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Physical and Chemical Properties of Large Metal and Semiconductor Clusters in View of Future Applications

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Abstract

Metal and semiconductor clusters in the nanometer size regime exhibit quantum size behavior which is demonstrated by means of scanning tunneling spectroscopy and scanning capacitance microscopy on single clusters. Cluster monolayers can be prepared by self-assembly processes on modified surfaces of substrates. Clusters in the channels of nanoporous alumina are promising candidates not only for a novel kind of cluster arrangement for future electronic applications but also for the easy generation of light emitting diodes.

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REFERENCES

  1. For a summarizing article see G. Longoni and M. C. Lapalucci, in G. Schmid (ed.), Clusters and Colloids. From Theory to Applications (VCH, Weinheim, 1994).

    Google Scholar 

  2. B. K. Teo, X. Shi, and H. Zhang (1992). J. Am. Chem. Soc. 114, 2743.

    Google Scholar 

  3. G. Schmid, in G. Schmid (ed.), Clusters and Colloids. From Theory to Applications (VCH, Weinheim, 1994).

    Google Scholar 

  4. D. Fenske, in G. Schmid (ed.), Clusters and Colloids. From Theory to Applications (VCH, Weinheim, 1994).

    Google Scholar 

  5. H. Weller (1993). Angew. Chem. Int. Ed. Engl. 32, 41.

    Google Scholar 

  6. A. P. Alivisatos (1996). Science 271, 933.

    Google Scholar 

  7. A. P. Alivisatos (1998). MRS Bull. 23, 18.

    Google Scholar 

  8. D. C. Ralph, C. T. Black, and M. Tinkham (1995). Phys. Rev. Lett. 74, 3241.

    Google Scholar 

  9. D. C. Ralph, C. T. Black, and M. Tinkham (1996). Physika B 218, 258.

    Google Scholar 

  10. J. G. A. Dubois, J. W. Gerritsen, S. E. Shafranjuk, E. J. G. Boon, G. Schmid, and H. van Kempen (1996). Europhys. 33, 279.

    Google Scholar 

  11. H. van Kempen, J. G. A. Dubois, J. W. Gerritsen, and G. Schmid (1995). Physika B 204, 51.

    Google Scholar 

  12. A. Bezryadin, C. Dekker, and G. Schmid (1997). Appl. Phys. Lett. 71, 1273.

    Google Scholar 

  13. G. Schmid and L. F. Chi (1998). Adv. Mater. 10, 515.

    Google Scholar 

  14. G. Schmid and M. Bäumle (1998). Unpublished results.

  15. F. Müller, A.-D. Müller, St. Peschel, M. Hietschold, and G. Schmid (1998). Unpublished results.

  16. R. P. Andres, J. D. Bielefeld, J. I. Henderson, D. B. Jones, V. R. Kolagunta, C. P. Kubiak, W. J. Mahony, and R. G. Osifchin (1996). Science 273, 1690.

    Google Scholar 

  17. R. L. Whetten, J. T. Khoury, M. M. Alvarez, S. Murthy, I. Vezmar, Z. Wang, P. W. Stephens, Ch. L. Cleveland, W. D. Luedtke, and U. Landmann (1996). Adv. Mater. 8, 428.

    Google Scholar 

  18. M. Brust, M. Walker, D. Bethell, J. D. Shiffirin, and R. Whyman (1994). J. Chem. Soc. Chem. Commun. 801.

  19. S. A. Harfenist, Z. L. Wang, M. M. Alvarez, I. Vezmar, and R. L. Whetten (1996). J. Phys. Chem. 100, 13904.

    Google Scholar 

  20. G. Schmid, R. Pugin, J.-O. Malm, and J.-O Bovin (1998). Eur. J. Inorg Chem. 6, 813.

    Google Scholar 

  21. G. Schmid and St. Peschel (1998). New. J. Chem. 669.

  22. G. Decher and J. D. Hong (1991). Ber. Bunsenges. Phys. Chem. 95, 1430.

    Google Scholar 

  23. G. Decher (1993). Nachr. Chem. Tech. Lab. 41, 793.

    Google Scholar 

  24. T. Yonezawa, S. Onoue, and T. Kunitake (1998). Adv. Mater. 10, 414.

    Google Scholar 

  25. J. W. Diggle, T. C. Downie, and C. W. Goulding (1996). Chem. Rev. 69, 365.

    Google Scholar 

  26. M. M. Lohrengel (1993). Mater. Sci. Eng. R11, 241.

    Google Scholar 

  27. H. Masuda and F. Fukuda (1995). Science 248, 1466.

    Google Scholar 

  28. C. Martin (1994). Science 266, 1961.

    Google Scholar 

  29. H. Masuda, K. Nishio, and N. Baba (1993). Thin Solid Films 223, 1.

    Google Scholar 

  30. G. Hornyak, M. Kröll, R. Pugin, Th. Sawitowski, G. Schmid, J.-O. Bovin, G. Karsson, H. Hofmeister, and S. Hopfe (1997). Chem. Eur. J. 3, 1951.

    Google Scholar 

  31. D. Al-Mawlawi, C. Z. Liu, and M. Moskovits (1994). J. Mater. Res. 9, 1014.

    Google Scholar 

  32. D. N. Davydov, J. Haruyama, D. Routkevitch, B. W. Statt, D. Ellis, M. Moskovits, and J. M. Xu (1998). Phys. Rev. B 57, 13550.

    Google Scholar 

  33. Th. Sawitowski and G. Schmid (1998). Unpublished results.

  34. A. Heilmann, P. Jutzi, A. Klipp, U. Kreibig, R. Neuendorf, Th. Sawitowski, and G. Schmid (1998). Adv. Mater. 10, 398.

    Google Scholar 

  35. G. Schmid and I. Heim (1998). Unpublished results.

  36. A. Heilmann, W. Grünwald, and G. Schmid (1998). Unpublished results.

  37. G. Schmid and M. Kröll (1998). Unpublished results.

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Schmid, G., Bäumle, M., Heim, I. et al. Physical and Chemical Properties of Large Metal and Semiconductor Clusters in View of Future Applications. Journal of Cluster Science 10, 223–237 (1999). https://doi.org/10.1023/A:1021921528340

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  • DOI: https://doi.org/10.1023/A:1021921528340

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