Abstract
The amphiphilic calix[4]resorcinolarenes, aminomethylated calix[4]resorcinolarenes, o-aminomethylphenols, and their quaternary derivatives in water—dimethylformamide media (10—75 vol.% DMF) form aggregates, which catalyze the hydrolysis of phosphonous esters. The ability to self-association and the catalytic activity of the aggregates depend on the hydrophobicity of the amphiphilic compound, the pH of solution, and the content of DMF.
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Ryzhkina, I.S., Babkina, Y.A., Lukashenko, S.S. et al. The aggregartion and catalytic activity of amphiphilic calix[4]resorcinolarenes and phenols in hydrolysis of phosphonous esters in water—dimethylformamide media. Russian Chemical Bulletin 51, 2183–2188 (2002). https://doi.org/10.1023/A:1022118931584
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DOI: https://doi.org/10.1023/A:1022118931584