Trondheim, N-7034, Norvay

Authors and Affiliations

  1. Faculty of Chemical Technology, Institute of Chemical Technology Prague, Technicka 5, 166 28, Prague 6, Czech Republic

    Petr Kačer & Libor Červený

  2. Institute of Microbiology, Academy of Sciences of the Czech Republic, Videnska 1083, 142 20, Prague 4, Czech Republic

    Marek Kuzma

Authors
  1. Petr Kačer
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  2. Leiv Låte
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  3. Marek Kuzma
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  4. Libor Červený
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Correspondence to Libor Červený.

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Kačer, P., Låte, L., Kuzma, M. et al. Structure effects of substituents located on the cyclohexene molecular skeleton in catalytic hydrogenations. Reaction Kinetics and Catalysis Letters 78, 59–64 (2003). https://doi.org/10.1023/A:1022505714681

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  • DOI: https://doi.org/10.1023/A:1022505714681

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