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Crystal structure of [Co(o-SC6H4NH2){P(OMe)3}3]PF6

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Abstract

A cobalt-thiolato-phosphite complex [Co(o-SC6H4NH2){P(OMe)3}3]PF6 has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group \(P\bar 1\) with a = 10.590(4), b = 11.122(3), c = 13.577(5) Å, α = 101.85(1), β = 108.50(1), γ = 101.75(1)°, V = 1420.6(8) Å3, and Z = 2. The structure comprises discrete [Co(o-SC6H4NH2){P(OMe)3}3]+ cations and PF −6 anions where the metal atom is coordinated in a highly distorted square-pyramidal environment by one chelate o-SC6H4NH −2 (abt) and two P(OMe)3 ligands in the basal positions, and a third P(OMe)3 in the axial site with Co–N,, 1.847(5), Co–S, 2.166(2), Co–P, 2.157(2), 2.147(2), and 2.125(2) Å.

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References

  1. Cavell, K.J.; Hay, D.G.; Masters, A.F.; Williams, G.A. Aust. J. Chem. 1985, 38, 369.

    Google Scholar 

  2. Gimeno, M.C.; Jones, P.C.; Laguna, A.; Laguna, M.; Terroba, R. Inorg. Chem. 1994, 33, 3932.

    Google Scholar 

  3. Forward, J.M.; Bohmann, D.; Fackler, J.P.; Staples, R.J. Inorg. Chem. 1995, 34, 6330.

    Google Scholar 

  4. Kang, B.S.; Xu, Y.J.; Xie, X.L.; Chen, C.N.; Liu, Q.T.; Liu, H.Q.; Lu, J.X. Inorg. Chem. 1994, 33, 3770.

    Google Scholar 

  5. Kang, B.S.; Chen, Z.N.; Zhou, Z.Y.; Liu, H.Q.; Gao, H.R.; Wu, B.M.; Mak, T.C.W.; Cai, Y.B.; Xu, Y.J.; Xu, Z.T. J. Cluster Sci. 1996, 7, 317.

    Google Scholar 

  6. Sheldrick, G.M. SHELXTL-PLUS, User's Manual; Siemens Analytical X-ray Instrument Inc.: Madison, WI, 1990.

    Google Scholar 

  7. Sheldrick, G.M. SHELXs-97, Program for X-ray Crystal Structure Refinement; University of Göttingen: Germany, 1997.

    Google Scholar 

  8. International Tables for X-Ray Crystallography, Vol. C, Tables 4.2.6.8. and 6.1.1.4; Kluwer Academic Publisher: Dordecht, 1992.

  9. Farrugia, L.J. Ortep-3 for Windows; University of Glasgow: Glasgow G12 8QQ, Scotland, UK, 1997.

    Google Scholar 

  10. Kang, B.S.; Xu, Y.J.; Peng, J.H.; Wu, D.X.; Chen, X.T.; Hu, Y.H.; Hong, M.C.; Lu, J.X. Polyhedron 1993, 12, 871.

    Google Scholar 

  11. Bianchini, C.; Meli, A.; Orlandini, A. Inorg. Chem. 1982, 21, 4166.

    Google Scholar 

  12. Kang, B.S.; Peng, J.H.; Hong, M.C.; Wu, D.X.; Chen, X.T.; Weng, L.H.; Lei, X.J.; Liu, H.Q. J. Chem. Soc. Dalton Trans. 1991, 2897.

  13. Kang, B.S.; Chen, Z.N.; Tong, Y.X.; Liu, H.Q.; Gao, H.R.; Wu, B.M.; Mak, T.C.W. Polyhedron 1997, 16, 17317.

    Google Scholar 

  14. Chen, Z.N.; Zhang, H.X.; Kang, B.S.; Sun, J. Synth. React. Inorg. Met.-Org. Chem. 1998, 28, 245.

    Google Scholar 

  15. Chen, Z.N.; Kang, B.S.; Zhou, Z.Y.; Li, W.J.; Tong, Y.X.; Zhang, H.X.; Su, C.Y. Bull. Chem. Soc. Jpn. 1998, in press.

  16. Kang, B.S.; Wen, T.B.; Yu, X.Y.; Zhang, H.X.; Tong, Y.X.; Su, C.Y.; Chen, Z.N.; Liu, H.Q. J. Cluster Sci. 1998, submitted for publication.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, Guangdong, 510275, China

    Ye-Xiang Tong, Bei-Sheng Kang, Cheng-Yong Su, Xiao-Lan Yu & Xiao-Ming Chen

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  1. Ye-Xiang Tong
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  2. Bei-Sheng Kang
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  3. Cheng-Yong Su
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  4. Xiao-Lan Yu
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  5. Xiao-Ming Chen
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Tong, YX., Kang, BS., Su, CY. et al. Crystal structure of [Co(o-SC6H4NH2){P(OMe)3}3]PF6 . Journal of Chemical Crystallography 28, 635–638 (1998). https://doi.org/10.1023/A:1022417127336

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