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Transport Properties of Selective Membranes Reversible to Nitrogen-Containing Organic Base Cations: Permeability and Ion Flow

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Abstract

Main transport properties were studied for selective membranes with low dielectric constants based on liquid ion exchangers involving nitrogen-containing organic base cations. Permeabilities and ion flows through a membrane were calculated for major and interfering ions. Dependences of the transport properties of membranes on the concentrations of the ion exchanger and near-membrane solution and their potentiometric characteristics are presented. It was demonstrated that the transport properties of liquid membranes are determined by two main factors: the transfer of counterions through the phase boundary by the extraction–exchange mechanism and the leaching of the ion exchanger from the membrane.

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  1. Department of Chemistry, Tver State University, Sadovyi per. 35, Tver, 170002, Russia

    S. V. Kharitonov

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  1. S. V. Kharitonov
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Kharitonov, S.V. Transport Properties of Selective Membranes Reversible to Nitrogen-Containing Organic Base Cations: Permeability and Ion Flow. Journal of Analytical Chemistry 58, 176–183 (2003). https://doi.org/10.1023/A:1022318424085

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