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Isotopic Study of the Formation of Phenoxazine Derivatives in the Transformations of 3,5-Di-tert-Butylcatechol Adsorbed in Thin SiO2-nTiO2 Layers in the Air

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A study was carried out on the isotopic composition of the tetra-tert-butylphenoxazine derivatives formed in the heterophase transformations of 3,5-di-tert-butylcatechol adsorbed on thin SiO2 layers with microscopic traces of Ti and Mn in a nitrogen-oxygen atmosphere enriched with 15N2. The formation of isotopically-labeled tetra-tert-butylphenoxazinyl and hydroxytetra-tert-butylphenoxazinyl radicals and tetra-tert-butylphenoxazinone indicated the participation of atmospheric nitrogen in the heterophase catalytic reaction.

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Authors and Affiliations

  1. N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 117977, Russia

    B. V. Vol'eva, N. L. Komissarova, I.S. Belostotskaya, T. I. Prokof'eva & V. V. Ershov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813, Russia

    A. I. Prokof'ev

Authors
  1. B. V. Vol'eva
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  2. A. I. Prokof'ev
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  3. N. L. Komissarova
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  4. I.S. Belostotskaya
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  5. T. I. Prokof'eva
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  6. V. V. Ershov
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Vol'eva, B.V., Prokof'ev, A.I., Komissarova, N.L. et al. Isotopic Study of the Formation of Phenoxazine Derivatives in the Transformations of 3,5-Di-tert-Butylcatechol Adsorbed in Thin SiO2-nTiO2 Layers in the Air. Chemistry of Heterocyclic Compounds 38, 1276–1282 (2002). https://doi.org/10.1023/A:1021797900885

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  • DOI: https://doi.org/10.1023/A:1021797900885

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