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Molecular structure of AlH3[N(CH2CH2)3CH]2

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Abstract

Reaction of AlH3[N(CH2CH2)3CH] with hexamethyltrisiloxane, (OSiMe2)3, gives rise to the bis-quinuclidine complex AlH3[N(CH2CH2)3CH]2, which has been characterized by 1H and 13C NMR spectroscopy and X-ray crystallography. The molecular structure of AlH3[N(CH2CH2)3CH]2 consists of a trigonal bipyramidal aluminum with axial coordination of the quinuclidine ligands. Crystal data: orthorhombic, space group Pbcn, a = 10.6895(9), b = 12.266(1), c = 12.3794(9) Å, V = 1623.2(2) Å3, and Z = 4.

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Authors and Affiliations

  1. Department of Chemistry, Rice University, Houston, Texas, 77005

    C. Jeff Harlan & Andrew R. Barron

  2. Department of Chemistry, University of Houston, Houston, Texas, 77204

    Simon G. Bott

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  1. C. Jeff Harlan
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  2. Simon G. Bott
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  3. Andrew R. Barron
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Harlan, C.J., Bott, S.G. & Barron, A.R. Molecular structure of AlH3[N(CH2CH2)3CH]2 . Journal of Chemical Crystallography 28, 649–651 (1998). https://doi.org/10.1023/A:1022473312315

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  • DOI: https://doi.org/10.1023/A:1022473312315

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