Abstract
Structures of the inclusion compounds formed between the host compound 1,4-bis(9-hydroxy-9-fluorenyl)benzene and three lutidine regioisomers, 2,4-, 3,5-, and 2,6-lutidine, have been elucidated. Competition experiments were performed to investigate the degree of host selectivity for complexation with the lutidine isomers. Lattice energy calculations explain the results of the competition experiments, and thermal analysis shows that the desolvation reactions are complex.
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Caira, M.R., Nassimbeni, L.R., Vujovic, D. et al. Separation of Lutidine Isomers by Inclusion. Structural Chemistry 10, 205–211 (1999). https://doi.org/10.1023/A:1021836513608
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DOI: https://doi.org/10.1023/A:1021836513608