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Effect of the Ligand Nature in Zinc(II) Complexes on the Inner-Sphere Reorganization in the Electron Transfer Reactions

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Abstract

The effect of the ligand surrounding on the character and degree of the inner-sphere reorganization during electroreduction of aqua, aquahydroxy, hydroxy, and Edta complexes of zinc(II) is studied in the framework of a quantum-chemical approach. It is established that the most substantial intramolecular reorganization occurs during the transfer of the first electron onto [Zn(Edta)]2–. The solvent's reorganization energy is estimated.

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REFERENCES

  1. Dogonadze, R.R. and Kuznetsov, A.M., Elektrokhimiya, 1967, vol. 3, p. 1324.

    Google Scholar 

  2. Dogonadze, R.R. and Kuznetsov, A.M., Elektrokhimiya, 1971, vol. 7, p. 172.

    Google Scholar 

  3. Vorotyntsev, M.A., Dogonadze, R.R., and Kuznetsov, A.M., Elektrokhimiya, 1971, vol. 7, p. 306.

    Google Scholar 

  4. German, E.D. and Kuznetsov, A.M., Elektrokhimiya, 1990, vol. 26, p. 931.

    Google Scholar 

  5. Kuznetsov, A.M., Charge Transfer in Physics, Chemistry and Biology: Mechanisms of Elementary Processes and Introduction to the Theory, Berkshire: Gordon and Breach, 1995.

    Google Scholar 

  6. Kuznetsov, A.M., Stochastic and Dynamic Views of Chemical Reaction Kinetics in Solutions, Lausanne: Press Polytechniques et Universitaires Romandes, 1999.

    Google Scholar 

  7. Kuznetsov, A.M. and Ulsturp, J., Electron Transfer in Chemistry and Biology, Chichester: Wiley, 1999.

    Google Scholar 

  8. Nazmutdinov, R.R. and Shapnik, M.S., Electrochim. Acta, 1996, vol. 41, p. 2253.

    Google Scholar 

  9. Nazmutdinov, R.R., Tsirlina, G.A., Kharkats, Yu.I., et al., J. Phys. Chem. B, 1998, vol. 102, p. 677.

    Google Scholar 

  10. Nazmutdinov, R.R., Pobelov, I.V., Tsirlina, G.A., and Petrii, O.A., J. Electroanal. Chem., 2000, vol. 491, p. 126.

    Google Scholar 

  11. Nazmutdinov, R.R., Tsirlina, G.A., Kharkats, Yu.I., et al., Electrochim. Acta, 2000, vol. 45, p. 3521.

    Google Scholar 

  12. Kudryavtsev, N.T., Elektroliticheskie pokrytiya metallami (Electroplating with Metals), Moscow: Khimiya, 1979.

    Google Scholar 

  13. Purin, B.A., Tsera, V.A., Ozola, E.A., and Vitinya, I.A., Kompleksnye elektrolity v gal'vanotekhnike (Complex Electrolytes in Electroplating Technology), Riga: Liesma, 1978.

    Google Scholar 

  14. Kravtsov, V.I., Elektrokhimiya, 1995, vol. 31, p. 1165.

    Google Scholar 

  15. Koene, L., Sluyters-Rehbach, M., and Sluyters, J.H., J. Electroanal. Chem., 1996, vol. 402, p. 57.

    Google Scholar 

  16. van Venroij, T.G.J., Sluyters-Rehbach, M., and Sluyters, J.H., J. Electroanal. Chem., 1996, vol. 419, p. 61.

    Google Scholar 

  17. Eberhardt, D., Wasserstoffentwicklung und Zinkabscheidung an Silbereinkristallelectroden, PhD Thesis, Ulm, 2001.

  18. Becke, A.D., J. Chem. Phys., 1992, vol. 98, p. 1372; 1992, vol. 98, p. 648.

    Google Scholar 

  19. Becke, A.D., Phys. Rev. A: Gen. Phys., 1988, vol. 38, p. 3098.

    Google Scholar 

  20. Vosco, S.H., Wilk, L., and Nusair, M., Phys. Rev. B: Condens. Matter, 1988, vol. 37, p. 785.

    Google Scholar 

  21. Vosco, S.H., Wilk, L., and Nusair, M., Can. J. Phys., 1980, vol. 58, p. 1200.

    Google Scholar 

  22. Blomberg, M.R.A. and Siegbahn, P.E.M., J. Phys. Chem. B, 2001, vol. 105, p. 9375.

    Google Scholar 

  23. Hehre, W.J., Radom, L., Schleyer, P.v.R., and Pople, J.A., Ab Initio Molecular Orbital Theory, New York: Wiley, 1986.

    Google Scholar 

  24. Hay, P.J. and Wadt, W.R., J. Chem. Phys., 1985, vol. 82, p. 270.

    Google Scholar 

  25. Levine, I.N., Quantum Chemistry, Englewood Cliffs (NJ): Prentice-Hall, 1991.

    Google Scholar 

  26. Nazmutdinov, R.R., Elektrokhimiya, 2002, vol. 38, p. 131.

    Google Scholar 

  27. Tomassi, J. and Persico, M., Chem. Rev., 1994, vol. 94, p. 2027.

    Google Scholar 

  28. Frisch, M.J., Trucks, G.W., Schlegel, H.B., et al., Gaussian 98, Revision A.9., Pittsburgh: Gaussian, Inc., 1998.

    Google Scholar 

  29. HyperChem. Computational Chemistry, Hypercube, Inc., 2001.

  30. Marcus, Y., Chem. Rev., 1988, vol. 88, p. 1475.

    Google Scholar 

  31. Lur'e, Yu.Yu., Spravochnik po analiticheskoi khimii (A Handbook of Analytical Chemistry), Moscow: Khimiya, 1979, 480.

    Google Scholar 

  32. Pandya, K.S., Russell, A.E., McBreen, J., and O'Grady, W.E., J. Phys. Chem., 1995, vol. 99, p. 11967.

    Google Scholar 

  33. Pozhidaev, A.I., Polynova, T.N., Porai-Koshits, M.A., and Neronova, N.N., Zh. Strukt. Khim., 1973, vol. 14, p. 570.

    Google Scholar 

  34. Marcus, R.A., J. Chem. Phys., 1956, vol. 24, p. 966.

    Google Scholar 

  35. Marcus, R.A., Can. J. Chem., 1959, vol. 37, p. 1551.

    Google Scholar 

  36. Tsirlina, G.A., Kharkats, Yu.I., Nazmutdinov, R.R., and Petrii, O.A., J. Electroanal. Chem., 1998, vol. 450, p. 63.

    Google Scholar 

  37. German, E.D. and Kuznetsov, A.M., J. Phys. Chem., 1994, vol. 98, p. 6120.

    Google Scholar 

  38. Savéant, J.-M., J. Am. Chem. Soc., 1987, vol. 109, p. 6788.

    Google Scholar 

  39. Savéant, J., Acc. Chem. Res., 1993, vol. 26, p. 455.

    Google Scholar 

  40. Borisevich, S.V., Kharkats, Yu.I., and Tsirlina, G.A., Elektrokhimiya, 1999, vol. 35, p. 753.

    Google Scholar 

  41. Vasilenko, A.A. and Berdnikov, V.M., Khim. Fiz., 1989, vol. 8, p. 687.

    Google Scholar 

  42. Nazmutdinov, R.R., Shapnik, M.S., and Malyucheva, O.I., Elektrokhimiya, 1991, vol. 27, p. 986.

    Google Scholar 

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Authors and Affiliations

  1. Kazan State Technological University, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia

    R. R. Nazmutdinov, M. S. Shapnik, E. E. Starodubets & T. P. Petrova

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  1. R. R. Nazmutdinov
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  2. M. S. Shapnik
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  3. E. E. Starodubets
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  4. T. P. Petrova
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Nazmutdinov, R.R., Shapnik, M.S., Starodubets, E.E. et al. Effect of the Ligand Nature in Zinc(II) Complexes on the Inner-Sphere Reorganization in the Electron Transfer Reactions. Russian Journal of Electrochemistry 38, 1339–1345 (2002). https://doi.org/10.1023/A:1021676923677

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