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Electrochemical oxidation of 2H-imidazole N-oxides

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Abstract

Electrochemical oxidation of 2H-imidazole N-oxides was studied using cyclic voltammetry and ESR spectroscopy. The formation of the 2,2-dimethyl-4,5-diphenyl-2H-imidazole 1,3-dioxide radical cation was noticed for the first time. The possibility of reaction between the 2H-imidazole N,N-dioxide radical cation and methanol including the detachment of a hydrogen atom from the MeOH methyl group was demonstrated.

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Authors and Affiliations

  1. Siberian Branch of the Russian Academy of Sciences, N. N. Vorozhtsov Institute of Organic Chemistry, 9 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    I. G. Irtegova, V. F. Starichenko, I. A. Kirilyuk & I. A. Grigor"ev

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  1. I. G. Irtegova
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  2. V. F. Starichenko
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  3. I. A. Kirilyuk
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  4. I. A. Grigor"ev
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Irtegova, I.G., Starichenko, V.F., Kirilyuk, I.A. et al. Electrochemical oxidation of 2H-imidazole N-oxides. Russian Chemical Bulletin 51, 2065–2069 (2002). https://doi.org/10.1023/A:1021663910782

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