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Effect of Heterogeneous Ion-Exchange Membranes Composition on Their Structure and Transport Properties

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Abstract

The physicochemical properties of experimental heterogeneous MK-40 and MA-41 membranes with different ratios of ion-exchange resin and polyethylene binder in their composition have been studied. It is shown that the specific electrical conductivity in 0.01–1 M NaCl solution decreases triply for cation-exchange membranes and doubly for anion-exchange ones with a decrease in the content of ion-exchange resin in the membranes from 69 to 55%. It has been established that the diffusion permeability of anion-exchange membranes is more sensitive to their composition and naturally increases with an increase in the ion-exchange resin proportion in the composition. Information on the influence of the heterogeneous membrane composition on its structure obtained by the method of standard contact porosimetry is supplemented by the calculation of transport-structural parameters of the microheterogeneous and extended three-wire models of the ion-exchange membrane.

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ACKNOWLEDGMENTS

The study was supported by the Russian Science Foundation, grant no. 21-19-00397, https://rscf.ru/project/21-19-00397/.

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Authors and Affiliations

  1. Voronezh State University, 394018, Voronezh, Russia

    V. I. Vasilieva & E. M. Akberova

  2. Kuban State University, 350040, Krasnodar, Russia

    E. E. Meshcheryakova, I. V. Falina, N. A. Kononenko & M. A. Brovkina

Authors
  1. V. I. Vasilieva
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  2. E. E. Meshcheryakova
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  3. I. V. Falina
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  4. N. A. Kononenko
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  5. M. A. Brovkina
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  6. E. M. Akberova
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Corresponding author

Correspondence to I. V. Falina.

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Translated by V. Avdeeva

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Vasilieva, V.I., Meshcheryakova, E.E., Falina, I.V. et al. Effect of Heterogeneous Ion-Exchange Membranes Composition on Their Structure and Transport Properties. Membr. Membr. Technol. 5, 139–147 (2023). https://doi.org/10.1134/S2517751623030083

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  • DOI: https://doi.org/10.1134/S2517751623030083

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