Skip to main content
Log in

Osmotic and Activity Coefficients of CH3SO4Na(aq) and CH3SO4K(aq) at 25°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The osmotic and activity coefficients of aqueous sodium and potassium methyl sulfates have been determined at 25°C by the isopiestic method, in the molality range from ca.0.2 to 25 and 19 mol-kg−1, respectively. The results have been discussed in terms of the ion–ion and ion–water interactions on the basis of the Pitzer and Mayorga model and a method developed in our laboratory.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Z. Libuś and K. Chachulska, Z. Phys. Chem. Neue Folge 167, 235 (1990).

    Google Scholar 

  2. Z. Libuś, Z. Phys. Chem. 209, 239 (1999).

    Google Scholar 

  3. T. Gampe and Z. Libuś, J. Chem. Thermodyn. 31, 93 (1999).

    Google Scholar 

  4. Z. Libuś, Z. Phys. Chem. Neue Folge 166, 71 (1990).

    Google Scholar 

  5. Z. Libuś and K. Chachulska, J. Mol. Liquids 46, 53 (1990).

    Google Scholar 

  6. T. Gampe and Z. Libuś, J. Chem. Thermodyn. 26, 261 (1994).

    Google Scholar 

  7. Z. Libuś, T. Sadowska, and J. Trzaskowski, J. Chem. Thermodyn. 11, 1151 (1979).

    Google Scholar 

  8. W. J. Hamer, Y. C. Wu, J. Phys. Chem. Ref. Data 1, 1047 (1972).

    Google Scholar 

  9. J. A. Rard, A. Habenschuss, and F. H. Spedding, J. Chem. Eng. Data 22, 180 (1977).

    Google Scholar 

  10. K. S. Pitzer, J. Phys. Chem. 77, 268 (1973).

    Google Scholar 

  11. K. S. Pitzer and G. J. Mayorga, J. Phys. Chem. 77, 2300 (1973).

    Google Scholar 

  12. Z. Libuś, Z. Phys. Chem. 196, 165 (1996).

    Google Scholar 

  13. J. Stangret and T. Gampe, Proc. Polish Chem. Soc. Conf., 1996, 23–26 September, Poznań, Poland, S-1, J-34.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gampe, T., Libuś, Z. Osmotic and Activity Coefficients of CH3SO4Na(aq) and CH3SO4K(aq) at 25°C. Journal of Solution Chemistry 28, 837–847 (1999). https://doi.org/10.1023/A:1021780130601

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021780130601

Navigation