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Preparation and Properties of Metal/CuInSe2 Diode Structures

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Abstract

The current–voltage characteristics of M/CuInSe2 (M = In, Sn, Cd, Ag, Au) structures were measured. The structures were found to have rectification ratios in the range k= 1.6–33 and to contain an interfacial oxide layer (M/n-In2O3/p-CuInSe2). The spectral response of the structures was studied at 300 K and photon energies from 0.8 to 1.3 eV. The photovoltaic effect was shown to be due not to electron photoemission from the metal to the semiconductor but to photocarrier separation at the interfacial barrier between n-In2O3 and p-CuInSe2.

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REFERENCES

  1. Dittrich, H., Vanghon, D.I., Pattric, R.A., et al., CTMC-10, Stuttgart, 1995, Book Abstr. I.

  2. Konstantinova, N.N., Prochukhan, V.D., Rud', Yu.V., and Tairov, M.A., Spectral Response of I-III-VI2/Electrolyte Contacts, Fiz. Tekh. Poluprovodn. (Leningrad), 1988, vol. 22, no. 9, pp. 1699–1701.

    Google Scholar 

  3. Rud', V.Yu., Rud', Yu.V., and Shpunt, V.Kh., Photovoltaic Effect in p-CuInSe2/Green Leaf Contacts, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 1997, vol. 31, no. 2, pp. 129–131.

    Google Scholar 

  4. Irie, T. and Kimura, E.E., Electrical Properties of p and n-Type CuInSe2 Single Crystals, Jpn. J. Appl. Phys., 1979, vol. 18, no. 7, p. 1303.

    Google Scholar 

  5. Fonash, S.I., Outline and Comparison of the Possible Effects Present in a Metal-Thin-Film-Insulator-Semiconductor Solar Cell, J. Appl. Phys., 1976, vol. 47, no. 8, pp. 3597–3602.

    Google Scholar 

  6. Abdullaev, M.A., Amirkhanova, D.Kh., Akhmedov, A.K., et al., Preparation and Transport Properties of CuInSe2 Crystals and Films, Neorg. Mater., 1992, vol. 28, no. 5, pp. 961–964.

    Google Scholar 

  7. Abdullaev, M.A., Amirkhanova, D.Kh., and Gadzhieva, R.M., Annealing Effect on the Electrical Conductivity and Thermoelectric Power of p-Type CuInSe2 Crystals, Izv. Akad. Nauk SSSR, Neorg. Mater., 1973, vol. 9, no. 6, pp. 785–787.

    Google Scholar 

  8. Gadzhieva, R.M. and Magomedov, I.M., Effects of Annealing Conditions and Nonstoichiometry on the Electrical Conductivity of CuInSe2 Crystals, in Transportnye yavleniya v poluprovodnikakh v sil'nykh polyakh (Transport Properties of Semiconductors in Strong Fields), Makhachkala: Inst. Fiziki Dagestanskogo Nauchnogo Tsentra Ross. Akad. Nauk, 1991, pp. 69–75.

    Google Scholar 

  9. Abdullaev, M.A., Gadzhieva, R.M., Magomedova, D.Kh., and Khokhlachev, P.P., Effect of Intrinsic defects on Hopping Conduction in n- and p-Type CuInSe2 Crystals, Neorg. Mater., 1997, vol. 33, no. 4, pp. 411–414 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 44, 342–345].

    Google Scholar 

  10. Milnes, A.G. and Feucht, D.L., Heterojunctions and Metal-Semiconductor Junctions, New York: Academic, 1972. Translated under the title Geteroperekhody i perekhody metall-poluprovodnik, Moscow: Mir, 1975.

    Google Scholar 

  11. Abdinov, A.Sh., Kyazym-zade, A.G., and Mamedov, V.K., Band Structure of p-GaSe/n-CuInSe2 Heterojunctions, Izv. Akad. Nauk Az. SSR, Ser. Fiz.-Tekh. Mat. Nauk, 1980, no. 2, pp. 113–115.

  12. Growell, C.R. and Sze, S.M., Current Transport in Metal-Semiconductor Barriers, Solid State Electron., 1966, vol. 9, no. 11/12, p. 1035.

    Google Scholar 

  13. Henish, H.K., Rectifying Semiconductor Contacts, Oxford: Clarendon, 1957.

    Google Scholar 

  14. Medvedkin, G.A., Bekimbetov, R.N., Makarova, T.L., et al., Optical Properties of Thermal Oxide on CuInSe2, Zh. Tekh. Fiz., 1987, vol. 57, no. 5, pp. 960–962.

    Google Scholar 

  15. Medvedkin, G.A., Ambrazyavichus, G.A., and Yakovenko, A.A., Oxidation of CuInSe2 Crystals, Poverkhnost, 1987, no. 2, pp. 81–87.

  16. Andrews, I.M. and Philips, J.S., Chemical Bonding and Structure of Metal-Semiconductor Interfaces, Phys. Rev. Lett., 1975, vol. 35, no. 1, pp. 56–59.

    Google Scholar 

  17. Abdullaev, M.A., Excitonic Structure of the Intrinsic Edge in CuInSe2, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 1992, vol. 26, no. 12, pp. 2131–2133.

    Google Scholar 

  18. Meredov, M.M., Kovalevskaya, G.G., Russu, E.V., and Slobodchikov, S.V., Electrical and Photoelectric Properties of Au/p-InP/Au/n-In2O3/p-InP Heterostructures, Fiz. Tekh. Poluprovodn., (S.-Peterburg), 1992, vol. 26, no. 9, pp. 1590–1595.

    Google Scholar 

  19. Deus, P., Neumann, H., Kühn, G., and Hinze, B., Low-Temperature Thermal Expansion in CuInSe2, Phys. Status Solidi A, 1983, vol. 80, pp. 205–209.

    Google Scholar 

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Abdullaev, M.A., Kamilov, I.K., Magomedova, D.K. et al. Preparation and Properties of Metal/CuInSe2 Diode Structures. Inorganic Materials 39, 103–107 (2003). https://doi.org/10.1023/A:1022130226018

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